Effect of the type of alkylammonium ion clay modifier on the structure and thermal/mechanical properties of glassy and rubbery epoxy-clay nanocomposites

European Polymer Journal

Volumn 46, Issue 3, 2010, Pages 404-417

  Xidas, Panagiotis I ^a,b   Triantafyllidis, Kostas S ^a  

^a ARISTOTLE UNIVERSITY OF THESSALONIKI   (Greece)

^b UNIVERSITY OF IOANNINA   (Greece)

Author keywords

Clays; Glassy and rubbery epoxy; Mechanical properties; Nanocomposites; Primary and quaternary alkylammonium ion modifier; Thermal stability

Indexed keywords

ALKYLAMMONIUM; AMMONIUM IONS; CLAY MODIFIER; CLOISITE; EPOXY NANOCOMPOSITES; EPOXY-CLAY NANOCOMPOSITES; EXFOLIATED CLAY; EXFOLIATED NANOCOMPOSITES; GLASSY AND RUBBERY EPOXY; HYDROGEN ATOMS; OCTADECYL; ORGANIC MODIFIER; ORGANOCLAYS; PRISTINE EPOXY; SIZE AND SHAPE; STRUCTURE AND PROPERTIES; TENSILE MEASUREMENTS; THERMAL STABILITY; THERMO-MECHANICAL; VARYING PARAMETERS;

AMMONIUM COMPOUNDS; CLAY MINERALS; IMPACT IONIZATION; IONS; NANOCOMPOSITES; ORGANOCLAY; SILICATE MINERALS; THERMODYNAMIC STABILITY;

MECHANICAL PROPERTIES;

EID: 76749146740     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.11.004     Document Type: Article

References (39)

