Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle

International Journal of Hydrogen Energy

Volumn 28, Issue 11, 2003, Pages 1255-1262

  Hodoshima, Shinya ^a   Arai, Hiroshi ^a   Takaiwa, Shigeki ^a   Saito, Yasukazu ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Carbon supported platinum based fine particles; Decalin dehydrogenation naphthalene hydrogenation pair; Hydrogen source for fuel cell vehicle; Liquid film state; Reactive distillation

Indexed keywords

CATALYSTS; DEHYDROGENATION; DISTILLATION; FUEL CELLS; HYDROGENATION; NAPHTHALENE;

LIQUID-FILM STATE;

HYDROGEN;

EID: 0038452607     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0360-3199(02)00250-1     Document Type: Article

References (23)

1. Brown L.F. A comparative study of fuels for on-board hydrogen production for fuel-cell-powered automobiles. Int J Hydrogen Energy. 26:2001;381-397.
2. Liu C., Fan Y.Y., Liu M., Cong H.T., Cheng H.M., Dresselhaus M.S. Hydrogen storage in single-walled carbon nanotubes at room temperature. Science. 286:1999;1127-1129.
3. Benard P., Chahine R. Modeling of adsorption storage of hydrogen on activated carbon. Int J Hydrogen Energy. 26:2001;849-855.
4. Gupta B.K., Srivastava O.N. Further studies on microstructural characterization and hydrogenation behavior of graphitic nanofibres. Int J Hydrogen Energy. 26:2001;857-862.
5. Liu C., Sakaguchi M., Saito Y. Long-term storage and long-distance transportation of hydrogen by use of catalyst-assisted decalin dehydrogenation/naphthalene hydrogenation pair. J Hydrogen Energy Systems Soc Jpn. 22(1):1997;27-32.
6. Hodoshima S., Saito Y. Characteristics of decalin dehydrogeno-aromatization catalyst driven by waste heats for long-term storage and long-distance transportation of hydrogen. J Hydrogen Energy Systems Soc Jpn. 24(1):1999;13-18.
7. Hodoshima S., Saito Y. Long-term storage and long-distance transportation of hydrogen by use of liquid organic compounds. J Hydrogen Energy Systems Soc Jpn. 25(2):2000;36-43.
8. Hodoshima S., Arai H., Saito Y. Liquid-film-type catalytic decalin dehydrogeno-aromatization for long-term storage and long-distance transportation of hydrogen. Int J Hydrogen Energy. 28:2003;197-204.
9. Weitkamp A.W. Stereochemistry and mechanism of hydrogenation of naphthalene on transition metal catalysts and conformational analysis of the products. Adv Catal. 18:1968;1-110.
10. Stull OR, Westrum Jr EF, Sinke GC. The chemical thermodynamics of organic compounds. New York: Wiley, 1969. p. 15-20.
11. Newson E, Truong TB, Hottinger P, Roth FV, Schucan THH. Optimization of seasonal energy storage in stationary systems with liquid hydrogen carriers, decalin and methylcyclohexane. Proceedings of the 12th World Hydrogen Energy Conference, Buenos Aires, Argentina, 1998. p. 935-42.
12. Loutfy RO, Veksler EM. Investigation of hydrogen storage in liquid organic hydrides. Proceedings of the International Hydrogen Energy Forum 2000, Munich, Germany, 2000. p. 335-40.
13. Meng N., Shinoda S., Saito Y. Improvements on thermal efficiency of chemical heat pump involving the reaction couple of 2-propanol dehydrogenation and acetone hydrogenation. Int J Hydrogen Energy. 22:1997;361-367.
14. Agreda V.H., Partin L.R., Heise W.H. High-purity methyl acetate via reactive distillation. Chem Eng Progr. 86:1990;40-46.
15. Otowa T. Development and application of high surface area activated carbon. Hyoumen (Surface). 34(2):1996;62-65.
16. Hodoshima S., Kubono T., Asano S., Arai H., Saito Y. Preparation of nanosize bimetallic particles on activated carbon. Stud Surf Sci Catal. 132:2001;323-326.
17. Arai H, Takaiwa S, Asano S, Hodoshima S, Saito Y. Characteristics of decalin dehydrogenation catalyst for hydrogen/air fuel cell vehicle. Proceedings of the 17th Energy System Economy Environment Conference, Tokyo, Japan, 2001:377-82.
18. Nakabayashi M, Yamashita M, Saito Y. Preparation of size-controlled ruthenium metal particles on carbon from hydro-carbonyl cluster complex. Chem Lett 1994:1275-8.
19. Mears D.E., Boudart M. The dehydrogenation of isopropanol on catalysts prepared by sodium borohydride reduction. AIChE Journal. 12:1966;313-321.
20. Meng N., Ando Y., Shinoda S., Saito Y. A deuterium-labeling study on the dehydrogenation of 2-propanol with Ru-Pt/carbon catalyst in the liquid-film state effective for the 2-propanol/acetone/hydrogen chemical heat-pump system. Bull Chem Soc Jpn. 72:1999;669-672.
21. Kawaguchi M., Nunome A., Saito Y. Synergetic effect of iridium cluster complex and platinum metal particle on dehydrogenation of alkane and alcohol. Catal catal. 42(6):2000;454-456.
22. Heidrich A, Jakob M. Heat transfer, Vol 1. New York: Wiley, 1957. p. 618.
23. Appleby A.J. The electrochemical engine for vehicles. Sci Am. 281(1):1999;74-79.