Expanding dinitrogen reduction chemistry to trivalent lanthanides via the LnZ3/alkali metal reduction system: Evaluation of the generality of forming Ln2(μ-η2:η2-N2) complexes via LnZ3/K

Journal of the American Chemical Society

Volumn 126, Issue 44, 2004, Pages 14574-14582

  Evans, William J ^a   Lee, David S ^a   Rego, Daniel B ^a   Perotti, Jeremy M ^a   Kozimor, Stosh A ^a   Moore, Ericka K ^a   Ziller, Joseph W ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METALS; METAL ANALYSIS; OXIDATION; POTASSIUM; SODIUM; URANIUM;

DINITROGEN REDUCTION; REDUCTION CHEMISTRY;

NITROGEN;

ALKALI METAL; AMIDE; DYSPROSIUM; ERBIUM; GADOLINIUM; HOLMIUM; LUTETIUM; NEODYMIUM; POTASSIUM; SODIUM; TETRAKIS[BIS(TRIMETHYLSILYL)]AMIDE; THULIUM; UNCLASSIFIED DRUG; YTTRIUM;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; COMPLEX FORMATION; CORRELATION ANALYSIS; CRYSTALLOGRAPHY; EVALUATION; METAL BINDING; OXIDATION; REACTION ANALYSIS; REDUCTION KINETICS; SOLVATION;

EID: 7744235051     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046047s     Document Type: Article

References (79)

