Efficient hydrogen supply through catalytic dehydrogenation of methylcyclohexane over Pt/metal oxide catalysts

International Journal of Hydrogen Energy

Volumn 35, Issue 9, 2010, Pages 4020-4026

  Shukla, Anshu A ^a   Gosavi, Priti V ^a   Pande, Jayshri V ^a   Kumar, Vanama P ^b   Chary, Komandur V R ^b   Biniwale, Rajesh B ^a  

^a NATIONAL ENVIRONMENTAL ENGINEERING RESEARCH INSTITUTE   (India)

^b INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Dehydrogenation; Hydrogen delivery; Methylcyclohexane; Perovskite; Pt over metal oxide; Pulse spray reactor

Indexed keywords

HYDROGEN DELIVERY; METAL OXIDES; METHYLCYCLOHEXANE; PULSE SPRAY REACTOR; SPRAY REACTOR;

CATALYST ACTIVITY; CATALYST SELECTIVITY; CHEMISORPTION; DEHYDROGENATION; ENERGY DISPERSIVE X RAY ANALYSIS; HYDROGEN; METALLIC COMPOUNDS; OXIDE MINERALS; PEROVSKITE; PLATINUM; SCANNING ELECTRON MICROSCOPY; X RAY DIFFRACTION;

CATALYST SUPPORTS;

EID: 77950331572     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.02.014     Document Type: Article

References (21)

1. Ali J.K., Newson E.J., and Rippin D.W.T. Exceeding equilibrium conversion with a catalytic membrane reactor for the dehydrogenation of methylcyclohexane. Chem Eng Sci 13 (1994) 2129-2134
2. Biniwale R.B., Kariya N., and Ichikawa M. Dehydrogenation of cyclohexane over Ni based catalysts supported on activated carbon using spray-pulsed reactor and enhancement in activity by addition of a small amount of Pt. Catal Lett 105 (2005) 83-87
3. Biniwale R.B., Rayalu S., Devotta S., and Ichikawa M. Chemical hydrides: a solution to high capacity hydrogen storage and supply. Int J Hydrogen Energy 33 (2007) 360-365
4. Biniwale R.B., Pande J., Dhakad M., Labhsetwar N., and Ichikawa M. Nitric oxide reduction using hydrogen over perovskite catalysts with promotional effect of platinum on catalytic activity. Catal Lett 123 (2008) 164-171
5. Kobayashi I., Yamamoto K., and Kameyama H. A proposal of a spray pulse operation for liquid film dehydrogenation. Chem Eng Sci 54 (1999) 1319-1323
6. Kariya N., Fukuoka A., and Ichikawa M. Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under "wet-dry multiphase conditions". Appl Catal A Gen 233 (2002) 91-102
7. Kariya N., Fukuoka A., Utagawa T., Sakuramoto M., Goto Y., and Ichikawa M. Efficient hydrogen production using cyclohexane and decalin by pulse spray mode reactor with Pt catalysts. Appl Catal A Gen 247 (2003) 247-259
8. Hodoshima S., Arai H., and Saito Y. Liquid film type catalytic decalin dehydrogenation-aromatization for long-term storage and long distance transportation of hydrogen. Int J Hydrogen Energy 28 (2003) 197-204
9. Hodoshima S., Arai H., Takaiwa S., and Saito Y. Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle. Int J Hydrogen Energy 28 (2003) 1255-1262
10. Hodoshima S., Nagata H., and Saito Y. Efficient hydrogen supply from tetralin with superheated liquid-film-type catalysis for operating fuel cells. Appl Catal A Gen 292 (2005) 90-96
11. Rao G.R. Influence of metal particles on reduction properties of ceria-based materials studied by TPR. Bull Mater Sci 22 (1999) 89-94
12. Pena M.A., and Fierro J.L.G. Chemical structures and performance of perovskite oxides. Chem Rev 101 (2000) 1981-2017
13. Levin M.E., Salmeron M., Bell A.T., and Somarjai G.A. The characterization of Ti and Al oxide overlayers on rhodium and gold by XPS. Surf Sci 195 (1988) 429-442
14. Levin M.E., Williams K.J., Salmeron M., Bell A.T., and Somarjai G.A. Alumina and titania overlayers on rhodium: a comparison of the chemisorption catalytic properties. Surf Sci 195 (1988) 341-351
15. 2 as a fuel for automobiles. Adv Hydrogen Energy 2 (1981) 1077-1082
16. 3 catalysts and their activity in dehydrogenation of methylcyclohexane for hydrogen production. Catal Today 138 (2008) 198-202
17. 3 perovskite as precursor for methane reforming reactions catalysts. Appl Catal B Environ 93 (2010) 346-353
18. Sha X., Knippenberg M.T., Cooper A.C., Pez G.P., and Cheng H. Dynamics of hydrogen spillover on carbon based material. J Phys Chem C Nanomater Interfaces 112 (2008) 17465-17470
19. Okada Y., Sasaki E., Watanabe E., Hyodo S., and Nishijima H. Development of dehydrogenation catalyst for hydrogen generation in organic chemical hydride method. Int J Hydrogen Energy 31 (2006) 1348-1356
20. 3 composite film for ferroelectric film devices. Acta Mater 57 (2009) 4109-4114
21. Gates B.C., Katzer J.R., and Schuit G.C.A. Chemistry of catalytic processes (1979), McGraw-Hill Inc, New York p. 264-75