Mechanism of general acid-base catalysis in transesterification of an RNA model phosphodiester studied with strongly basic catalysts

Organic and Biomolecular Chemistry

Volumn 8, Issue 4, 2010, Pages 873-880

  Corona Martínez, David O ^a   Taran, Olga ^a   Yatsimirsky, Anatoly K ^a  

^a Universidad Nacional Autonoma de Mexico Facultad de Quimica   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

ACID-BASE CATALYSIS; ALKYL AMINES; AMMONIUM CATIONS; AQUEOUS DMSO; BASIC CATALYSTS; BUFFER COMPONENTS; BUFFER MIXTURES; CATALYTIC EFFICIENCIES; CATALYZED REACTIONS; CONCENTRATION RANGES; FRACTIONATION FACTORS; GENERAL BASE CATALYSIS; GUANIDINIUM; GUANIDINIUM CATIONS; ISOTOPE EFFECT; KINETIC STUDY; MODEL SUBSTRATES; NITROPHENYL PHOSPHATES; PHOSPHATE GROUP; PHOSPHODIESTERS; PROTONATED; RATE LAWS; REACTION MEDIUM; SOLVENT ISOTOPE EFFECTS; TRANSITION STATE STABILIZATION;

AMMONIUM COMPOUNDS; BINDING ENERGY; CARRIER MOBILITY; CATALYSIS; ISOTOPES; PROTON TRANSFER; RATE CONSTANTS; RNA; STABILIZATION;

POSITIVE IONS;

4 NITROPHENYL; 4-NITROPHENYL; AMIDINE; DIMETHYL SULFOXIDE; GUANIDINE; NITROPHENOL; NITROPHENYL PHOSPHATE; ORGANOPHOSPHATE; ORGANOPHOSPHORUS COMPOUND; OXYGEN; RNA;

ARTICLE; CATALYSIS; CHEMISTRY; ESTERIFICATION; KINETICS; PH;

AMIDINES; CATALYSIS; DIMETHYL SULFOXIDE; ESTERIFICATION; GUANIDINE; HYDROGEN-ION CONCENTRATION; KINETICS; NITROPHENOLS; ORGANOPHOSPHORUS COMPOUNDS; OXYGEN ISOTOPES; PHOSPHORIC ACID ESTERS; RNA;

KOBUS;

EID: 76249103566     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b920398b     Document Type: Article

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