Contrasting arsine and phosphine coordination behaviour: Heteroleptic palladium(II) complexes with triphenylarsine and a crown thioether

Main Group Chemistry

Volumn 6, Issue 3-4, 2007, Pages 249-261

  Grant, Gregory J ^a   Biggers, Desireé A ^a   VanDerveer, Donald G ^b  

^a UNIVERSITY OF TENNESSEE AT CHATTANOOGA   (United States)

^b CLEMSON UNIVERSITY   (United States)

Author keywords

1,4,7 Trithiacyclononane; Arsine ligands; Crown thioethers; Palladium complexes; X ray crystal structures

Indexed keywords

EID: 74849087932     PISSN: 10241221     EISSN: 17451167     Source Type: Journal    
DOI: 10.1080/10241220801927767     Document Type: Conference Paper

References (43)

1. A.J. Blake, M. Schröder. Chemistry of thioether macrocyclic complexes. In Advances in Inorganic Chemistry, Vol. 35, A.G. Sykes, (Ed.), pp. 2-80, Academic Press, New York (1990).
2. S.R. Cooper. Crown thioether chemistry. Acc. Chem. Res., 21, 141 (1988).
3. S.R. Cooper, S.C. Rawle. Crown thioether chemistry. Struct. Bond., 72, 1 (1990).
4. M. Schröder. Macrocyclic complexes of the platinum metals. Pure Appl. Chem., 60, 517 (1988).
5. W.N. Setzer, E.L. Cacioppo, Q. Guo, G.J. Grant, D.D. Kim, J.L. Hubbard, D.G. VanDerveer. Synthesis and complexation studies of ten-membered ring trithioethers. Inorg. Chem., 29, 2672 (1990).
6. A.J. Blake, A.J. Holder, T.I. Hyde, Y.V. Roberts, A.J. Lavery, M. Schröder. Structural and electrochemical studies on trithia macrocyclic complexes of palladium. J. Organometal. Chem., 323, 261 (1987).
7. A.J. Blake, R.O. Gould, A.J. Holder, T.I. Hyde, A.J. Lavery, M.O. Odulate, M. Schröder. Stabilization of trivalent platinum by structurally accommodating thiamacrocycles. J. Chem. Soc., Chem. Commun., 118 (1987).
8. A.J. Blake, R.D. Crofts, M. Schröder. Synthesis, structure and electrochemistry of [Pt([10]aneS3) 2](PF6)2. J. Chem. Soc., Dalton Trans., 2259 (1993).
9. G.J. Grant, K.A. Sanders, W.N. Setzer, D.G. VanDerveer. Synthesis and crystal structure of bis(1,4,7-trithiacyclodecane)palladium(II) hexafluorophosphate. Inorg. Chem., 30, 4053 (1991).
10. S. Chandrasekhar, A. McAuley. Evidence for linkage isomerism in the palladium(II) complexes of 1,4,7-trithiacyclodecane. Inorg. Chem., 31, 2663 (1992).
11. G.J. Grant, W. Chen, A.M. Goforth, C.L. Baucom, K. Patel, P. Repovic, D.G. VanDerveer, W.T. Pennington. Anion and solvent effects upon the structures of platinum(II) complexes with thiacrown ligands. Eur. J. Inorg. Chem., 479 (2005).
12. T.W. Hambley. van der Waals Radii of Pt(II) and Pd(II) in molecular mechanics models and an analysis of their relevance to the description of axial M-S Interactions. Inorg. Chem., 37, 3767 (1998).
13. G.J. Grant, A.M. Goforth, D.G. VanDerveer, W.T. Pennington. Homoleptic Pt(II) and Pd(II) complexes of 1,5,9-trithiacyclododecane. Inorg. Chim. Acta, 357, 2107 (2004).
14. G.J. Grant, D.F. Galas, M.W. Jones, K.D. Loveday, W.T. Pennington, G.L. Schimek, C.T. Eagle, D.G. VanDerveer. Platinum group metal complexes of macrocyclic oxathiaethers. Inorg. Chem., 37, 5299 (1998).
15. D.E. Janzen, D.G. VanDerveer, L.F. Mehne, D.A. da Silva Filho, J.-L. Brédas, G.J. Grant. Cyclometallated Pt(II) and Pd(II) complexes with a trithiacrown ligand. J. Chem. Soc., Dalton Trans., 2008; first published as an Advance Article on the RSC website on Jan. 15, 2008, DOI 10.1039/b717910c.
16. G.J. Grant, N.J. Spangler, W.N. Setzer, D.G. VanDerveer, L.F. Mehne. Crown thioether complexes of palladium(II) and platinum(II). Inorg. Chim. Acta, 246, 31 (1996).
17. H. Nikol, H.-B. Bü rgi, K.L. Hardcastle, H.B. Gray. Syntheses and structures of the five-coordinate complexes [M(N-N)(9S3)](PF6)2. Inorg. Chem., 34, 6319 (1995).
18. A.J. Blake, Y.V. Roberts, M. Schröder. Synthesis and structures of half-sandwich palladium(II) complexes of 1,4,7-trithiacyclononane incorporating halide, phosphine, and heterocyclic ligands. J. Chem. Soc. Dalton Trans., 1885 (1996).
