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Volumn , Issue 14, 2006, Pages 2792-2807

The reactivity of hexa(N-methylideneimine)CoIII complexes towards nucleophiles: Structure and mechanism

Author keywords

Chelates; Cobalt; Hydrogen transfer; N ligands; Nucleophilic addition

Indexed keywords

ADDITION REACTIONS; ALKYLATION; ANILINE; COBALT COMPOUNDS; CRYSTAL STRUCTURE; CYANIDES; HYDRIDES; HYDROGEN; ISOMERS; SPECTROSCOPIC ANALYSIS;

EID: 33746210185     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200501120     Document Type: Article
Times cited : (7)

References (63)
  • 19
    • 85153234137 scopus 로고    scopus 로고
    • note
    • e = (1Z)-N′-(all-cis-3,5-diamino-2,4,6-trihydroxycyclohexyl)- 2-[all-cis-(3,5-diamino-2,4,6-trihydroxycyclohexyl)amino]ethanimidamide.
  • 20
    • 85153188477 scopus 로고    scopus 로고
    • note
    • [16]
  • 26
    • 85153290105 scopus 로고    scopus 로고
    • note
    • 3+, this value is somewhat lower apparently due to a γ effect caused by the non-hydrogen substituents attached to the neighbouring nitrogen donors. The 2D NMR experiments confirmed our proposition that it is the high-frequency cyclohexane-carbon atom at δ = 76-80 ppm which is directly bonded to the coordinated oxygen donor.
  • 38
    • 85153321441 scopus 로고    scopus 로고
    • note
    • [31] to 1.9854(18) Å - 2.0057(18) Å (mean value 1.994 Å).
  • 40
    • 85153247299 scopus 로고    scopus 로고
    • note
    • [33]
  • 56
    • 85153314961 scopus 로고    scopus 로고
    • 2O have been deposited with The Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-293087 and -293088. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.