Scanning electrochemical microscopy: Surface interrogation of adsorbed hydrogen and the open circuit catalytic decomposition of formic acid at platinum

Journal of the American Chemical Society

Volumn 132, Issue 14, 2010, Pages 5121-5129

  Rodríguez López, Joaquín ^a   Bard, Allen J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIC MEDIA; ADSORBED HYDROGEN; ADSORBED SPECIES; CATALYTIC DECOMPOSITION; CONCENTRATION OF; ELECTROCHEMICAL MEDIATORS; FEEDBACK RESPONSE; IN-SITU; OPEN CIRCUIT POTENTIAL; OPEN CIRCUITS; P-PHENYLENE DIAMINES; POLYCRYSTALLINE PLATINUM; POSITIVE POTENTIAL; PT ELECTRODE; SCANNING ELECTROCHEMICAL MICROSCOPY; SURFACE INTERROGATION; TETRAMETHYL; UNDERPOTENTIAL DEPOSITION;

CATALYST ACTIVITY; FORMIC ACID; FREE RADICALS; HYDROGEN; MONOLAYERS; OPEN CIRCUIT VOLTAGE; ORGANIC ACIDS; OXYGEN; SCANNING ELECTRON MICROSCOPY; SCANNING PROBE MICROSCOPY; SURFACE STRUCTURE;

PLATINUM;

FORMIC ACID; HYDROGEN; METAL COMPLEX; PLATINUM;

ADSORPTION; ARTICLE; CATALYSIS; COMPLEX FORMATION; DECOMPOSITION; ELECTROCHEMISTRY; ELECTRON; MICROSCOPY; OXIDATION; SCANNING ELECTROCHEMICAL MICROSCOPY;

ADSORPTION; CATALYSIS; ELECTROCHEMISTRY; ELECTRODES; FORMIC ACIDS; HYDROGEN; MICROSCOPY, ELECTRON, SCANNING; PLATINUM; SURFACE PROPERTIES;

EID: 77950830631     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9090319     Document Type: Article

References (65)