1. MacKay, B. A.; Fryzuk, M. D. Chem. Rev. 2004, 104, 385-401.
2. Yandulov, D. V.; Schrock, R. R. Science 2003, 301, 76-78.
3. Peters, J. C.; Cherry, J. P. F.; Thomas, J. C.; Baraldo, L.; Mindiola, D. J.; Davis, W. M.; Cummins, C. C. J. Am. Chem. Soc. 1999, 121, 10053-10067.
4. Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2003, 42, 4958-4961.
5. Pool, J. A.; Lobkovsky, E.; Chirik, P. J. Nature 2004, 427, 527-530.
6. Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 10782-10783.
7. Evans, W. J.; Lee, D. S.; Ziller, J. W. J. Am. Chem. Soc. 2004, 126, 454-455.
8. Bradley, D. C.; Ghotra, J. S.; Hart, F. A. J. Chem. Soc., Dalton Trans. 1973, 1021-1023.
9. Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877-6879.
10. Fryzuk, M. D.; Love, J. B.; Rettig, S. J.; Young, V. G. Science 1997, 275, 1445-1447.
11. Guan, J.; Dube, T.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 4820-4827.
12. Campazzi, E.; Solari, E.; Floriani, C.; Scopelliti, R. Chem. Commun. 1998, 2603-2604.
13. Evans, W. J. J. Organomet. Chem. 2002, 652, 61-68.
14. Bochkarev, M. N.; Fedushkin, I. L.; Fagin, A. A.; Petrovskaya, T. V.; Ziller, J. W.; Broomhall-Dillard, R. N. R.; Evans, W. J. Angew. Chem., Int. Ed. Engl. 1997, 56, 133-135.
15. Evans, W. J.; Allen, N. T.; Ziller, J. W. J. Am. Chem. Soc. 2000, 122, 11749-11750.
16. Bochkarev, M. N.; Fedushkin, I. L.; Fagin, A. A.; Dechert, S.; Schumann, H. Angew. Chem., Int. Ed. 2001, 40, 3176-3178.
17. Evans, W. J.; Allen, N. T.; Ziller, J. W. J. Am. Chem. Soc. 2001, 723, 7927-7928.
18. Evans, W. J.; Allen, N. T.; Ziller, J. W. Angew. Chem., Int. Ed. 2002, 41, 359-361.
19. Evans, W. J.; Zucchi, G.; Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 10-11.
20. Ganesan, M.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2001, 40, 766-769.
21. Dube, T.; Ganesan, M.; Conoci, S.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 3716-3721.
22. Morss, L. R. Chem. Rev. 1976, 76, 827-841.
23. Meyer, G.; Wickleder, M. S. Handbook on the Physics and Chemistry of Rare Earths 2000, 28, 53-129.
24. Meyer, G.; Morss, L. R., Eds. Synthesis of Lanthanide and Actinide Compounds 1991, 159-173.
25. Evans, W. J. Coord. Chem. Rev. 2000, 206-207, 263-283.
26. Cassani, M. C.; Gun'ko, Y. K.; Hitchcock, P. B.; Hulkes, A. G.; Khvostov, A. V.; Lappert, M. F.; Protchenko, A. V. J. Organomet. Chem. 2002, 647, 71-83.
27. Sanner, R. D.; Manriquez, J. M.; Marsh, R. E.; Bercaw, J. E. J. Am. Chem. Soc. 1976, 98, 8351-8357.
28. O'Donoghue, M. B.; Davis, W. M.; Schrock, R. R.; Reiff, W. M. Inorg. Chem. 1999, 38, 243-252.
29. Fryzuk, M. D.; Love, J. B.; Rettig, S. T. J. Am. Chem. Soc. 1990, 112, 8185-8186.
30. Fryzuk, M. D.; Kozak, C. M.; Bowridge, M. R.; Patrick, B. O.; Rettig, S. J. J. Am. Chem. Soc. 2002, 124, 8389-8397.
31. Evans, W. J.; Davis, B. L. Chem. Rev. 2002, 102, 2119-2136.
32. Cassani, M. C.; Lappert, M. F.; Laschi, F. Chem. Commun. 1997, 1563-1564.
33. Cassani, M. C.; Duncalf, D. J.; Lappert, M. F. J. Am. Chem. Soc. 1998, 120, 12958-12959.
34. Lappert, M. F.; Cassani, M. C.; Gun'ko, Y. K.; Hitchcock, P. B.; Laschi, F. Organometallics 1999, 18, 5539-5547.
35. Lappert, M. F.; Gun'ko, Y. K.; Hitchcock, P. B. Organometallics 2000, 19, 2832-2834.
36. Bergbreiter, D. E.; Killough, J. M. J. Am. Chem. Soc. 1978, 100, 2126-2134.
37. Edelmann, F. T. Synthetic Methods of Organometallic and Inorganic Chemistry 1997, 6, 37-40.
38. Avens, L. R.; Bott, S. G.; Clark, D. L.; Sattelberger, A. P.; Watkin, J. G.; Zwick, B. D. Inorg. Chem. 1994, 33, 2248-2256.
39. Evans, W. J.; Engerer, S. C.; Coleson, K. M. J. Am. Chem. Soc. 1981, 103, 6672-6677.
