Electrical manipulation of spin states in a single electrostatically gated transition-metal complex

Nano Letters

Volumn 10, Issue 1, 2010, Pages 105-110

  Osorio, Edgar A ^a   Moth Poulsen, Kasper ^b   Van Der Zant, Herre S J ^a   Paaske, Jens ^b   Hedegård, Per ^b   Flensberg, Karsten ^b   Bendix, Jesper ^b   Bjørnholm, Thomas ^b  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

Electromigration; Molecular spintronics; Single molecule electronics; Spin blockade; Transition metal complex

Indexed keywords

ELECTRICAL MANIPULATION; EXACT DIAGONALIZATION; INELASTIC COTUNNELING; LIGAND-FIELD; LOW TEMPERATURES; MAGNETIC EXCITATION SPECTRA; MOLECULAR SPINTRONICS; SEQUENTIAL TUNNELLING; SINGLE ELECTRON; SINGLE-MOLECULE ELECTRONICS; SINGLET-TRIPLET SPLITTING; SPIN BLOCKADE; SPIN CONFIGURATIONS; SPIN STATE; TERPYRIDINES; THREE-TERMINAL DEVICES; TRANSITION-METAL COMPLEX;

ELECTROMIGRATION; LIGANDS; MANGANESE; MANGANESE COMPOUNDS; METAL COMPLEXES; MOLECULES; NANOTECHNOLOGY; SEMICONDUCTOR QUANTUM DOTS;

SPIN DYNAMICS;

EID: 74849109418     PISSN: 15306984     EISSN: None     Source Type: Journal    
DOI: 10.1021/nl9029785     Document Type: Article

References (31)

1. Osorio, E. A.; O'Neill, K.; Stuhr-Hansen, N.; Nielsen, O. F.; Bjoørnholm, T.; van der Zant, H. S. J. Adv. Mater. 2007, 19, 281-285.
2. Osorio, E. A.; O'Neill, K.; Wegewijs, M.; Stuhr-Hansen, N.; Paaske, J.; Bjørnholm, T.; van der Zant, H. S. T. Nano Lett. 2007, 7, 3336.
3. Yeganeh, S.; Galperin, M.; Ratner, M. A. J. Am. Chem. Soc. 2007, 129, 13313.
4. Kaasbjerg, K.; Flensberg, K. Nano Lett. 2008, 8, 3809-3814.
5. Moth-Poulsen, K.; Bjørnholm, T. Nat. Nanotechnol. 2009, 24, 551-556.
6. Moth-Poulsen, K.; Bendix, J.; Hammershøj, P.; Bjørnholm, T. Acta Cryst. 2009, C65, 14-16.
7. (a) Albrecht, T.; Moth-Poulsen, K.; Christensen, J. B.; Guckian, A.; Bjoørnholm, T.; Vos, J. G.; Ulstrup, J. Faraday Discuss. 2005, 131, 265.
8. (b) Albrecht, T.; Guckian, A.; Ulstrup, J.; Vos, J. G. Nano Lett. 2005, 5, 1451-1455.
9. Rajadurai, C.; Schramm, F.; Brink, S.; Fuhr, O.; Ghafari, M.; Kruk, R.; Ruben, M. Inorg. Chem. 2006, 45, 10019-10021.
10. Bogani, L.; Wernsdorfer, W. Nat. Mater. 2008, 7, 179-186.
11. Sanvito, S.; Rocha, A. R. J. Comput. Theor. Nanosci. 2006, 3, 624-642, 2006.
12. Lehmann, J.; Gaita-Ariňo, A.; Coronado, E.; Loss, D. Nat. Nanotechnol. 2001, 2, 312-317.
13. Ruben, M.; Landa, A.; Lörtscher, E.; Riel, H.; Mayor, M.; Görls, H.; Weber, H. B.; Arnold, A.; Evers, F. Small 2008, 4, 2229-2235.
14. Park, H.; Lim, A. K. L.; Alivisatos, A. P.; Park, J.; McEuen, P. L. Appl. Phys. Lett. 1999, 75, 301-303.
15. Strachan, D. R.; Smith, D. E.; Johnston, D. E.; Park, T. H.; Therien, M. J.; Bonnell, D. A.; Johnson, A. T. Appl. Phys. Lett. 2005, 86, No.043109.
16. O'Neill, K.; Osorio, E. A.; van der Zant, H. S. J. Appl. Phys. Lett. 2007, 90, 133109.
17. Osorio, E. A.; Bjørnholm, T.; Lehn, J. M.; Ruben, M.; van der Zant, H. S. J. J. phys.: Condens. Matter. 2008, 20, 374121.
18. Goldhaber-Gordon, D.; Shtrikman, H.; Mahalu, D.; AbuschMagder, D.; Meirav, U.; Kastner, M. A. Nature. 1998, 391, 156-159.
19. Cronenwett, S. M.; Oosterkamp, T. H.; Kouwenhoven, L. P. Science 1998, 281, 540-544.
20. Nygard, J.; Cobden, D. H.; Lindelof, P. E. Nature 2000, 408, 342-346.
21. De Franceschi, S.; Sasaki, S.; Elzerman, J. M.; van der Wiel, W. G.; Tarucha, S.; Kouwenhoven, L. P. Phvs. Rev. Lett. 2001, 86, 878-881.
22. Paaske, J.; Rosch, A.; Wölfle, P.; Mason, N.; Marcus, C. M.; Nygård, J. Nat.Phys. 2006, 2, 460-464.
23. Kogan, A.; Granger, G.; Kastner, M. A.; Goldhaber-Gordon, D.; Shtrikman, H. Phys. Rev. B. 2003, 67, 113309.
24. Roch, N.; Florens, S.; Bouchiat, V.; Wernsdorfer, W.; Balestro, F. Nature 2008, 453, 633-637.
25. Borel, A.; Daul, C. A. THEOCHEM 2006, 762, 93-107.
26. Brorson, M.; Schärfer, C. E. Inorg. Chem. 1988, 27, 2522.
27. Lever, A. B. P. Studies on Physical and Theoretical Chemistry: Inorganic Electronic Spectroscopy, 2nd ed.; Elsevier: Amsterdam, 1984.
28. For examples of rare low-spin manganese(II) complexes, see: Bendix, J.; Weyhermüller, T.; Bill, E.; Wieghardt, K. Angew. Chem. Int. Ed. 1999, 38, 2766-2768, and references therein.
29. Braterman, P. S.; Song, J.-I.; Peacock, R. D. Inorg. Chem. 1992, 31, 555.
30. Weinmann, D.; Hausler, H.; Kramer, B. Phys. Rev. Lett. 1995, 74, 984-987.
31. Schleser, R.; Ihn, T.; Ruh, E.; Ensslin, K.; Tews, M.; Pfannkuche, D.; DriscoII, D. C.; Gossard, A. C. Phys. Rev. Lett. 2005, 94, 206805.