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Specifically, 2,6-bis-(2-bromophenyl)-4-phenyl pyrylium salts were condensed with sodium phenyl acetate and the resulting tetraphenylbenzenes Pd(0)-catalyzed dehydrohalogenated.
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50
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The product ratio of phenyl dibenzonaphthacenes to diphenyl triphenylenes depends on the catalyst and on the specific substituents attached to the molecules.
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Independent from our work, the application of aryl-substituted aromatics, including triphenylenes, in electroluminescent devices has been described in the patent literature, e.g. H.-N. Cho, S.H. Jung, S.-J. Park, S.-E. Lee, US Patent 2005067955, 2005
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Independent from our work, the application of aryl-substituted aromatics, including triphenylenes, in electroluminescent devices has been described in the patent literature.; e.g. H.-N. Cho, S.H. Jung, S.-J. Park, S.-E. Lee, US Patent 2005067955, 2005.
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Independent from our work, the application of aryl-substituted aromatics, including triphenylenes, in electroluminescent devices has been described in the patent literature, e.g. T. Schäfer, K. Müllen, M.G.R. Turbiez, M. Baumgarten, WO Patent 2008012250, 2008
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Independent from our work, the application of aryl-substituted aromatics, including triphenylenes, in electroluminescent devices has been described in the patent literature.; e.g. T. Schäfer, K. Müllen, M.G.R. Turbiez, M. Baumgarten, WO Patent 2008012250, 2008.
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Specifically, when triphenylpyrylium salts are treated with sodium 2-bromo phenylacetate, the intermediate 1-(2-bromophenyl)-2,4,6-triphenyl benzene can be isolated and Pd(0)-catalyzed dehydrobromination gives 1,3-diphenyl triphenylene. However, the purification process decreases the isolated amount of pure material so that this approach can not compete with the synthetic strategy described here.
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