Rhodium-catalyzed reductive allylation of conjugated aldehydes with allyl acetate

Journal of Organic Chemistry

Volumn 75, Issue 8, 2010, Pages 2710-2713

  Vasylyev, Maksym ^a   Alper, Howard ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

[CARBONYL; A-CARBON; ALKENYL; ALLYL ACETATE; ALLYLATIONS; CONJUGATED ALDEHYDES; HOMOALLYLIC ALCOHOL; ISOLATED YIELD; RHODIUM COMPLEXES; RHODIUM-CATALYZED;

ALDEHYDES; CARBON MONOXIDE; RHODIUM;

RHODIUM COMPOUNDS;

ALDEHYDE DERIVATIVE; ALLYL ACETIC ACID; ALLYL COMPOUND; BENZALDEHYDE; RHODIUM COMPLEX; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; CATALYSIS; REACTION ANALYSIS; REDUCTION; SYNTHESIS;

EID: 77950988253     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo902706p     Document Type: Article

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19. +] 2%), 123 (97), 121 (100), 107 (4), 105 (4), 95 (5), 93 (6), 81 (5), 78 (5)). Formation of propene explains the need for an excess of allyl acetate for the reaction.
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24. Carbon monoxide is a highly poisonous gas; please see the Supporting Information for the safety requirements.