Anomalous non-prussian blue structures and magnetic ordering of K 2MnII[MnII(CN)6] and Rb 2MnII[MnII(CN)6]

Inorganic Chemistry

Volumn 49, Issue 4, 2010, Pages 1524-1534

  Her, Jae Hyuk ^b,c   Stephens, Peter W ^b   Kareis, Christopher M ^a   Moore, Joshua G ^a   Min, Kil Sik ^a,d   Park, Jong Won ^a   Bali, Garima ^a   Kennon, Bretni S ^a   Miller, Joel S ^a  

^a UNIVERSITY OF UTAH   (United States)

^b STONY BROOK UNIVERSITY   (United States)

^c GE GLOBAL RESEARCH   (United States)

^d Kyungpook National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77249145968     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic901903f     Document Type: Article

References (64)

1. Verdaguer, M.; Girolami, G. S. In Magnetism-Molecules toMaterials; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, 2005, Vol.5, p 283.
2. Hashimoto, K.; Ohkoshi, S. Phil. Trans. R. Soc. Lond. A 1999, 357, 2977.
3. Verdaguer, M.; Bleuzen, A.; Marvaud, V.; Vaissermann, J.; Seuleiman, M.; Desplanches, C.; Scuiller, A.; Train, C.; Garde, R.; Gelly, G.; Lomenech, C.; Rosenman, I.; Veillet, P.; Cartier, C.; Villain, F. Coord. Chem. Rev. 1999, 190-192, 1023.
4. (a) Ferlay, S.; Mallah, T.; Ouahes, R.; Veillet, P.; Verdaguer, M. Nature 1995, 378, 701
5. (b) Dujardin, E.; Ferlay, S.; Phan, X.; Desplanches, C.; Moulin, C. C. D.; Sainctavit, P.; Baudelet, F.; Dartyge, E.; Veillet, P.; Verdaguer, M. J. Am. Chem. Soc. 1998, 120, 11347
6. (c) Ferlay, S.; Mallah, T.; Ouahes, R.; Veillet, P.; Verdaguer, M. Inorg. Chem. 1999, 38, 229
7. (d) Verdaguer, M.; Bleuzen, A.; Train, C.; Garde, R.; Fabrizi de Biani, F.; Desplanches, C. Phil. Trans. R. Soc. Lond. A 1999, 357, 2959
8. (a) Holmes, S. M.; Girolami, G. S. J. Am. Chem. Soc. 1999, 121, 5593
9. (b) Hatlevik, Oe.; Buschmann, W. E.; Zhang, J.; Manson, J. L.; Miller, J. S. Adv. Mater. 1999, 11, 914
10. (a) Morin, B. G.; Hahm, C.; Epstein, A. J.; Miller, J. S. J. Appl. Phys. 1994, 75, 5782
11. (b) Miller, J. S. Adv. Mater. 1994, 6, 322
12. (c) Landee, C. P.; Melville, D.; Miller, J. S. In NATO ARW Molecular Magnetic Materials; Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds.; Kluwer Academic Publishers: London, 1991, Vol.E198, p 395
13. Prigodin, V. N.; Raju, N. P.; Pokhodnya, K. I.; Miller, J. S.; Epstein, A. J. Adv. Mater. 2002, 14, 1230.
14. (a) Anderson, P. W. Phys. Rev. 1950, 79, 350(a)
15. (b) Goodenough, J. B. J. Phys. Chem. Solids 1958, 6, 287(b)
16. (c) Kanamori, J. J. Phys. Chem. Solids 1959, 10, 87
17. Buschmann, W. E.; Miller, J. S. Inorg. Chem. 2000, 39, 2411.
18. (a) Entley, W. R.; Girolami, S. G. Inorg. Chem. 1994, 33, 5165
19. (b) Entley, W. R.; Girolami, S. G. Inorg. Chem. 1995, 34, 2262
20. Franz, P.; Ambrus, C.; Hauser, A.; Chernyshov, D.; Hostettler, M.; Hauser, J.; Keller, L.; Krämer, K.; Stoeckli-Evans, H.; Pattison, P.; Bürgi, H.-B.; Decurtins, S. J. Am. Chem. Soc. 2004, 126, 16472.
21. Klenze, R.; Kanellakopoulos, B.; Trageser, G.; Eysel, H. H. J. Chem. Phys. 1980, 72, 5819.
22. Qureshi, A. M.; Sharpe, A. G. J. Inorg. Nucl. Chem. 1968, 30, 2269.
23. Dong, W.; Zhu, L.-N.; Song, H.-B.; Liao, D.-Z.; Jiang, Z.-H.; Yan, S.-P.; Cheng, P.; Gao, S. Inorg. Chem. 2004, 43, 2465.
24. Buschmann, W. E.; Ensling, J.; Gütlich, P.; Miller, J. S. Chem.; Eur. J. 1999, 5, 3019.
25. (a) Keggin, J. F.; Miles, F. D. Nature 1936, 137, 577
26. (b) Itaya, K.; Uchida, I.; Neff, V. D. Acc. Chem. Res. 1986, 19, 162
27. Beall, G. W.; Milligan, W. O.; Korp, J.; Bernal, I. Inorg. Chem. 1977, 16, 2715.
