Chiral effects on a fluxional ligand: Chiral diphosphine platinum(II) complexes with thiacrowns

Journal of the Chemical Society. Dalton Transactions

Volumn , Issue 20, 2003, Pages 3981-3984

  Grant, Gregory J ^a   Pool, Jaime A ^a   VanDerveer, Donald G ^b  

^a UNIVERSITY OF TENNESSEE AT CHATTANOOGA   (United States)

^b GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; CHEMICAL BONDS; CONFORMATIONS; CROWN ETHERS; CRYSTAL STRUCTURE; CRYSTALLIZATION; CRYSTALLOGRAPHY; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL); X RAY ANALYSIS;

CHIRAL DIPHOSPHINE PLATINUM COMPLEXES; CHIRAL EFFECTS; FLUXIONAL LIGAND; THIACROWNS;

PLATINUM COMPOUNDS;

EID: 0242366233     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b306663k     Document Type: Article

References (27)

1. R. Noyori and H. Takaya, Acc. Chem. Res., 1990, 23, 345
2. R. Noyori, Science, 1990, 248, 1194.
3. J. Seyden-Penne, Chiral Auxiliaries and Ligands in Asymmetric Catalysis, Wiley, New York, 1995
4. M. L. Clarke, Polyhedron, 2001, 20, 151.
5. Part IV. G. J. Grant, D. F. Galas, I. M. Poullaos, S. M. Carter and D. G. VanDerveer, J. Chem. Soc., Dalton Trans., 2002, 15, 2973.
6. A. J. Blake, M. Schröder, in Advances in Inorganic Chemistry, ed. A. G. Sykes, Academic Press, Inc., New York, 1990, vol. 35, p. 2
7. M. Schröder, Pure Appl. Chem., 1988, 60, 517.
8. P. Dierkes and P. W. N. M. van Leeuwen, J. Chem. Soc., Dalton Trans., 1999, 1520
9. P. W. N. M. van Leeuwen, P. C. J. Kramer, J. N. H. Reek and P. Dierkes, Chem. Rev., 2000, 100, 2741.
10. G. J. Grant, I. M. Poullaos, D. F. Galas, D. G. VanDerveer, J. D. Zubkowski and E. J. Valente, Inorg. Chem., 2001, 40, 564
11. G. J. Grant, D. F. Galas and D. G. VanDerveer, Polyhedron, 2002, 21, 879
12. G. J. Grant, S. M. Carter, I. M. Poullaos, A. L. Russell and D. G. VanDerveer, J. Organomet. Chem., 2001, 637-639, 683.
13. A. J. Blake, Y. V. Roberts and M. Schröder, J. Chem. Soc., Dalton Trans., 1996, 1885
14. H. Nikol, H.-B. Bürgi, K. I. Hardcastle and H. B. Gray, Inorg. Chem., 1995, 34, 6391
15. E. W. Abel, P. D. Beer, I. Moss, K. G. Orrell, V. Sik, P. A. Bates and M. B. Hurthouse, J. Chem. Soc., Chem. Commun., 1987, 978.
16. G. J. Grant, C. G. Brandow, D. F. Galas, J. P. Davis, W. P. Pennington, J. D. Zubkowski and E. J. Valente, Polyhedron, 2001, 20, 3333.
17. J. E. Huheey, E. A. Keiter, R. L. Keiter, Inorganic Chemistry, Harper Collins, New York, 4th edn., 1993, p. 292.
18. E. J. Corey and J. C. Bailar, J. Am. Chem. Soc., 1956, 81, 2620.
19. -1 lower in energy than the δ.
20. H. Barucki, S. J. Coles, J. F. Costello and M. B. Hursthouse, J. Organometal. Chem., 2001, 622, 265
21. K. Sakai, X.-M. Wu, T. Hata, N Marubayashi and K. Funakoshi, J. Chem. Soc., Perkin Trans. 1, 1991, 2531.
22. N. M. Brunkan, P. S. White and M. R. Gagné, Angew. Chem., Int. Ed., 1998, 37, 1579
23. J. J. Becker, P. S. White and M. R. Gagné, J. Am. Chem. Soc., 2001, 123, 9478.
24. P. S. Pregosin, in Transition Metal Nuclear Magnetic Resonance, ed. P.S. Pregosin, Elsevier, New York, 1991, p. 251; and references cited therein.
25. 13C Nuclear Magnetic Resonance of Transition Metal Phosphine Complexes, ed. P. S. Pregosin and R. W. Kunz, Springer-Verlag, New York, 1979.
26. + 6.01, SHELXTL 5.1, Bruker AXS, Madison, WI, USA, 1998-1999; M. N. Burnett and C. K. Johnson, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations, Report ORNL-6895, Oak Ridge National Laboratory, Oak Ridge, TN, USA, 1996.
27. SADABS, R. H. Blessing, Acta Crystallogr., Sect. A, 1995, 51, 33.