-
4
-
-
0000753474
-
-
JAPIAU 0021-8979 10.1063/1.1324703
-
D. Manno, G. Micocci, A. Serra, M. Di Giulio, and A. Tepore, J. Appl. Phys. JAPIAU 0021-8979 10.1063/1.1324703 88, 6571 (2000).
-
(2000)
J. Appl. Phys.
, vol.88
, pp. 6571
-
-
Manno, D.1
Micocci, G.2
Serra, A.3
Di Giulio, M.4
Tepore, A.5
-
5
-
-
0020113054
-
-
JAPIAU 0021-8979 10.1063/1.331079
-
T. Oyabu, J. Appl. Phys. JAPIAU 0021-8979 10.1063/1.331079 53, 2785 (1982).
-
(1982)
J. Appl. Phys.
, vol.53
, pp. 2785
-
-
Oyabu, T.1
-
6
-
-
0003350952
-
-
PTRMAD 0962-8428 10.1098/rsta.1904.0024
-
J. C. M. Garnett, Philos. Trans. R. Soc. London PTRMAD 0962-8428 10.1098/rsta.1904.0024 203, 385 (1904).
-
(1904)
Philos. Trans. R. Soc. London
, vol.203
, pp. 385
-
-
Garnett, J.C.M.1
-
7
-
-
84980703555
-
-
ANPYA2 0003-3804 10.1002/and19354160705
-
D. A. G. Bruggemann, Ann. Phys. ANPYA2 0003-3804 10.1002/andp.19354160705 24, 636 (1935).
-
(1935)
Ann. Phys.
, vol.24
, pp. 636
-
-
Bruggemann, D.A.G.1
-
8
-
-
5244347502
-
-
JAPIAU 0021-8979 10.1063/1.1702301
-
R. Landauer, J. Appl. Phys. JAPIAU 0021-8979 10.1063/1.1702301 23, 779 (1952).
-
(1952)
J. Appl. Phys.
, vol.23
, pp. 779
-
-
Landauer, R.1
-
10
-
-
0031673284
-
-
SUMIEK 0749-6036 10.1006/spmi.1997.0524
-
D. Stroud, Superlattices Microstruct. SUMIEK 0749-6036 10.1006/spmi.1997.0524 23, 567 (1998).
-
(1998)
Superlattices Microstruct.
, vol.23
, pp. 567
-
-
Stroud, D.1
-
11
-
-
35949020523
-
-
PRBMDO 0163-1829 10.1103/PhysRevB.25.3199
-
J. Garner and D. Stroud, Phys. Rev. B PRBMDO 0163-1829 10.1103/PhysRevB.25.3199 25, 3199 (1982).
-
(1982)
Phys. Rev. B
, vol.25
, pp. 3199
-
-
Garner, J.1
Stroud, D.2
-
12
-
-
75449104996
-
-
2nd ed., edited by J. D. Jackson (Wiley, New York)
-
Classical Electrodynamics, 2nd ed., edited by J. D. Jackson (Wiley, New York, 1975), p. 155.
-
(1975)
Classical Electrodynamics
, pp. 155
-
-
-
13
-
-
4043158815
-
-
Irving Langmuir was one of the pioneers in studies of gas adsorption on solid surfaces. See, JACSAT 0002-7863 10.1021/ja02268a002
-
Irving Langmuir was one of the pioneers in studies of gas adsorption on solid surfaces. See I. Langmuir and D. S. Villars, J. Am. Chem. Soc. JACSAT 0002-7863 10.1021/ja02268a002 38, 2221 (1916).
-
(1916)
J. Am. Chem. Soc.
, vol.38
, pp. 2221
-
-
Langmuir, I.1
Villars, D.S.2
-
14
-
-
84893322637
-
-
In light of Langmuir's work, which is summarized in Physical Chemistry, 2nd ed., edited by Gilbert W. Castellan (Addison-Wesley, Reading, 1971), p. 436. It is reasonable to believe that in the approach to equilibrium, the transient adsorption process obeys d θ / d t = k a P A (1-θ) ≡ α (1-θ), where P is the gas pressure, A is the area of the solid surface or in our case, the area of the exposed thin film surface, t is time, k a is the temperature-dependent adsorption constant, and θ is related to our function p (t), by θ (t) = 1-p (t). That is, θ is the area fraction of the gas. Integration gives, p (t) = e-α t, where α = k a P A. Others have also used exponentials for the time dependence of the adsorbed gas area fractions. See Adsorption: Theory, Modeling, and Analysis, edited by Jozsef Toth (Marcel Dekker, New York, 2002).
-
(1971)
Physical Chemistry, Adsorption: Theory, Modeling, and Analysis
, pp. 436
-
-
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