Practical and highly selective sulfur ylide mediated asymmetric epoxidations and aziridinations using an inexpensive, readily available chiral sulfide. Applications to the synthesis of quinine and quinidine

Journal of the American Chemical Society

Volumn 132, Issue 6, 2010, Pages 1828-1830

  Illa, Ona ^a   Arshad, Muhammad ^a   Ros, Abel ^a   McGarrigle, Eoghan M ^a   Aggarwal, Varinder K ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALIPHATIC ALDEHYDES; ASYMMETRIC EPOXIDATION; AZIRIDINES; CHIRAL SULFIDE; CINCHONA ALKALOID; DIASTEREOISOMERS; DIASTEREOSELECTIVITIES; ELEMENTAL SULFUR; HIGH YIELD; HOMOCHIRAL; NATURALLY OCCURRING; ONE STEP SYNTHESIS; SCALEABLE; STEREOSELECTIVE SYNTHESIS; SULFONIUM SALTS;

ADDITION REACTIONS; ALDEHYDES; ENANTIOSELECTIVITY; EPOXIDATION; INDICATORS (CHEMICAL); INORGANIC COMPOUNDS; STEREOSELECTIVITY; SULFUR; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL);

INORGANIC CHEMICALS;

QUINIDINE DERIVATIVE; SULFONIUM DERIVATIVE; SULFUR DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHIRALITY; ENANTIOSELECTIVITY; EPOXIDATION; NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS;

AZIRIDINES; BIOLOGICAL PRODUCTS; COSTS AND COST ANALYSIS; EPOXY COMPOUNDS; QUINIDINE; QUININE; STEREOISOMERISM; SUBSTRATE SPECIFICITY; SULFIDES; SULFUR;

EID: 77249084687     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9100276     Document Type: Article

References (59)

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