|
Volumn 39, Issue 15, 2010, Pages 3595-3608
|
Tuning the reactivity of chelated dinuclear Pt(II) complexes through a flexible diamine linker. A detailed kinetic and mechanistic study
|
Author keywords
[No Author keywords available]
|
Indexed keywords
ACTIVATION ENTROPIES;
ANIONIC NUCLEOPHILES;
AQUA LIGANDS;
CAGE EFFECT;
CONCOMITANT DECREASE;
DETAILED KINETICS;
DIMETHYLTHIOUREA;
DINUCLEAR;
DISPLACEMENT REACTIONS;
ELECTROSTATIC INTERACTIONS;
FIRST-ORDER CONDITIONS;
FIRST-ORDER RATE CONSTANTS;
HIGH REACTIVITY;
IN-LINE;
INDUCTIVE EFFECTS;
MECHANISTIC STUDIES;
PYRIDYL;
RATE LAWS;
RETARDATION EFFECT;
SECOND ORDER KINETICS;
STERIC INFLUENCE;
STOPPED-FLOW TECHNIQUES;
TETRAKIS;
TETRAMETHYLTHIOUREA;
UV-VISIBLE SPECTROPHOTOMETRY;
CHAIN LENGTH;
CHELATION;
COMPLEXATION;
DYES;
LIGANDS;
MODEL STRUCTURES;
NUCLEOPHILES;
OPTICAL SWITCHES;
PLATINUM;
RATE CONSTANTS;
SUBSTITUTION REACTIONS;
THIOUREAS;
UREA;
PLATINUM COMPOUNDS;
CHELATING AGENT;
COORDINATION COMPOUND;
DIAMINE;
DRUG DERIVATIVE;
LIGAND;
PLATINUM;
TETRAMETHYLTHIOUREA;
THIOUREA;
ARTICLE;
CHEMISTRY;
CONFORMATION;
KINETICS;
SYNTHESIS;
ULTRAVIOLET SPECTROPHOTOMETRY;
CHELATING AGENTS;
COORDINATION COMPLEXES;
DIAMINES;
KINETICS;
LIGANDS;
MOLECULAR CONFORMATION;
PLATINUM;
SPECTROPHOTOMETRY, ULTRAVIOLET;
THIOUREA;
|
EID: 77950274545
PISSN: 14779226
EISSN: 14779234
Source Type: Journal
DOI: 10.1039/b921687a Document Type: Article |
Times cited : (39)
|
References (58)
|