40. Evans, W. J.; Johnston, M. A.; Clark, R. D.; Anwander, R.; Ziller, J. W. Polyhedron 2001, 20, 2483-2490.
41. SMART Software Users Guide, Version 5.1, Bruker Analytical X-ray Systems, Inc.; Madison, WI 1999.
42. SAINT Software Users Guide, Version 6.34A, Bruker Analytical X-ray Systems, Inc.; Madison, WI 2003.
43. Sheldrick, G. M. SADABS, Version 2.05; Bruker Analytical X-ray Systems, Inc.: Madison, WI 2001.
44. Sheldrick, G. M. SHELXTL Version 6.12; Bruker Analytical X-ray Systems, Inc.: Madison, WI 2001.
45. International Tables for X-ray Crystallography; Kluwer Academic Publishers: Dordrecht, 1992; Vol. C.
46. Caravan, P.; Ellison, J. J.; McMurry, T. J.; Lauffer, R. B. Chem. Rev. 1999, 99, 2293-2352.
47. Adam, J. L. Chem. Rev. 2002, 102, 2461-2476.
48. Kido, J.; Okamoto, Y. Chem. Rev. 2002, 102, 2357-2368.
49. Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070-1071.
50. Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836-5837.
51. Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352-9353.
52. Evans, W. J.; Kozimor, S. A.; Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264-14265.
53. Shannon, R. D. Acta Crystallogr. 1976, A32, 751-767.
54. Burns, C. J.; Clark, D. L.; Donohoe, R. J.; Duval, P. B.; Scott, B. L.; Tait, C. D. Inorg. Chem. 2000, 39, 5464-5468.
55. Dash, A. K.; Razavi, A.; Mortreux, A.; Lehmann, C. W.; Carpentier, J. F. Organometallics 2002, 21, 3238-3249.
56. Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Heitz, W.; Neumuller, B.; Dehnicke, K. Z. Anorg. Allg. Chem. 1999, 625, 1301-1309.
57. Karl, M.; Harms, K.; Dehnicke, K. Z. Anorg. Allg. Chem. 1999, 625, 1774-1776.
58. Nagel, I.; Scherer, W.; Tafipolsky, M.; Anwander, R. Eur. J. Inorg. Chem. 1999, 1405-1407.
59. Lee, L.; Berg, D. J.; Bushnell, G. W. Inorg. Chem. 1994, 33, 5302-5308.
60. Aspinall, H. C.; Tillotson, M. R. Polyhedron 1994, 13, 3229-3234.
61. Evans, W. J.; Anwander, R.; Ziller, J. W.; Khan, S. I. Inorg. Chem. 1995, 34, 5927-5930.
62. Stewart, J. L.; Andersen, R. A. Polyhedron 1998, 17, 953-958.
63. Evans, W. J.; Nyce, G. W.; Forrestal, K. J.; Ziller, J. W. Organometallics 2002, 120, 1050-1055.
64. Andersen, R. A.; Templeton, D. H.; Zalkin, A. Inorg. Chem. 1978, 17, 2317-2319.
65. Bradley, D. C.; Ghotra, J. S.; Hart, F. A.; Hursthouse, M. B.; Raithby, P. R. J. Chem. Soc., Dalton 1977, 1166-1172.
66. Tilley, T. D.; Andersen, R. A.; Zalkin, A. J. Am. Chem. Soc. 1982, 104, 3725-3727.
67. Tilley, T. D.; Andersen, R. A.; Zalkin, A. Inorg. Chem. 1984, 23, 2271-2276.
68. Boncella, J. M.; Andersen, R. A. Organometallics 1985, 4, 205-206.
69. Evans, W. J.; Drummond, D. K.; Zhang, H.; Atwood, J. L. Inorg. Chem. 1988, 27, 575-579.
70. Karl, M.; Harms, K.; Seybert, G.; Massa, W.; Fau, S.; Frenking, G.; Dehnicke, K. Z. Anorg. Allg. Chem. 1999, 625, 2055-2063.
71. Evans, W. J. The Chemistry of the Metal-Carbon Bond 1982, 1, 489-537.
72. Watt, G. W.; Gillow, E. W. J. Am. Chem. Soc. 1969, 91, 775-776.
73. Evans, W. J.; Drummond, D. K.; Zhang, H.; Atwood, J. L. Inorg. Chem. 1988, 27, 575-579.
74. Bond, A. M.; Deacon, G. B.; Newnham, R. H. Organomelallics 1986, 5, 2312-2316.
75. Finke, R. G.; Keenan, S. R.; Schiraldi, D. A. Organometallics 1986, 5, 598-601.
76. Watson, P. L.; Tulip, T. H.; Williams, I. Organometallics 1990, 9, 1999-2009.
77. Lochner, U.; Barnighausen, H.; Corbett, J. D. Inorg. Chem. 1977, 16, 2134-2135.
78. Khoroshenkov, G. V.; Petrovskaya, T. V.; Fedushkin, I. L.; Bochkarev, M. N. Z. Anorg. Allg. Chem. 2002, 628, 699-702.
79. Evans, W. J.; Shreeve, J. L.; Ziller, J. W. Inorg. Chem. 1994, 33, 6435-6437.