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Volumn 37, Issue 6, 1998, Pages 781-783

Structure and properties of tetracyanomanganate(II), [Mn11(CN)4]2-, the first paramagnetic tetrahedral cyanometalate complex

Author keywords

EPR spectroscopy; Magnetic properties; Manganese

Indexed keywords


EID: 0031897956     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980403)37:6<781::AID-ANIE781>3.0.CO;2-Z     Document Type: Article
Times cited : (43)

References (35)
  • 3
    • 0001397007 scopus 로고
    • b) S. J. Carter, B. M. Foxman, L. S. Stuhl, Inorg. Chem. 1986, 25, 2888; J. Am. Chem. Soc. 1984, 10, 4265;
    • (1984) J. Am. Chem. Soc. , vol.10 , pp. 4265
  • 14
    • 0344102131 scopus 로고    scopus 로고
    • note
    • 4], which exhibits virtually identical spectroscopic properties, has also been prepared.
  • 15
    • 0344964509 scopus 로고    scopus 로고
    • note
    • w (on F) [R (on F)] = 0.0500 [0.0425], for 3011 unique reflections with I > 3σ(I). Data were collected on a CAD4 diffractometer, and the crystal structure solved with MOLEN software distributed by Enraf Nonius. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-179178. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ (fax: (+44)1223-336-033: e-mail: deposit@ccdc.cam.ac.uk).
  • 23
    • 0345395844 scopus 로고    scopus 로고
    • note
    • 4] makes it difficult to obtain well-resolved Raman spectra of low-intensity absorptions even with a 764.925 nm (Ti sapphire) excitation line.
  • 30
    • 0345395842 scopus 로고    scopus 로고
    • note
    • a) This resonance is about 384 G wide, and the peak-to-peak linewidths vary from 69 through 70, 71, and 72 to 73 ±1 G from low to high field. b) This resonance is about 414 G wide with an average hyperfine coupling constant |A\= 71 ± 1 G. The peak-to-peak linewidths are 56, 68. 73. 78, 80 ± 1 G from low to high field.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.