Chelation versus binudeation: Metal complex formation with the hexadentate all-cis-N1,N1-bis(2,4,6-trihydroxy-3,5-diaminocyclohexyl) ethane-l,2-diamine

Chemistry - A European Journal

Volumn 16, Issue 11, 2010, Pages 3326-3340

  Bartholomä, Mark ^a   Gisbrecht, Sergej ^a   Stucky, Stefan ^a   Neis, Christian ^a   Morgenstern, Bernd ^a   Hegetschweiler, Kaspar ^a  

^a SAARLAND UNIVERSITY   (Germany)

Author keywords

Amino alcohols; Bridging ligands; Chelates; Coordination modes; N,O ligands

Indexed keywords

ALCOHOLS; AMINES; CHELATION; CYCLIC VOLTAMMETRY; ETHANE; GALLIUM; ISOMERS; MANGANESE; MANGANESE COMPOUNDS; METAL COMPLEXES; PROTONATION; TITRATION; ZINC;

AMINO ALCOHOLS; AMINO GROUP; AQUEOUS SOLUTIONS; BRIDGING LIGANDS; CHAIN STRUCTURE; COMPLEX 1; COORDINATION MODES; EQUILIBRIUM SYSTEMS; FORMATION CONSTANTS; HEXADENTATE; HYDROXY GROUPS; METAL BINDING; METAL COMPLEX FORMATION; MOLECULAR FRAMEWORKS; MOLECULAR MECHANICS CALCULATIONS; N ,O LIGANDS; NUMBER OF SPECIES; PROTONATED; REDOX POTENTIALS; SPECTROPHOTOMETRIC TITRATIONS; STARTING MATERIALS; STERIC STRAINS;

LIGANDS;

CHELATING AGENT; COORDINATION COMPOUND; CYCLOHEXANE DERIVATIVE; DIAMINE; N1,N2 BIS(2,4,6 TRIHYDROXY 3,5 DIAMINOCYCLOHEXYL)ETHANE 1,2 DIAMINE; N1,N2-BIS(2,4,6-TRIHYDROXY-3,5-DIAMINOCYCLOHEXYL)ETHANE-1,2-DIAMINE;

ARTICLE; CHEMISTRY; CONFORMATION; HYDROGEN BOND; OXIDATION REDUCTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CHELATING AGENTS; CHEMICAL SYNTHESIS; CHEMISTRY; COORDINATION COMPLEXES; CRYSTALLOGRAPHY, X-RAY; CYCLOHEXANES; DIAMINES; HYDROGEN BONDING; MOLECULAR CONFORMATION; OXIDATION-REDUCTION;

EID: 77949311597     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902552     Document Type: Article

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