28. Mullica, D. F.; Zielke, J. T.; Sappenfield, E. L. J. Sol. State. Chem. 1994, 112, 92.
29. Herren, F.; Fisher, P.; Ludi, A.; Hälg, W. Inorg. Chem. 1980, 19, 956.
30. Kotani, M. J. Phys. Soc. Jpn. 1949, 4, 293.
31. Buschmann, W. E.; Arif, A. M.; Miller, J. S. Angew. Chem., Int. Ed. 1998, 37, 781.
32. Angew. Chem. 1998, 110, 813.
33. Her, J.-H.; Stephens. P. W.; Kareis, C. M.; Moore, J. G.; Min, K. S.; Park, J.-W.; Miller, J. S., in preparation.
34. DeLong, M. C.; Rosenberger, F. J. Cryst. Growth 1986, 75, 164
35. (a) Figgis, B. N. Trans. Faraday Soc. 1964, 57, 298
36. (b) Markley, T. J.; Toby, B. H.; Pearlstein, R. M.; Ramprasad, D. Inorg. Chem. 1997, 36, 3376
37. Brandon, E. J.; Rittenberg, D. K.; Arif, A. M.; Miller, J. S. Inorg. Chem. 1998, 37, 3376.
38. TOPAS V3: General profile and structure analysis software for powder diffraction data.-User's Manual; Bruker AXS: Karlsruhe, Germany, 2005.
39. Coelho, A. A. J. Appl. Crystallogr. 2000, 33, 899
40. TOPAS-Academic is available at http://pws.prserv.net/Alan.Coelho.
41. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; John Wiley and Sons: New York, 1997; Part A, p 161, also Part B, pp 53-57.
42. Hornick, C.; Rabu, P.; Drillon, M. Polyhedron 2000, 19, 259.
43. (a) Shriver, D. F.; Shriver, S. A.; Anderson, S. E. Inorg. Chem. 1965, 4, 725
44. (b) Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 288
45. (c) Jones, L. H.; Swanson, B. I. Acc. Chem. Res. 1976, 9, 128
46. Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: New York, 1976.
47. (a) Gupta, M. P.; Milledge, H. J. Acta Crystallogr. 1974, B30, 656
48. (b) Buschmann, W. E.; Liable-Sands, L.; Rheingold, A. L.; Miller, J. S. Inorg. Chim. Acta 1999, 284, 175
49. Buckelew, A.; Galán-Mascarós, J. R.; Dunbar, K. R. Adv. Mater. 2002, 14, 1646.
50. (a) Tullberg, A.; Vannerberg, N. Acta Chem. Scand. A 1974, 28, 551
51. (b) Tullberg, A.; Vannerberg, N.-G. Acta Chem. Scand. 1971, 25, 343
52. (c) Beall, G. W.; Milligan, W. O.; Korp, J.; Bernal, I. Inorg. Chem. 1977, 16, 2715
53. (d) Brown, D. B.; Shriver, D. F. Inorg. Chem. 1969, 8, 37
54. (e) Ludi, A.; Güdel, H. U. Struct. Bonding (Berlin) 1973, 14, 1
55. Covalency increases with crystal field stabilization, Δ o; hence, high spin MnII-N6 is more ionic than low spin MnII-C6.
56. Mingos D. M. P. Essential Trends in Inorganic Chemistry; Oxford University Press: New York 1998; p 331.
57. (a) Heinrich, J. L.; Sokol, J. J.; Hee, A. G.; Long, J. R. J. Sol. State Chem. 2001, 159, 293
58. (b) Rodríquez-Hernández, J.; Reguera, E.; Lima, E.; Balmaseda, J.; Martínez-Garcia, R.; Yee-Maderia, H. J. Phys. Chem. Sol. 2007, 68, 1630
59. (c) Escorihuela, I.; Falvello, L. R.; Tomás, M. Inorg. Chem. 2001, 40, 636(c)
60. The observed XRPD pattern of 3 can also be equally well-explained with the Fm3c space group symmetry whereby all C and N are positionally disordered, but this was discarded, as it is inconsistent with the structure of the other PBAs, and the magnetic data.
61. (a) Néel, L. Ann. Phys. 1948, 3, 137
62. (b) Smart, J. S. Am. J. Phys. 1955, 23, 356
63. Kumar, A.; Yusuf, S. M.; Keller, L. Phys. Rev. B 2005, 71, 054414
64. It is also substantially greater than the 1.0 emu Oe/mol expected for two low-spin, S=1/2MnII (g∼ 2.3) sites, and is substantially lower than the 8.75 emu Oe/mol expected for two high-spin, S = 5/2 MnII (g ∼ 2.0) sites. It is also substantially greater than the 1.0 emu Oe/mol expected for two low-spin, S=1/2MnII (g∼ 2.3) sites, and is substantially lower than the 8.75 emu Oe/mol expected for two high-spin, S = 5/2 MnII (g ∼ 2.0) sites.