1. Pinnavaia TJ, Beall GW, editors. Polymer-clay nanocomposites. Wiley series in polymer science, 2000.
2. Vaia R.A., and Giannelis E.P. Polymer nanocomposites: status and opportunities. MRS Bulletin (2001) 394-401
3. Becker O., Simon G.P., and Dusek K. Epoxy layered silicate nanocomposites. Inorganic polymeric nanocomposites and membranes (2005), Springer, Berlin 29-82
4. Sinha Ray S., and Okamoto M. Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28 11 (2003) 1539-1641
5. LeBaron P.C., and Pinnavaia T.J. Clay nanolayer reinforcement of a silicone elastomer. Chem Mater 13 10 (2001) 3760-3765
6. Lagaly G. Introduction: from clay mineral-polymer interactions to clay mineral-polymer nanocomposites. Appl Clay Sci 15 1-2 (1999) 1-9
7. Giannelis E.P. Polymer layered silicate nanocomposites. Adv Mater 8 1 (1996) 29-35
8. Manias E., Touny A., Wu L., Strawhecker K., Lu B., and Chung T.C. Polypropylene/montmorillonite nanocomposites. Review of the synthetic routes and materials properties. Chem Mater 13 10 (2001) 3516-3523
9. Okada A., and Usuki A. The chemistry of polymer-clay hybrids. Mater Sci Eng C 3 2 (1995) 109-115
10. Chen B., Evans J.R.G., Greenwell H.C., Boulet P., Coveney P.V., Bowden A.A., et al. A critical appraisal of polymer-clay nanocomposites. Chem Soc Rev 37 3 (2008) 568-594
11. Pinnavaia T.J. Intercalated clay catalysts. Science 220 4595 (1983) 365-371
12. Vaia R.A., and Giannelis E.P. Polymer melt intercalation in organically-modified layered silicates: model predictions and experiment. Macromolecules 30 (1997) 8000-8009
13. Calcagno C.I.W., Mariani C.M., Teixeira S.R., and Mauler R.S. The effect of organic modifier of the clay on morphology and crystallization properties of PET nanocomposites. Polymer 48 4 (2007) 966-974
14. Chrissopoulou K., Altintzi I., Anastasiadis S.H., Giannelis E.P., Pitsikalis M., Hadjichristidis N., et al. Controlling the miscibility of polyethylene/layered silicate nanocomposites by altering the polymer/surface interactions. Polymer 46 26 (2005) 12440-12451
15. Shi H., Lan T., and Pinnavaia T.J. Interfacial effects on the reinforcement properties of polymer-organoclay nanocomposites. Chem Mater 8 8 (1996) 1584-1587
16. Wang M.S., and Pinnavaia T.J. Clay-polymer nanocomposites formed from acidic derivatives of montmorillonite and an epoxy resin. Chem Mater 6 4 (1994) 468-474
17. Lan T., Kaviratna P.D., and Pinnavaia T.J. Mechanism of clay tactoid exfoliation in epoxy-clay nanocomposites. Chem Mater 7 11 (1995) 2144-2150
18. Wang Z., and Pinnavaia T.J. Hybrid organic-inorganic nanocomposites: exfoliation of magadiite nanolayers in an elastomeric epoxy polymer. Chem Mater 10 7 (1998) 1820-1826
19. Brown J.M., Curliss D., and Vaia R.A. Thermoset-layered silicate nanocomposites. Quaternary ammonium montmorillonite with primary diamine cured epoxies. Chem Mater 12 11 (2000) 3376-3384
20. Bin Bae S., Kim C.K., Kim K., and Chung I.J. The effect of organic modifiers with different chain lengths on the dispersion of clay layers in HTPB (hydroxyl terminated polybutadiene). Eur Polym J 44 11 (2008) 3385-3392
21. Chen C., and Curliss D. Preparation, characterization, and nanostructural evolution of epoxy nanocomposites. J Appl Polym Sci 90 8 (2003) 2276-2287
22. Kim Y., and White J.L. Formation of polymer nanocomposites with various organoclays. J Appl Polym Sci 96 5 (2005) 1888-1896
23. Vaia R.A., Teukolsky R.K., and Giannelis E.P. Interlayer structure and molecular environment of alkylammonium layered silicates. Chem Mater 6 7 (2002) 1017-1022
24. Triantafillidis C.S., LeBaron P.C., and Pinnavaia T.J. Thermoset epoxy-clay nanocomposites: the dual role of [alpha],[omega]-diamines as clay surface modifiers and polymer curing agents. J Solid State Chem 167 2 (2002) 354-362
25. Triantafillidis C.S., LeBaron P.C., and Pinnavaia T.J. Homostructured mixed inorganic-organic ion clays: a new approach to epoxy polymer-exfoliated clay nanocomposites with a reduced organic modifier content. Chem Mater 14 10 (2002) 4088-4095
26. Triantafyllidis K.S., Xidas P.I., and Pinnavaia T.J. Alternative synthetic routes to epoxy polymer-clay nanocomposites using organic or mixed-ion clays modified by protonated di/triamines (Jeffamines). Macromol Symp 267 1 (2008) 41-46
27. Yoon K.-b., Sung H.-d., Hwang Y.-y., Kyun Noh S., and Lee D.-h. Modification of montmorillonite with oligomeric amine derivatives for polymer nanocomposite preparation. Appl Clay Sci 38 1-2 (2007) 1-8
28. Wang Z., and Pinnavaia T.J. Intercalation of poly(propyleneoxide) amines (Jeffamines) in synthetic layered silicas derived from ilerite, magadiite, and kenyaite. J Mater Chem 13 (2003) 2127-2131
29. Salahuddin N.A. Layered silicate/epoxy nanocomposites: synthesis, characterization and properties. Polym Adv Tech 15 (2004) 251-259
30. Gatos K.G., and Karger-Kocsis J. Effects of primary and quaternary amine intercalants on the organoclay dispersion in a sulfur-cured EPDM rubber. Polymer 46 9 (2005) 3069-3076
31. Tsai J.-L., Kuo J.-C., and Hsu S.-M. Organoclay effect on transverse compressive strength of glass/epoxy nanocomposites. J Mater Sci 41 22 (2006) 7406-7412
32. Ngo T.-D., Ton-That M.-T., Hoa S.V., and Cole K.C. Curing kinetics and mechanical properties of epoxy nanocomposites based on different organoclays. Polym Eng Sci 47 5 (2007) 649-661
33. Dai C.-F., Li P.-R., and Yeh J.-M. Comparative studies for the effect of intercalating agent on the physical properties of epoxy resin-clay based nanocomposite materials. Eur Polym J 44 8 (2008) 2439-2447
34. Usuki A., Hasegawa N., and Kato M. Polymer-clay nanocomposites. Adv Polym Sci (2005), Springer, Berlin Heidelberg 135-195
35. Ngo T.-D., Ton-That M.T., Hoa S.V., and Cole K.C. Reinforcing effect of organoclay in rubbery and glassy epoxy resins, part 1: dispersion and properties. J Appl Polym Sci 107 2 (2008) 1154-1162
36. Ho M.-W., Lam C.-K., Lau K.-t., Ng D.H.L., and Hui D. Mechanical properties of epoxy-based composites using nanoclays. Comp Struct 75 1-4 (2006) 415-421
37. Becker O., Varley R., and Simon G. Morphology, thermal relaxations and mechanical properties of layered silicate nanocomposites based upon high-functionality epoxy resins. Polymer 43 16 (2002) 4365-4373
38. Zilg C., Mólhaupt R., and Finter J. Morphology and toughness/stiffness balance of nanocomposites based upon anhydride-cured epoxy resins and layered silicates. Macromol Chem Phys 200 3 (1999) 661-670
39. Ratna D., Manoj N.R., Varley R., Singh Raman R.K., and Simon G.P. Clay-reinforced epoxy nanocomposites. Polym Int 52 9 (2003) 1403-1407