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85153234137
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note
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e = (1Z)-N′-(all-cis-3,5-diamino-2,4,6-trihydroxycyclohexyl)- 2-[all-cis-(3,5-diamino-2,4,6-trihydroxycyclohexyl)amino]ethanimidamide.
-
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20
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85153188477
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[16]
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85153290105
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note
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3+, this value is somewhat lower apparently due to a γ effect caused by the non-hydrogen substituents attached to the neighbouring nitrogen donors. The 2D NMR experiments confirmed our proposition that it is the high-frequency cyclohexane-carbon atom at δ = 76-80 ppm which is directly bonded to the coordinated oxygen donor.
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0000469070
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85153321441
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note
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[31] to 1.9854(18) Å - 2.0057(18) Å (mean value 1.994 Å).
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2O have been deposited with The Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-293087 and -293088. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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