N,N-Bis(2-hydroxyethyl)formamide as a new plasticizer for thermoplastic starch

Starch/Staerke

Volumn 60, Issue 12, 2008, Pages 676-684

  Dai, Hongguang ^a   Chang, Peter R ^b   Yu, Jiugao ^a   Xiaofei, Ma ^a  

^a TIANJIN UNIVERSITY   (China)

^b AGRICULTURE AND AGRI FOOD CANADA   (Canada)

Author keywords

N; N bis(2 hydroxyethyl)formamlde; New plastlcizer; Thermoplastic starch

Indexed keywords

AMIDES; ATMOSPHERIC HUMIDITY; DIFFERENTIAL SCANNING CALORIMETRY; FOURIER TRANSFORMS; GLYCEROL; HEAT SHIELDING; HYDROGEN; HYDROGEN BONDS; INFRARED SPECTROSCOPY; LASER INTERFEROMETRY; LIGHT WEIGHT ROLLING STOCK; PLASTICIZERS; REINFORCED PLASTICS; SCANNING; SCANNING ELECTRON MICROSCOPY; X RAY ANALYSIS;

BOND INTERACTIONS; CORN STARCHES; ELONGATION AT BREAKS; FOURIER-TRANSFORM; N; N-BIS(2-HYDROXYETHYL)FORMAMLDE; NEW PLASTLCIZER; RELATIVE HUMIDITIES; STARCH GRANULES; THERMAL BEHAVIORS; WATER RESISTANCES; X-RAY DIFFRACTIONS;

STARCH;

ZEA MAYS;

EID: 58049211603     PISSN: 00389056     EISSN: 1521379X     Source Type: Journal    
DOI: 10.1002/star.200800017     Document Type: Article

References (22)

1. X. F. Ma, J. G. Yu: Formamide as the plastlcizer for thermoplastic starch. J. Appl. Polym. Sci. 2004, 93, 1769-1773.
2. P. M. Forssell, J. M. Mikkilä, G. K. Moates, R. Parker: Phase and glass transition behaviour of concentrated barley starch-glycerol-water mixtures, a model for thermoplastic starch. Carbohydr. Polym. 1997, 34, 275-282.
3. A. L. Da Róz, A. J. F. Carvalho, A. Gandini, A. A. S. Curvelo: The effect of plasticlzers on thermoplastic starch compositions obtained by melt processing. Carbohydr. Polym. 2006, 63, 417-424.
4. C. Tristao de Andrade, R. C. Rocha de Souza: BR Pat. 2002000174 (2004).
5. L. Wang, R. L. Shogren, C. Carriere: Preparation and properties of thermoplastic starch-polyester laminate sheets by coextrusion. Polym. Eng.Sci. 2000, 40, 499-506.
6. A. Barrett, G. Kaletunc, S. Rosenburg, K. Breslauer: Effect of sucrose on the structure, mechanical strength and thermal properties of corn extrudates. Carbohydr. Polym. 1995, 26, 261-269.
7. T. M. Stein, R. V. Greene: Amino acids as plasticizers for starch-based plastics. Starch/Stärke 1997, 49, 245-249.
8. J. H. Yang, J.G. Yu, X. F. Ma: Preparation of a novel thermoplastic starch material using ethylenebisformamide as the plasticizer. Starch/Stärke 2006, 58, 330-337.
9. K. Coupland, P. J. Smith: N-Acylalkanolamine humectants - an alternative approach to moisturisation. Spec. Chem. 1986, 6, 10-17.
10. W. Kibler, Richard: US Pat. 3760578 (1973).
11. A. Ricci, G. Sbrana, G. Braca: EP Pat. 0248259 (1991).
12. R. B. Frings, G. F. Grahe: EP Pat. 469550 (1992).
13. F. E. Teng, Y. M. Wang: The principle of analysis of X-ray and experiment of diffraction of crystal, Press of JiMn University, Changchun, 2002.
14. X. F. Ma, J. G. Yu, J. J. Wan: Urea and ethanolamine as a mixed plasticizer for thermoplastic starch. Carbohydr. Polym. 2006, 64, 267-273.
15. L. Godbillot, P. Dole, C. Joly, B. Rogé, M. Mathlouthi: Analysis of water binding in starch plasticized films. Food Chem. 2006, 96, 380-386.
16. J. M. Fang, P. A. Fowler, J. Tomkinson, C. A. S. Hill: The preparation and characterisation of a series of chemically modified potato starches. Carbohydr. Polym. 2002, 47, 245-252.
17. K. Aol, A. Takasu, M. Tsuchiya, M. Okada: New chitin-based polymer hybrids, 3 Miscibillty of chitin-graft-poly(2-ethyl-2-oxazoline) with polyvinyl alcohol). Macromol. Chem. Phys. 1998, 199, 2805-2811.
18. A. Pawlak, M. Mucha: Thermogravimetric and FTIR studies of chitosan blends. Thermochlm. Acta 2003, 396, 153-166.
19. J. J. G. van Soest, S. H. D. Hulleman, D. de Wit, J. F. G. Vliegenthart: Crystallinity in starch bioplastics. Ind. Crop. Prod. 1996, 5, 11-22.
20. A. Buléon, M. M. Delage, J. Brisson, H. Chanzy: Single crystals of Vamylose oomplexed with isopropanol and acetone. Int. J. Biol. Macromol. 1990, 12, 25-33.
21. h-amylose. Carbohydr. Res. 1981, 89, 11-19.
22. X. F. Ma, P. R. Chang, J. G. Yu: Properties of biodegradable thermoplastic pea starch/carboxymethyl cellulose and pea starch/microcrystalline cellulose composites. Carbohydr. Polym. 2008, 72, 369-375.