Decoupling optical properties in metallo-supramolecular poly(p-phenylene ethynylene)s

Macromolecules

Volumn 41, Issue 6, 2008, Pages 2157-2163

  Burnworth, Mark ^a   Mendez, James D ^a   Schroeter, Michael ^a,c   Rowan, Stuart J ^a,b   Weder, Christoph ^a,b  

^a Case Western Reserve University   (United States)

^b CASE WESTERN RESERVE UNIVERSITY   (United States)

^c INSTITUTE OF MATERIALS RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

METAL-LIGAND BINDING; SUPRAMOLECULAR POLYMERS;

LIGANDS; MOLECULAR WEIGHT; POLYMERIZATION; POLYPHENYLENE OXIDES;

ORGANOMETALLICS;

EID: 41749087816     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma702712e     Document Type: Article

References (45)

1. For recent reviews see: (a) Lohmeijer, B. G. G.; Schubert, U. S. J. Polym. Sci., Part A: Polym. Chem. 2003, 47, 1413.
2. (b) Dobrawa, R.; Würthner, F. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 4981-4995.
3. (c) Holliday, B. J.; Swager, T. M. Chem. Commun. 2005, 23.
4. (d) Friese, V. A.; Kurth, D. G. Coord. Chem. Rev. 2008, 252, 199.
5. (a) Iyer, P. K.; Beck, J. B.; Weder, C.; Rowan, S. J. Chem. Commun. 2005, 319.
6. (b) Knapton, D.; Burnworth, M.; Rowan, S. J.; Weder, C. Angew. Chem., Int. Ed. 2006, 45, 5825.
7. (c) Burnworth, M.; Rowan, S. J.; Weder, C. Chem. - Eur. J. 2007, 13, 7828.
8. (a) Knapton, D.; Rowan, S. J.; Weder, C. Macromolecules 2006, 39, 651.
9. (b) Burnworth, M.; Knapton, D.; Rowan, S. J.; Weder, C. J. Inorg. Organomet. Polym. Mater. 2007, 17, 40, 91.
10. Voskerician, G.; Weder, C. Adv. Polym. Sci. 2005, 177, 209.
11. (a) Beck, J. B.; Rowan, S. J. J. Am. Chem. Soc. 2003, 125, 13922.
12. (b) Zhao, Y.; Beck, J. B.; Rowan, S. J.; Jamieson, A. M. Macromolecules 2004, 37, 3529.
13. (c) Rowan, S. J.; Beck, J. B. Faraday Discuss. 2005, 128, 43.
14. (d) Beck, J. B.; Ineman, J. M.; Rowan, S. J. Macromolecules 2005, 38, 5060.
15. (e) Knapton, D.; Rowan, S. J.; Weder, C. Macromolecules 2006, 39, 4069.
16. (f) Weng, W.; Beck, J. B.; Jamieson, A. M.; Rowan, S. J. J. Am. Chem. Soc. 2006, 128, 11663.
17. (g) Weng, W.; Jamieson, A. M.; Rowan, S. J. Tetrahedron 2007, 63, 7419.
18. (a) Huber, C.; Bangerter, F.; Caseri, W.; Weder, C. J. Am. Chem. Soc. 2001, 123, 3857.
19. (b) Kokil, A.; Shiyanovskaya, I.; Singer, K. D.; Weder, C. J. Am. Chem. Soc. 2002, 124, 9978.
20. (c) Kokil, A.; Huber, C.; Caseri, W.; Weder, C. Macromol. Chem. Phys. 2003, 204, 40.
21. (d) Kokil, A.; Yao, P.; Weder, C. Macromolecules 2005, 38, 3800.
22. (e) Weder, C. Chem. Commun. 2005, 5378.
23. (f) Weder, C. J. Inorg. Organomet. Polym. Mater. 2006, 16, 1.
24. See for example: (a) Encinas, S.; Flamigni, L.; Barigelletti, F.; Constable, E. C.; Housecroft, C. E.; Schofield, E.; Figgemeier, E.; Fenske, D.; Neuburger, M.; Vos, J. G.; Zehnder, M. Chem. - Eur. J. 2002, 8, 137.
25. (b) Dobrawa, R.; Lysetska, M.; Ballester, P.; Grüne, M.; Würthner, F. Macromolecules 2005, 38, 1315.
26. (c) Chen, Y.-Y.; Tao, Y.-T.; Lin, H.-C. Macromolecules 2006, 39, 8559.
27. (d) Gerhardt, W. W.; Zucchero, A. J.; South, C. R.; Bunz, U. H. F.; Weck, M. Chem. - Eur. J. 2007, 13, 4467.
28. (e) Han, F. S.; Higuchi, M.; Kurth, D. G. Adv. Mater. 2007, 19, 3928.
29. (a) Weder, C.; Wrighton, M. S. Macromolecules 1996, 29, 5157.
30. (b) Dellsperger, S.; Dötz, F.; Smith, P.; Weder, C. Macromol. Chem. Phys. 2000, 201, 192.
31. (a) Halkyard, C. E.; Rampey, M. E.; Kloppenburg, L.; Studer-Martinez, S. L.; Bunz, U. H. F. Macromolecules 1998, 31, 8655.
32. (b) Levitus, M.; Schmieder, K.; Ricks, H.; Shimizu. K. D.; Bunz, U. H. F.; Garcia-Garibay, M. A. J. Am. Chem. Soc. 2001, 123, 4259.
33. Li, H.; Powell, D. R.; Hayashi, R. K.; West, R. Macromolecules 1998, 31, 52.
34. Jaeger, F. M.; van Dijk, J. A. Z Anorg. Chem. 1938, 227, 273.
35. Dobrawa, R.; Wuerthner, F. Chem. Commun. 2002, 1878.
36. n, was a time-consuming process, and direct processing of the original metallopolymer solution is clearly a sensible alternative. However, we found it convenient to first prepare and store this metallopolymer in a solid form, of which portions could be employed for the various processing experiments described.
37. (a) Zhou, Q.; Swager, T. M. J. Am. Chem. Soc. 1995, 117, 12593.
38. (b) Swager, T. M. Acc. Chem. Res. 1998, 31, 201.
39. Krumholz, P. Inorg. Chem. 1965, 4, 612.
40. El-ghayoury, A.; Schenning, A. P. H. J.; Meijer, E. W. J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 4020.
41. Note that the changes on the high-energy end of the spectrum also reflect increasing internal absorption for thicker samples.
42. (a) Montali, A.; Smith, P.; Weder, C. Synth. Met. 1998, 97, 123.
43. (b) Schmitz, C.; Pösch, P.; Thelakkat, M.; Schmidt, H.-W.; Montali, A.; Feldman, K.; Smith, P.; Weder, C. Adv. Fund Mater. 2001, 11, 41.
44. Steiger, D.; Smith, P.; Weder, C. Macromol. Rapid Commun. 1997, 18, 643.
45. To unequivocally exclude experimental errors, the previously reported materials were resynthesized and remeasured and the mechanical data reported in ref 2 were confirmed.