N-(2-Hydroxypropyl)formamide and N-(2-hydroxyethyl)-N-methylformamide as two new plasticizers for thermoplastic starch

Carbohydrate Polymers

Volumn 80, Issue 1, 2010, Pages 139-144

  Dai, Hongguang ^a,b   Chang, Peter R ^c,d   Yu, Jiugao ^a   Geng, Fengying ^a   Ma, Xiaofei ^a  

^a TIANJIN UNIVERSITY   (China)

^b INNER MONGOLIA AGRICULTURAL UNIVERSITY   (China)

^c AGRICULTURE AND AGRI FOOD CANADA   (Canada)

^d UNIVERSITY OF SASKATCHEWAN   (Canada)

Author keywords

Crystallinity; N (2 Hydroxyethyl) N methylformamide; N (2 Hydroxypropyl)formamide; New plasticizer; Thermoplastic starch

Indexed keywords

CRYSTALLINITIES; FORMAMIDES; N-(2-HYDROXYPROPYL)FORMAMIDE; N-METHYLFORMAMIDE; THERMOPLASTIC STARCH;

AMIDES; ATMOSPHERIC HUMIDITY; HEAT SHIELDING; HYDROGEN BONDS; INFRARED SPECTROSCOPY; LIGHT WEIGHT ROLLING STOCK; PLASTICIZERS; SCANNING ELECTRON MICROSCOPY; SOLVENTS; STARCH; TENSILE STRENGTH;

REINFORCED PLASTICS;

ZEA MAYS;

EID: 75449085308     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2009.11.001     Document Type: Article

References (19)

1. Aoi K., Takasu A., Tsuchiya M., and Okada M. New chitin-based polymer hybrids. 3. Miscibility of chitin-graft-poly(2-ethyl-2-oxazoline) with poly(vinyl alcohol). Macromolecular Chemistry and Physics 199 (1998) 2805-2811
2. Barrett A., Kaletunc G., Rosenburg S., and Breslauer K. Effect of sucrose on the structure, mechanical strength and thermal properties of corn extrudates. Carbohydrate Polymers 26 (1995) 261-269
3. Coupland K., and Smith P.J. N-Acylalkanolamine humectants - an alternative approach to moisturisation. Speciality Chemicals 6 (1986) 10-17
4. Da Róz A.L., Carvalho A.J.F., Gandini A., and Curvelo A.A.S. The effect of plasticizers on thermoplastic starch compositions obtained by melt processing. Carbohydrate Polymers 63 (2006) 417-424
5. Dai H., Chang P.R., Peng F., Yu J., and Ma X. N-(2-Hydroxyethyl)formamide as a new plasticizer for thermoplastic starch. Journal of Polymer Research 16 (2009) 529-535
6. Dai H., Chang P.R., Yu J., and Ma X. N,N-Bis(2-hydroxyethyl)formamide as a new plasticizer for thermoplastic starch. Starch/Stärke 60 (2008) 676-684
7. Fang J.M., Fowler P.A., Tomkinson J., and Hill C.A.S. The preparation and characterisation of a series of chemically modified potato starches. Carbohydrate Polymers 47 (2002) 245-252
8. Forssell P.M., Mikkilä J.M., Moates G.K., and Parker R. Phase and glass transition behaviour of concentrated barley starch-glycerol-water mixtures, a model for thermoplastic starch. Carbohydrate Polymers 34 (1997) 275-282
9. Godbillot L., Dole P., Joly C., Rogé B., and Mathlouthi M. Analysis of water binding in starch plasticized films. Food Chemistry 96 (2006) 380-386
10. Kibler, & Richard, W. (1973). Nylon tire cords. United States Patent Office, Pat. No. US 3760578.
11. Ma X.F., and Yu J.G. Formamide as the plasticizer for thermoplastic starch. Journal of Applied Polymer Science 93 (2004) 1769-1773
12. Pawlak A., and Mucha M. Thermogravimetric and FTIR studies of chitosan blends. Thermochimica Acta 396 (2003) 153-166
13. Pontes R.M., Basso E.A., and dos Santos F.P. Medium effect on the rotational barrier of carbamates and its sulfur congeners. The Journal of Organic Chemistry 72 (2007) 1901-1911
14. Stein T.M., Gordon S.H., and Greene R.V. Amino acids as plasticizers. II. Use of quantitative structure-property relationships to predict the behavior of monoammoniummonocarboxylate plasticizers in starch-glycerol blends. Carbohydrate Polymers 39 (1999) 7-16
15. Stein T.M., and Greene R.V. Amino acids as plasticizers for starch-based plastics. Starch/Stärke 49 (1997) 245-249
16. Tristao de Andrade, C., & Rocha de Souza, R. C. (2004). Process for production of totally biodegradable thermoplastic based on starch and natural polymers. Brazil Patent Office, Pat. No. BR 2002000174.
17. van Soest J.J.G., Hulleman S.H.D., de Wit D., and Vliegenthart J.F.G. Crystallinity in starch bioplastics. Industrial Crops and Products 5 (1996) 11-22
18. Wang L., Shogren R.L., and Carriere C. Preparation and properties of thermoplastic starch-polyester laminate sheets by coextrusion. Polymer Engineering and Science 40 (2000) 499-506
19. Yang J.H., Yu J.G., and Ma X.F. Preparation of a novel thermoplastic starch material using ethylenebisformamide as the plasticizer. Starch/Stärke 58 (2006) 330-337