Fluorescent Fe(II) metallo-supramolecular polymers: Metal-ion-directed self-assembly of new bisterpyridines containing triethylene glycol chains

Polymer Journal

Volumn 42, Issue 4, 2010, Pages 336-341

  Pal, Ravindra R ^a   Higuchi, Masayoshi ^a,b   Negishi, Yuichi ^c   Tsukuda, Tatsuya ^d   Kurth, Dirk G ^e  

^a NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c TOKYO UNIVERSITY OF SCIENCE   (Japan)

^d HOKKAIDO UNIVERSITY   (Japan)

^e UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Bisterpyridine; Fluorescence; Metallo supramolecular polymers; Triethylene glycol

Indexed keywords

DIRECTED SELF-ASSEMBLY; METALLO-SUPRAMOLECULAR; METALLO-SUPRAMOLECULAR POLYMERS; PYRIDINE RINGS; SUBSTITUENT EFFECT; TRIETHYLENE GLYCOL;

ELECTROCHEMICAL PROPERTIES; FLUORESCENCE; GLYCOLS; IONS; SUPRAMOLECULAR CHEMISTRY; THERMOELECTRIC EQUIPMENT;

POLYMERS;

EID: 77950522485     PISSN: 00323896     EISSN: 13490540     Source Type: Journal    
DOI: 10.1038/pj.2010.3     Document Type: Article

References (20)

1. Friend, R. H., Gymer, R. W., Holmes, A. B., Burroughes, J. H., Marks, R. N., Taliani, C., Bradley, D. D. C., Dos Santos, D. A., Brédas, J. L., Lögdlund, M. & Salaneck, W. R. Electroluminescence in conjugated polymers. Nature 397, 121-128 (1999). (Pubitemid 29050908)
2. Brabec, C. J., Sariciftci, N. S. & Hummelen, J. C. Plastic solar cells. Adv. Funct. Mater. 11, 15-26 (2001).
3. Wilson, J. S., Dhoot, A. S., Seeley, A.J.A.B., Khan, M. S., Köhler, A. & Friend, R. H. Spindependent exciton formation in p-conjugated compounds. Nature 413, 828-831 (2001). (Pubitemid 33026846)
4. Schubert, U. S., Hofmeier, H. & Newkome, G. R. Modern Terpyridine Chemistry, Wiley- VCH: Weinheim, (2006).
5. Auffrant, A., Barbieri, A., Barigelletti, F., Collin, J. P., Flamigni, L., Sabatini, C. & Sauvage, J. P. Dinuclear Iridium(iii) complexes consisting of back-to-back tpy bridging ligands (n=0,1, or 2) and terminal cyclometallating tridentate N-C-N ligands. Inorg. Chem. 45, 10990-10997 (2006).
6. Medlycott, E. A. & Hanan, G. S. Designing tridentate ligands for ruthenium(II) with prolonged room temperature luminescence lifetimes. Chem. Soc. Rev. 34, 133-142 (2005).
7. Brombosz, S. M., Zucchero, A. J., Phillips, R. L., Vazquez, D., Wilson, A. & Bunz, U. H. F. Terpyridine-based Cruciform-Zn2+ complexes as anion-responsive fluorophores. Org. Lett. 9, 4519-4522 (2007) and references therein.
8. Hofmeier, H. & Schubert, U. S. Recent development of supramolecular chemistry of terpyridine-metal complexes. Chem. Soc. Rev. 33, 373-399 (2004). (Pubitemid 39172100)
9. Dobrawa, R., Lysetska, M., Ballester, P., Grüne, M. & Wü rthner, F. Fluorescent supramolecular polymers: metal directed self-assembly of perylene bisimide building blocks. Macromolecules 38, 1315-1325 (2005). (Pubitemid 40324815)
10. Burnworth, M., Mendez, J. D., Schroeter, M., Rowan, S. J. & Weder, C. Decoupling optical properties in metallo-supramolecular Poly(p-phenylene ethynylene)s. Macromolecules 41, 2157-2163 (2008). (Pubitemid 351489827)
11. Hwang, S. H., Moorefield, C. N., Fronzek, R., Lukoyanova, O., Echegoyen, L. & Newkome, G. R. Construction of triangular metallomacrocycles: [M3(1,2- bis(2,2′:6′,2′-terpyridin-4yl-ethynyl) benzene)3][M=Ru (II), Fe(II), 2Ru(II)Fe(II)]. Chem. Commun. 6, 713-715 (2005).
12. Dobrawa, R. & Wü rthner, F. Photoluminescent supramolecular polymers: metal-ion directed polymerization of terpyridine-functionalized perylene bisimide dyes. Chem. Commun. 17, 1878-1879 (2002). (Pubitemid 36138986)
13. Knapton, D., Rowan, S. J. & Weder, C. Synthesis and properties of metallo-supramolecular Poly(p-phenylene ethynylene)s. Macromolecules 39, 651-657 (2006) and references cited therein. (Pubitemid 43168250)
14. Han, F. S., Higuchi, M. & Kurth, D. G. Metallosupramolecular polyelectrolytes selfassembled from various pyridine ring-substituted bisterpyridines and metal ions: photophysical, electrochemical, and electrochromic properties. J. Am. Chem. Soc. 130, 2073-2081 (2008). (Pubitemid 351238658)
15. Pal, R. R., Higuchi, M. & Kurth, D. G. Optically active metallo-supramolecular polymers derived from chiral bis-terpyridines. Org. Lett. 11, 3562-3565 (2009).
16. Maestri, M., Armaroli, N., Balzani, V., Constable, E. C. & Thompson, A.M.W.C. Complexes of the ruthenium (II)- 2,2′:6′,2′′- terpyridine family. effect of electronaccepting and-donating substituents on the photophysical and electrochemical properties. Inorg. Chem. 34, 2759-2767 (1995).
17. Han, F. S., Higuchi, M., Ikeda, T., Negishi, Y., Tsukuda, T. & Kurth, D. G. Luminescence properties of metallo-supramolecular coordination polymers assembled from pyridine ring functionalized Ditopic Bis-terpyridines and Ru(II) Ion. J. Mater. Chem. 18, 4555-4560 (2008).
18. Gosh, P., Bharadwaj, P. K., Roy, J. & Ghosh, S. Transition metal (II)/(III), Eu(III), and Tb(III) ions induced molecular photonic or gates using trianthryl cryptands of varying cavity dimension. J. Am. Chem. Soc. 119, 11903-11909 (1997) and references cited therein. (Pubitemid 28012753)
19. Yu, S. C., Kwok, C. C., Chan, W. K. & Che, C. M. Self-assembled electroluminescent polymers derived from terpyridine-based moieties. Adv. Mater. 15, 1643-1647 (2003).
20. Vasquez, J. M., Vu, A., Schultz, J. S. & Vullev, V. I. Fluorescence enhancement of warfarin induced by interaction with b-cyclodextrin. Biotechnol. Prog. 25, 906-914 (2009).