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Volumn 38, Issue 5, 2009, Pages 400-401

Synthesis and X-ray structural analysis of hydrido(thiolato) platinum(II) complexes

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EID: 67650360823     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.2009.400     Document Type: Article
Times cited : (17)

References (24)
  • 1
    • 0001034345 scopus 로고    scopus 로고
    • For reviews on catalytic hydrothiolations, see: a
    • For reviews on catalytic hydrothiolations, see: a) T. Beletskaya, C. Moberg, Chem. Rev. 1999, 99, 3435.
    • (1999) Chem. Rev , vol.99 , pp. 3435
    • Beletskaya, T.1    Moberg, C.2
  • 14
    • 84869358703 scopus 로고    scopus 로고
    • 3: mp 148°C, 1HNMR (C6D6, 400MHz, δ, 1.70 (br s, 24H, 2.00 (br s, 6H, 3,25-3.33 (m, 4H, 6.88-7.00 (m, 18H, 7.58-7.60 (m, 12H, 31P{1H}NMR (C 6D6, 162MHz, δ, 27.0 s, 1J Pt-P, 2827Hz, Anal. Calcd for C58H64P 2PtS2: C, 64.37; H, 5,96, Found: C, 63.68; H, 6.06
    • 2: C, 64.37; H, 5,96%. Found: C, 63.68; H, 6.06%.
  • 15
    • 67650349046 scopus 로고    scopus 로고
    • Crystallographic data have been deposited with Cambridge Crystallo-graphic Data Centre as supplementary publication nos. CCDC-721303 for 3 and CCDC-721304 for 5
    • Crystallographic data have been deposited with Cambridge Crystallo-graphic Data Centre as supplementary publication nos. CCDC-721303 for 3 and CCDC-721304 for 5.
  • 17
    • 84869347974 scopus 로고    scopus 로고
    • 5: mp 136-138°C, 1HNMR (CDC13, 400MHz, δ, 5.96 (dd, 2JP-H, 189, 18 Hz, 1JPt-H= 947 Hz, 1H, 5.28 (s, 1H, 6.91-7.04 (m, 12H, 7.13-7.35 (m, 24H, 7.60-7.64 (m, 6H, 31P{1H)NMR (CDCl3, 162MHz, δ, 23.1 (d, 2JP-P =15 Hz, 1JPt-P, 3189Hz, 32.4 (d. 2JP-P, 15Hz, 2JPt-P, 1963Hz, IR (KBr, v, cm-1, 2100. Anal. Calcd for C 56H44P2PtS·CH2C 12, C, 59.24; H, 4.11, Found: C, 59.29; H, 3.99
    • 12): C, 59.24; H, 4.11%. Found: C, 59.29; H, 3.99%,
  • 19
    • 84869358695 scopus 로고    scopus 로고
    • 6: mp 253-254°C, 1HNMR (CDCl3, 400 MHz, δ, 5.24 (s, 1H, 5.92 (dt, J, 8.1 Hz, 1H, 6.52 (t, J, 8 Hz, 1H, 6.73 (d, J, 7 Hz, 1H, 6.88-6.98 (m, 12H, 7.12-7.40 (m, 18H, 7.62-7.69 (m, 6H, 7.89 (d. J, 8Hz, 2H, 31P{1H}NMR (CDCl3, 162 MHz, δ, 24.5 (d, 2J P-P, 21 Hz, 1JPt-P, 1852 Hz, 26.2 d, 2JP-P, 21 Hz, 1JPt-P, 3183 Hz, Anal, Calcd for C56H42P2PtS: C, 66.99; H, 4.22. Found: C, 66.68;H. 4.11
    • 2PtS: C, 66.99; H, 4.22. Found: C, 66.68;H. 4.11.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.