Functional group chemistry at the group 4 bent metallocene framework: [2+2] cycloaddition of the parent bis(vinyl-Cp/vinyl-Ind)ZrCl2 systems

Organometallics

Volumn 29, Issue 4, 2010, Pages 860-866

  Greger, Ingo ^a   Kehr, Gerald ^a   Fröhlich, Roland ^b   Erker, Gerhard ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b X ray Crystal Structure Analyses ^*

Author keywords

[No Author keywords available]

Indexed keywords

[2 + 2] CYCLOADDITION; AMBIENT CONDITIONS; ANSA-METALLOCENE; BRIDGING UNITS; CYCLOADDITION REACTION; ETHENE POLYMERIZATIONS; GROUP 4; METALLOCENE COMPLEXES; METALLOCENES; METHYLALUMOXANE; PYREX FILTER; UV LIGHT; ZIRCONIUM DICHLORIDE; ZIRCONOCENES;

CYCLOADDITION; ETHYLENE; FUNCTIONAL GROUPS; LIGHT; ORGANOMETALLICS; PHOTOLYSIS; ZIRCONIUM; ZIRCONIUM COMPOUNDS;

ISOMERS;

EID: 76849111221     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om900939v     Document Type: Article

References (51)

1. Erker, G.; Kehr, G.; Fröhlich, R. J. Organomet. Chem. 2004, 689, 1402-1412.
2. Erker, G. Polyhedron 2005, 24, 1289-1297.
3. Erker, G.; Kehr, G.; Fröhlich, R. Coord. Chem. Rev. 2006, 250, 36-46.
4. See also: Erker, G. J. Organomet. Chem. 2007, 692, 1187-1497.
5. For a recent development see: Ryabov, A. N.; Izmer, V. V.; Tzarev, A. A.; Uborsky, D. V.; Asachenko, A. F.; Nikulin, M. V.; Canich, J. A. M.; Voskoboynikov, A. Z. Organometallics 2009, 28, 3614-3617.
6. (a) Knüppel, S.; Erker, G.; Fröhlich, R. Angew. Chem. 1999, 111, 2048-2051.
7. Angew. Chem., Int. Ed. 1999, 38, 1923-1926.
8. (b)Knüppel, S.; Wang, C.; Kehr, G.; Fröhlich, R.; Erker, G. J. Organomet. Chem. 2005, 690, 14-32.
9. Bai. S.-D.; Wei, X.-W.; Quo. J.-P.: Liu. D.-S.; Zhou. Z.-Y. Angew. Chem. 1999, 111, 2051-2054.
10. Angew. Chem., Int. Ed. 1999, 38, 1926-2192
11. Hüerländer, D.; Kleigrewe, N.; Kehr, G.; Erker, G.; Fröhlich, R. Eur. J. Inorg. Chem. 2002, 2633-2642.
12. Ogasawara, M.; Nagano, T.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 9068-9069.
13. Sierra, J. C.; Hüerländer, D.; Hill, M.; Kehr, G.; Erker, G.; Fröhlich, R. Chem.-Eur. J. 2003, 9, 3618-3622.
14. Kuwabara, J.; Takeuchi, D.; Osakada, K. Organometallics 2005, 24, 2705-2712.
15. Alhomaidan, O.; Bai, G.; Stephan, D. W. Organometallics 2008, 27, 6343-6352.
16. Tumay, T. A.; Kehr, G.; Fröhlich, R.; Erker, G. Dalton Trans. 2009, 8923-8928.
17. Cohen, M. D.; Schmidt, G. M. J. J. Chem. Soc. 1964, 1996-2000.
18. Cohen, M. D.; Schmidt, G. M. J.; Sonntag, F. I. J. Chem. Soc. 1964, 2000-2013.
19. Schmidt, G. M. J. Pure Appl. Chem. 1971, 27, 647-678.
20. Hopf, H.; Greiving, H.; Jones, P. G.; Bubenitschek, P. Angew. Chem. 1995, 107, 742-744.
21. Angew. Chem., Int. Ed. Engl. 1995, 34, 685-687.
22. Erker, G.; Wilker, S.; Krüger, C.; Nolte, N. Organometallics 1993, 12, 2140-2151.
23. Erker, G.; Nolte, M.; Aul, R.; Wilker, S.; Krüger, C.; Noe, R. J. Am. Chem. Soc. 1991, 113, 7594-7602.
24. Paradies, J.; Kehr, G.; Fröhlich, R.; Erker, G. Proc Natl. Acad. Sci. 2006, 103, 15333-15337.
25. Nie, W.-L.; Erker, G.; Kehr, G.; Fröhlich, R. Angew. Chem. 2004, 116, 313-317.
26. Angew. Chem., Int. Ed. 2004, 43, 310-313.
27. Paradies, J.; Fröhlich, R.; Kehr, G.; Erker, G. Organometallics 2006, 25, 3920-3925.
28. Chen, L.; Nie, W.-L.; Paradies, J.; Kehr, G.; Fröhlich, R.; Wedeking, K.; Erker, G. Organometallics 2006, 25, 5333-5344.
29. Iwama, N.; Kato, T.; Sugano, T. Organometallics 2004, 23, 5813-5817.
30. Antberg, M.; Herrmann, H. F.; Rohrmann, J. Eur. Pat. Appl, EP 496193, 1992.
31. Macomber, D. W.; Spink, W. C.; Rausch, M. D. J. Oreanomet. Chem. 1983, 250, 311-318.
32. Hafner, K.; Völpel, K. H.; Ploss, G.; König, C. Org. Synth. 1967, 47, 52.
33. Eliel, E. L.; Wilen, S. H.; Doyle, M. P. Basic Organic Stereochemistry; Wiley-Interscience: New York, 2001.
34. Marks, T. J. Acc. Chem. Res. 1992, 25, 57-65.
35. Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem. 1995, 107, 1255-1283.
36. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143-1170.
37. Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255-270.
38. Bochmann, M. J. Organomet. Chem. 2004, 689, 3982-3998.
39. Tamao, K. J. Organomet. Chem. 2002, 653, 23-26.
40. Palmer, M. J.; Kenny, J. A.; Walsgrove, T.; Kawamoto, A. M.; Wills, M. J. Chem. Soc., Perkin Trans. 1 2002, 416-427.
41. Halterman, R. L.; Fahey, D. R.; Bailly, E. F.; Dockter, D. W.; Stenzel, O.; Shipman, J. L.; Khan, M. A.; Dechert, S.; Schumann, H. Organometallics 2000, 19, 5464-5470.
42. Adam, W.; De Lucchi, O. J. Org. Chem. 1980, 45, 4167-4168.
43. Paradies, J.; Greger, L; Kehr, G.; Erker, G.; Bergander, K.; Fröhlich, R. Angew. Chem. 2006, 118, 7792-7795;
44. Angew. Chem., Int. Ed. Engl. 2006, 45, 7630-7633.
45. Kumada, M. pure Appl. Chem. 1980, 52, 669-679.
46. Keegstra, M. A.; Verkruijsse, H. D.; Andringa, H.; Brandsma, L. Synth Commun. 1991, 21 (5), 721-726.
47. Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem, 1999, 111, 448-468;
48. Angew. Chem., Int. Ed. 1999, 38, 428-447.
49. See also: Paradies, J.; Erker, G.; Fröhlich, R. Angew. Chem. 2006, 118, 3150-3153;
50. Angew. Chem., Int. Ed. 2006, 45, 3079-3082.
51. Tumay, T. A.; Kehr, G.; Fröhlich, R.; Erker, G. Organometallics 2009, 28, 4513-4518.