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Actually, the Le Chatelier principle also predicts that β-CD will form more complexes with the surfactant at a higher concentration. According to this principle, one might intuitively expect the difference to be similar to the difference in concentrations of the two surfactants. In the present case (SDS/DEAB 15/5 mM), it was found that the selectivity of β-CD to SDS over that to DEAB is ∼100:1, much larger than the ratio of concentrations of SDS and DEAB, 3:1. Therefore, the interplay between the host-guest and biased aggregation equilibria is within the frame of the Le Chatelier principle, yet they are not exactly the same. In addition, the present thermodynamic model can predict the exact value of the selectivity, whereas the Le Chatelier principle cannot.
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56
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85067763033
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Recently, it has been established that β-CD can form aggregates with diameters ∼200 nm above 3 mM by itself; see
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Recently, it has been established that β-CD can form aggregates with diameters ∼200 nm above 3 mM by itself; see:
-
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(a) Bonini, M.; Rossi, S.; Karlsson, G.; Almgren, M.; Nostra, P. L.; Baglioni, P. Innemuir 2006, 22, 1478.
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and references thereinHowever, in the present case of SDS/DEAB/β-CD solutions, most ofβ-CD will form complexes with SDS or DEAB, and the complexes will not aggregate, as evidenced by the diffusion coefficient of the complexes (measured by PGSE-NMR)
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(b) Rossi, S.; Bonini, M. Nostra, P. L.; Baglioni, P. Langmuir 2007, 23, 10959, and references thereinHowever, in the present case of SDS/DEAB/β-CD solutions, most ofβ-CD will form complexes with SDS or DEAB, and the complexes will not aggregate, as evidenced by the diffusion coefficient of the complexes (measured by PGSE-NMR).
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