Method for the determination of organophosphorus and pyrethroid pesticides in food via gas chromatography with electron-capture detection

Journal of Agricultural and Food Chemistry

Volumn 58, Issue 3, 2010, Pages 1396-1402

  Hunter Jr , Ronald E ^a   Riederer, Anne M ^b   Ryan, P Barry ^a,b  

^a EMORY UNIVERSITY   (United States)

^b EMORY UNIVERSITY   (United States)

Author keywords

Electron capture detection; Food samples; GC ECD; GC MS; Multiresidue; Organophosphorus pesticides; Pyrethroid pesticides; QuEChERS

Indexed keywords

ORGANOPHOSPHORUS COMPOUND; PESTICIDE RESIDUE; PYRETHROID;

ARTICLE; EVALUATION; FOOD CONTAMINATION; GAS CHROMATOGRAPHY; INSTRUMENTATION; METHODOLOGY;

CHROMATOGRAPHY, GAS; FOOD CONTAMINATION; ORGANOPHOSPHORUS COMPOUNDS; PESTICIDE RESIDUES; PYRETHRINS;

EID: 76449091891     PISSN: 00218561     EISSN: 15205118     Source Type: Journal    
DOI: 10.1021/jf9028859     Document Type: Article

References (36)

1. Ridgway, K.; Lalljie, S. P.; Smith, R. M. Sample preparation techniques for the determination of trace residues and contaminants in foods. J. Chromatogr., A 2007, 1153 (1-2), 36-53. (Pubitemid 46778853)
2. Avramides, E. J.; Gkatsos, S. A multiresidue method for the determination of insecticides and triazine herbicides in fresh and processed olives. J. Agric. Food Chem. 2007, 55 (3), 561-565
3. Cho, S. K.; Abd El-Aty, A. M.; Choi, J. H.; Jeong, Y. M.; Shin, H. C.; Chang, B. J.; Lee, C.; Shim, J. H. Effectiveness of pressurized liquid extraction and solvent extraction for the simultaneous quantification of 14 pesticide residues in green tea using GC J. Sep. Sci. 2008, 31 (10), 1750-1760 (Pubitemid 351911739)
4. Fenoll, J.; Hellin, P.; Lopez, J.; Gonzalez, A.; Flores, P. Determination of pesticide residues in lettuce by gas chromatography with electron-capture detection. J. AOAC Int. 2007, 90 (6), 1670-1676
5. Li, L.; Zhang, H.; Pan, C.; Zhou, Z.; Jiang, S.; Liu, F. Multiresidue analytical method of pesticides in peanut oil using low-temperature cleanup and dispersive solid phase extraction by GC-MS. J. Sep. Sci. 2007, 30 (13), 2097-2104 (Pubitemid 47377085)
6. Fernandez-Moreno, J. L.; Garrido-Frenich, A.; Plaza-Bolanos, P.; Martinez-Vidal, J. L. Multiresidue method for the analysis of more than 140 pesticide residues in fruits and vegetables by gas chromatography coupled to triple quadrupole mass spectrometry. J. Mass Spectrom. 2008, 43 (9), 1235-1254
7. Romero-Gonzalez, R.; Garrido-Frenich, A.; Martinez-Vidal, J. L. Multiresidue method for fast determination of pesticides in fruit juices by ultra performance liquid chromatography coupled to tandem mass spectrometry. Talanta 2008, 76 (1), 211-225
8. Schenck, F. J.; Brown, A. N.; Podhorniak, L. V.; Parker, A.; Reliford, M.; Wong, J. W. A rapid multiresidue method for determination of pesticides in fruits and vegetables by using acetonitrile extraction/partitioning and solid-phase extraction column cleanup. J. AOAC Int. 2008, 91 (2), 422-438
9. Takatori, S.; Okihashi, M.; Okamoto, Y.; Kitagawa, Y.; Kakimoto, S.; Murata, H.; Sumimoto, T.; Tanaka, Y. A rapid and easy multiresidue method for the determination of pesticide residues in vegetables, fruits, and cereals using liquid Chromatography/tandem mass spectrometry. J. AOAC Int. 2008, 91 (4), 871-883
10. Osteen, C.; Moshfegh, A.; Kott, P. Pesticide Data Program: Progress Report. http://www.ams.usda.gov/AMSv1.0/getfile?dDocName= STELDEV3002094 (March 11, 2009).
11. USFDA Total Diet Study, http://vm.cfsan.fda.gov/~comm/tds-toc. html (March 11, 2009).
12. USEPA Pesticides and Food: What the Pesticide Residue Limits Are on Food, http://www.epa.gov/opp00001/food/viewtols.htm (March 11, 2009).
13. Sawaya, W. N.; Al-Awadhi, F. A. A.; Saeed, T.; Al-Omair, A.; Husain, A.; Ahmad, N.; Al-Omirah, H.; Al-Zenki, S.; Khalafawi, S.; Al-Otaibi, J.; Al-Amiri, H. Dietary intake of organophosphate pesticides in Kuwait. Food Chem. 2000, 69, 331-338. (Pubitemid 30136386)
14. Eskenazi, B.; Bradman, A.; Castorina, R. Exposures of children to organophosphate pesticides and their potential adverse health effects. Environ. Health Perspect. 1999, 107 (Suppl. 3), 409-419. (Pubitemid 29346987)
15. Kamel, F.; Engel, L. S.; Gladen, B. C.; Hoppin, J. A.; Alavanja, M. C. R.; Sandler, D. P. Neurologic symptoms in licensed private pesticide applicators in the agricultural health study. Environ. Health Perspect. 2005, 113, 877-882. (Pubitemid 40984188)
16. Richardson, R. J. Assessment of the neurotoxic potential of chlorpyrifos relative to other organophosphorus compounds: a critical review of the literature. J. Toxicol. Environ. Health 1995, 44, 135-165.