19. G.J. Grant, C.G. Brandow, D.F. Galas, J.P. Davis, W.T. Pennington, J.D. Zubkowksi, E.J. Valente. Heteroleptic platinum(II) complexes of macrocyclic thioethers and halides. Polyhedron, 20, 3333 (2001).
20. G.J. Grant, I.M. Poullaos, D.F. Galas, D.G. VanDerveer, J.D. Zubkowski, E.J. Valente. Heteroleptic platinum(II) complexes with crown thioether and phosphine ligands I. Inorg. Chem., 40, 564 (2001).
21. G.J. Grant, S.M. Carter, A.L. Russell, I.M. Poullaos, D.G. VanDerveer. Synthetic, electrochemical, and structural studies on heterobimetallic crown thioether complexes with group 10 metals. J. Organometal. Chem., 637-639, 683 (2001).
22. G.J. Grant, D.F. Galas, D.G. VanDerveer. Heteroleptic platinum(II) complexes with crown thioether and phosphine ligands. Polyhedron, 21, 879 (2002).
23. G.J. Grant, S.M. Carter, I.M. Poullaos, D.G. VanDerveer. Synthetic and Structural studies of platinum(II) complexes containing macrocyclic trithioethers and achiral diphosphine ligands. J. Chem. Soc., Dalton Trans, 15, 2973 (2002).
24. G.J. Grant, J.P. Pool, D.G. VanDerveer. Chiral effects on a fluxional ligand: Chiral diphosphine platinum(II) complexes with thiacrowns. J. Chem. Soc., Dalton Trans., 3981 (2003).
25. G.J. Grant, K.N. Patel, M.L. Helm, L.F. Mehne, D.W. Klinger, D.G. VanDerveer. Heteroleptic platinum(II) complexes with crown thioethers and diimine ligands. Polyhedron, 23, 1361 (2004).
26. T.W. Green, R. Lieberman, N. Mitchell, J.A. Krause Bauer, W.B. Connick. Intramolecular metal-sulfur interactions of platinum(II) 1,4,7-trithiacyclononane complexes with bipyridyl ligands. Inorg. Chem., 44, 1955 (2005).
27. D.E. Janzen, L.F. Mehne, D.G. VanDerveer, G.J. Grant. Cationic five-coordinate Pt(II) complexes as donors in the formation of Pt!Ag dative bonds. Inorg. Chem., 44, 8182 (2005).
28. Cambridge Structural Database v 5.29, November. Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ. U.K (2007).
29. D.R. Allan, A.J. Blake, D. Huang, T.J. Prior, M. Schröder. High pressure coordination chemistry of a palladium thioether complex: Pressure vs. electrons. J. Chem. Soc., Chem. Comm., 4081 (2006).
30. J.E. Huheey, E.A. Keiter, R.L. Keiter. Inorganic Chemistry, 4th edition, p. 292, Harper Collins, New York (1993).
31. J.C. Cloyd Jr., C.A. McAuliffe. Transition metal complexes containing monotertiary arsenines and stibines. In Transition metal complexes of phosphorus, arsenic, and antimony ligands. C.A. McAuliffe (Ed.), p. 205, Wiley, New York (1973).
32. W. Levason, G. Reid. Acyclic arsine, stibine, and bismuthine ligands. In Comprehensive Coordination Chemistry II, Vol. 1, A.B.P. Lever (Ed.), pp. 377-387, Elsevier, Amsterdam (2004).
33. E. Becker, C. Slugvoc, E. Rü ba, C. Standfest-Hauser, K. Mereiter, R. Schmid, K. Kirchner. Synthesis, characterization, and reactivity of half-sandwich Ru(II) complexes containing phosphine, arsine, stibine, and bismuthine ligands. J. Organometal. Chem., 649, 55 (2002).
34. S. Otto, M.H. Johansson. Quantifying the trans effect of triphenylarsine. Inorg. Chim. Acta, 329, 135 (2002).
35. R.H.E. Hudson, A.J. Poe. Systematic kinetic studies of nucleophilic addition to [(m2-H)2Os23(CO)]10. Organometallics, 14, 3238 (1995).
36. G.J. Grant. A convenient synthesis of platinum(II) and palladium(II) dichloro complexes with thiacrown ligands. Inorg. Synth., in review.
37. CrystalClear; Rigaku/MSC, The Woodlands, TX, USA (1999).
38. R.A. Jacobson. REQAB, subroutine of CrystalClear; Rigaku/MSC, The Woodlands, TX, USA (1999).
39. G.M. Sheldrick. SHELXTL 5.1, Bruker AXS, Madison, WI, USA (1998-1999).
40. G.J. Grant, D.A. Biggers, D.G. VanDerveer. Manuscript in preparation.
41. G.L. Miessler, D.A. Tarr. Inorganic Chemistry, 3rd edition, p. 415, Pearson-Prentice Hall, Upper Saddle River, NJ (2004).
42. S.F.A. Kettle. Physical Inorganic Chemistry, a Coordination Chemistry Approach, p. 129, Spektrum Publishers, Oxford (1996).
43. A.J. Blake, R.O. Gould, A.J. Holder, A.J. Lavery, M. Schröder. Copper thioether chemistry. Polyhedron, 9, 2919 (1990).