Et3B-Pd-promoted allylation of benzaldehyde with allylic alcohols

Tetrahedron Letters

Volumn 41, Issue 19, 2000, Pages 3627-3629

  Kimura, Masanari ^a   Tomizawa, Tatsuya ^a   Horino, Yoshikazu ^a   Tanaka, Shuji ^a   Tamaru, Yoshinao ^a  

^a NAGASAKI UNIVERSITY   (Japan)

Author keywords

Aldehydes; Allylation; Boron and compounds; Palladium and compounds

Indexed keywords

ALLYL COMPOUND; BENZALDEHYDE; BORON DERIVATIVE; PALLADIUM;

ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; NONHUMAN; SYNTHESIS;

EID: 0034612040     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00429-9     Document Type: Article

References (7)

1. (a) Yamamoto, Y.; Asao, N. Chem. Rev. 1993, 93, 2207;
2. (b) Brown, H. C.; Racherla, U. S.; Pellechia, P. J. J. Org. Chem. 1990, 55, 1868.
3. Takahara, J. P.; Masuyama, Y.; Kurusu, Y. J. Am. Chem. Soc. 1992, 114, 2577.
4. Kimura, M.; Kiyama, I.; Tomizawa, T.; Horino, Y.; Tanaka, S.; Tamaru, Y. Tetrahedron Lett. 1999, 40, 6795.
5. 2, see: Stary, I.; Stara, I. G.; Kocovsky, P. Tetrahedron Lett. 1993, 34, 179.
6. Details of the palladium-catalyzed direct allylation of soft nucleophiles with allyl alcohols will be reported in due course.
7. Financial support from the Ministry of Education, Science, Sports and Culture, Japanese Government, Grant-in-Aid for Scientific Research B, is acknowledged. We also thank Mr. Y. Ohhama (NMR Facility) for his splendid assistance.