17. Whyatt, R. M.; Barr, D. B. Measurement of organophosphate metabolites in postpartum meconium as a potential biomarker of prenatal exposure: a validation study. Environ. Health Perspect. 2001, 109.
18. Bearer, C. F. How are children different from adults? Environ. Health Perspect. 1995, 103 (Suppl. 6), 7-12.
19. Hercegová, A.; Dömötörova, M.; Matisová, E. Sample preparation methods in the analysis of pesticide residues in baby food with subsequent chromatographic determination. J. Chromatogr., A 2007, 1153 (1-2), 54-73. (Pubitemid 46755187)
20. Luke, M.; Froberg, J. E.; Masumoto, H. T. Extraction and cleanup of organochlorine, organophosphate, organonitrogen, and hydrocarbon pesticides in produce for determination by gas-liquid chromatography. J. Assoc. Off. Anal. Chem. 1975, 58,1020-1026.
21. Bicchi, C.; Balbo, C.; Binello, A.; D'Amato, A. HPLC - UV determination of pesticide residues at 0.01 ppm in apple and pear pulp used for baby food. J. High Resol. Chromatogr. 1996, 19 (2), 105-110. (Pubitemid 126414405)
22. Anastassiades, M.; Lehotay, S. J.; Štajnbaher, D.; Schenck, F. J. Fast and easy multiresidue method employing acetonitrile extraction/ partitioning and "dispersive solid-phase extraction" for the determination of pesticide residues in produce. J. AOAC Int. 2003, 86 (2), 412-431.
23. Barbini, D. A.; Vanni, F.; Girolimetti, S.; Dommarco, R. Development of an analytical method for the determination of the residues of four pyrethroids in meat by GC-ECD and confirmation by GC-MS. Anal. Bioanal. Chem. 2007, 389 (6), 1791-1798 (Pubitemid 350231582)
24. Cao, P.; Liu, F.; Wang, S.; Wang, Y.; Han, L. GC-ECD analysis of S-metolachlor (Dual Gold) in cotton plant and soil in trial field. Environ. Monit. Assess. 2008, 143 (1-3), 1-7. (Pubitemid 351998287)
25. Khay, S.; Abd El-Aty, A. M.; Choi, J. H.; Shin, E. H.; Shin, H. C. C.; Kim, J. S.; Chang, B. J.; Lee, C. H.; Shin, S. C.; Jeong, J. Y.; Shim, J. H. Simultaneous determination of pyrethroids from pesticide residues in porcine muscle and pasteurized milk using GC. J. Sep. Sci. 2009, 32 (2), 244-251
26. Valsamaki, V. I.; Sakkas, V. A.; Albanis, T. A. Determination of the pesticides considered as endocrine-disrupting compounds (EDCs) by solid-phase extraction followed by gas chromatography with electron capture and mass spectrometric detection. J. Sep. Sci. 2007, 30 (12), 1936-1946 (Pubitemid 47243980)
27. Lehotay, S. J.; Kok, A. d.; Hiemstra, M.; Bodegraven, P. V. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection. J. AOAC Int. 2005, 88 (2), 595-614.
28. Lightfield, A. R.; Lehotay, S. J.; Maštovská, K. Use of buffering and other means to improve results of problematic pesticides in a fast and easy method for residue analysis of fruits and vegetables. J. AOAC Int. 2005, 88, 615-629. (Pubitemid 40479419)
29. Leandro, G C.; Hancock, P.; Fussell, R. J.; Kelly, B. J. Comparison of ultra-performance liquid chromatography and high-performance liquid chromatography for the determination of priority pesticides in baby foods by tandem quadrupole mass spectrometry. J. Chromatogr., A 2006, 1103, 94-101.
30. Fillion, J.; Sauve, F.; Selwyn, J. Multiresidue method for the determination of residues of 251 pesticides in fruits and vegetables by gas chromatography/mass spectrometry and liquid chromatography with fluorescence detection. J. AOAC Int. 2000, 83 (3), 698-713.
31. USEPA Measure E8: Pesticide Residues on Foods Frequently Consumed by Children, http://www.epa.gov/opeedweb/children/contaminants/e8-background.htm (March 11, 2009).
32. Skoog, D. A.; Holler, F. J.; Nieman, T. A. Principles of Instrumental Analysis, 5th ed.; Brooks Cole: Pacific Grove, CA, 1997; p 960.
33. Schenck, F.; Wong, J.; Lu, C.; Li, J.; Holcomb, J.; Mitchel, L., Multiresidue analysis of 102 organophosphorus pesticides in produce at parts-per billion levels using a modified quechers method and gas chromatography with pulsed flame photometric detection. J. AOAC Int. 2009, 92, 561-573.
34. Supelco Technical Report: Extraction of Pesticides from Agricultural Products Using Multi-Layer ENVI-Carb-II/PSA SPE Tubes; Sigma-Aldrich, Inc.: Bellefonte, PA, 2005.
35. Ahmed, F. E. Analyses of pesticides and their metabolites in foods and drinks. Trends Anal. Chem. 2001, 20, 649-661.
36. Arndt, T.; Kropf, J. Alcohol abuse and carbohydrate-deficient transferrin analysis: Are screening and confirmatory analysis required? Clin. Chem. 2002, 48, 2072-2074. (Pubitemid 35222774)