Cobalt(II) "scorpionate" Complexes as models for cobalt-substituted zinc enzymes: Electronic structure investigation by high-frequency and -field electron paramagnetic resonance spectroscopy

Journal of the American Chemical Society

Volumn 132, Issue 14, 2010, Pages 5241-5253

  Krzystek, J ^a   Swenson, Dale C ^b   Zvyagin, S A ^c   Smirnov, Dmitry ^a   Ozarowski, Andrew ^a   Telser, Joshua ^d  

^a FLORIDA STATE UNIVERSITY   (United States)

^b E11 SSH   (United States)

^c INSTITUTE OF ION BEAM PHYSICS AND MATERIALS RESEARCH   (Germany)

^d ROOSEVELT UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANGULAR OVERLAP MODEL; AXIAL ZERO-FIELD SPLITTING PARAMETER; COBALT COMPLEXES; ELECTRON PARAMAGNETIC RESONANCE; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; ELECTRONIC ABSORPTION SPECTROSCOPY; ENERGY LEVEL; G-VALUES; HIGH FREQUENCY HF; HIGH-SPIN GROUND STATE; LIGAND-FIELD; METALLO-PROTEINS; NEAR-IR; POINT GROUP SYMMETRY; PSEUDOTETRAHEDRAL; SPIN HAMILTONIAN PARAMETERS; THIENYL; VISIBLE AND NEAR INFRARED;

ABSORPTION SPECTROSCOPY; CATALYSTS; COBALT; COBALT COMPOUNDS; CRYSTAL STRUCTURE; ELECTRON RESONANCE; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; ENZYMES; HAMILTONIANS; INFRARED SPECTROSCOPY; METAL IONS; METAL RECOVERY; PARAMAGNETIC MATERIALS; PARAMAGNETIC RESONANCE; SPIN DYNAMICS; ZINC;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

COBALT COMPLEX; HYDRO(TRIS PYRAZOL 1 YL)BORATE; LIGAND; METAL COMPLEX; METALLOPROTEIN; PYRAZOLE DERIVATIVE; UNCLASSIFIED DRUG; ZINC;

ABSORPTION SPECTROSCOPY; ARTICLE; BINDING SITE; COMPLEX FORMATION; COMPUTER ANALYSIS; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; GEOMETRY; INFRARED SPECTROSCOPY; LIGAND BINDING; LIGAND FIELD THEORY; MODEL; PROTEIN ANALYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

COBALT; CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; ZINC;

EID: 77950851523     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910766w     Document Type: Article

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