1. Scanning Electrochemical Microscopy; Bard, A. J. and Mirkin, M. V., Eds.; Marcel Dekker: New York, 2001.
2. Rodríguez-López, J., Alpuche-Avilés, M. A., and Bard, A. J. J. Am. Chem. Soc. 2008, 130, 16985-16995
3. Woods, R. Chemisorption at Electrodes. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1976; pp 1-162.
4. Bard, A. J., Fan, F. F., Pierce, D. T., Unwin, P. R., Wipf, D. O., and Zhou, F. Science 1991, 254 (5028) 68-74
5. Bard, A. J., Denuault, G., Lee, C., Mandler, D., and Wipf, D. O. Acc. Chem. Res. 1990, 23, 357-363
6. Pust, S. E., Maier, W., and Wittstock, G. Z. Phys. Chem. 2008, 222, 1463-1517
7. Bard, A. J. and Faulkner, L. R. Electrochemical Methods; Wiley: New York, 2001.
8. Fernandez, J. L., Walsh, D. A., and Bard, A. J. J. Am. Chem. Soc. 2005, 127, 357-365
9. Sánchez-Sánchez, C. M., Rodríguez-López, J., and Bard, A. J. Anal. Chem. 2008, 80, 3254-3260
10. Minguzzi, A., Alpuche-Avilés, M. A., Rodríguez- López, J., Rondinini, S., and Bard, A. J. Anal. Chem. 2008, 80, 4055-4064
11. Lin, C.-L., Sánchez-Sánchez, C. M., and Bard, A. J. J. Electrochem. Solid-State Lett. 2008, 11, B136-B139
12. Lee, J., Ye, H., Pan, S., and Bard, A. J. Anal. Chem. 2008, 80, 7445-7450
13. Sun, Y. M., Alpuche-Avilés, M. A., Bard, A. J., Zhou, J. P., and White, J. M. J. Nanosci. Nanotechnol. 2009, 9, 1281-1286
14. Jung, C., Sánchez-Sánchez, C. M., Lin, C.-L., Rodríguez-López, J., and Bard, A. J. Anal. Chem. 2009, 81, 7003-7008
15. Rice, C., Ha, S., Masel, R. I., and Wieckowski, A. J. Power Sources 2003, 115, 229-235
16. Rodríguez, J. L. and Pastor, E. Electrochim. Acta 1998, 44, 1173-1179
17. Lu, G.-Q., Crown, A., and Wieckowski, A. J. Phys. Chem. B 1999, 103, 9700-9711
18. Chen, Y.-X., Shen, Y., Heinen, M., Jusys, Z., Osawa, M., and Behm, R. J. J. Phys. Chem. B 2006, 110, 9534-9544
19. Chen, Y.-X., Heinen, M., Jusys, Z., and Behm, R. J. Langmuir 2006, 22, 10399-10408
20. Chen, Y.-X., Heinen, M., Jusys, Z., and Behm, R. J. Chem. Phys. Chem. 2007, 8, 380-385
21. Miki, A., Ye, S., Senzaki, T., and Osawa, M. J. Electroanal. Chem. 2004, 563, 23-31
22. Samjeske, G., Miki, S., Ye, A., Yamakata, Y., Mukouyama, H., Okamoto, H., and Osawa, M. J. Phys. Chem. B 2005, 109, 23509-23516
23. Breiter, M. W. J. Electrochem. Soc. 1964, 111, 1298-1299
24. Gottlieb, M. H. J. Electrochem. Soc. 1964, 111, 465-472
25. Munson, R. A. J. Electrochem. Soc. 1964, 111, 372-376
26. Parsons, R. and VanderNoot, T. J. Electroanal. Chem. 1988, 257, 9-45
27. Oxley, J. E., Johnson, G. K., and Buzalski, B. T. Electrochim. Acta 1964, 9, 897-910
28. Schwabe, K. Z. Elektrochem. 1957, 61, 744-752
29. Breiter, M. W. Electrochim. Acta 1963, 8, 447-456, 457-470.
30. Fleischmann, C. W., Johnson, G. K., and Kuhn, A. T. J. Electrochem. Soc. 1964, 111, 602-605
31. Eckert, J. Electrochim. Acta 1967, 12, 307-328
32. Podlovchenko, B. I., Manzhos, R. A., and Maksimov, Y. M. Russ. J. Electrochem. 2006, 42, 1061-1066
33. See also: Podlovchenko, B. I., Manzhos, R. A., and Maksimov, Y. M. Russ. J. Electrochem. 2006, 42, 658-664
34. Podlovchenko, B. I., Manzhos, R. A., and Maksimov, Y. M. Electrochim. Acta 2005, 50, 4807-4813
35. Tian, M. and Conway, B. E. J. Electroanal. Chem. 2008, 616, 45-56
36. Papapolymerou, G. A. and Schmidt, L. D. Langmuir 1987, 3, 1098-1102
37. Columbia, M. R. and Thiel, P. A. J. Electroanal. Chem. 1994, 369, 1-14
38. Columbia, M. R., Crabtree, A. M., and Thiel, P. A. J. Electroanal. Chem. 1993, 345, 93-105
39. Dahlberg, S. C., Fisk, G. A., and Rye, R. R. J. Catal. 1975, 36, 224-234
40. Tevault, D. E., Lin, M. C., Umstead, M. E., and Smardzewski, R. R. Int. J. Chem. Kinet. 1979, 11, 445-449
41. Thomas, F. S. and Masel, R. I. Surf. Sci. 2004, 573, 169-175
42. Baldauf, M. and Kolb, D. M. J. Phys. Chem. 1996, 100, 11375-11381
43. Brandt, K., Steinhausen, M., and Wandelt, K. J. Electroanal. Chem. 2008, 616, 27-37
44. Burke, L. D. and Casey, J. K. J. Appl. Electrochem. 1993, 23, 573 582
45. Burke, L. D., Kemball, C., and Lewis, F. A. Catalysis 1966, 5, 539-542
46. Ananiev, A. V., Broudic, J.-C., and Brossard, P. App. Catal., B 2003, 45, 197-203
47. Parravano, G. J. Am. Chem. Soc. 1950, 72, 5546-5549
48. Bickford, D. F., Coleman, C. J., Hsu, C. L. W., and Eibling, R. E. Ceram. Trans. 1991, 23, 283-294
49. Yue, C. M. Y. and Lim, K. W. Catal. Lett. 2009, 128, 221-226
50. Hamada, I. and Yoshitada, M. J. Phys. Chem. C 2008, 112, 10889-10898
51. Kunimatsu, K., Senzaki, T., Tsushima, M., and Osawa, M. Chem. Phys. Lett. 2005, 401, 451-454
52. Chun, J. H., Ra, K. H., and Kim, N. Y. Int. J. Hydrogen Energy 2001, 26, 941-948
53. Rodríguez-López, J., Alpuche-Aviles, M. A., and Bard, A. J. Anal. Chem. 2008, 80, 1813-1818
54. Xiong, H., Guo, J., and Amemiya, S. Anal. Chem. 2007, 79, 2735-2744
55. Macpherson, J. V., Slevin, C. J., and Unwin, P. R. J. Chem. Soc. Faraday Trans. 1996, 92, 3799-3805
56. Zhang, M., Bin, S., Cortes-Salazar, F., Hojeij, M., and Girault, H. H. Electrochem. Commun. 2008, 10, 714-718
57. Schnippering, M., Powell, H. V., Zhang, M., Macpherson, J. V., Unwin, P. R., Mazurenka, M., and Mackenzie, S. R. J. Phys. Chem. C 2008, 112, 15274-15280
58. Sheffer, M. and Mandler, D. J. Electrochem. Soc. 2008, 155, D203-D208
59. Wang, Q., Rodríguez-López, J., and Bard, A. J. J. Am. Chem. Soc. 2009, 131, 17046-17047
60. Zhang, Y. and Weaver, M. J. Langmuir 1993, 9, 1397-1403
61. Hamelin, A., Ho, Y., Chang, S.-C., Gao, X., and Weaver, M. J. Langmuir 1992, 8, 975-981
62. Offer, G. J. and Kucernak, A. R. J. Electroanal. Chem. 2008, 613, 171-185
63. Ma, Z. and Zaera, F. Catal. Lett. 2004, 96, 5-12
64. Neurock, M., Janik, M., and Wieckowski, A. Faraday Discuss. 2008, 140, 363-378
65. Jacobs, G., Patterson, P. M., Graham, U. M., Crawford, A. C., and Davis, B. H. Int. J. Hydrogen Energy 2005, 30, 1265-1276