Synthesis and reactivity of a dithiolate-bridged ruthenium-rhodium heterobimetallic dihydride complex

Organometallics

Volumn 25, Issue 4, 2006, Pages 982-988

  Takemoto, Shin ^a   Shimadzu, Daisuke ^a   Kamikawa, Ken ^a   Matsuzaka, Hiroyuki ^a,b   Nomura, Ryoki ^c  

^a Osaka Prefecture University   (Japan)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^c OSAKA INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; DISSOCIATION; MOLECULAR STRUCTURE; RHODIUM COMPOUNDS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ALKYNES; HETEROBIMETALLIC COMPLEX;

ORGANOMETALLICS;

EID: 33644519027     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050871n     Document Type: Article

References (62)

1. Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby, P. R., Eds.; Wiley-VCH: Weinheim, Germany, 1999.
2. Catalysis by Di- and Polynuclear Metal Cluster Complexes; Adams, R. A., Cotton, F. A., Eds.; Wiley-VCH: New York, 1998.
3. Adams, R. D. Synthesis of Compounds Containing Heteronuclear Metal-Metal Bonds. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 10, Chapter 1, pp 1-22.
4. Rampersad, M. V.; Jeffery, S. P.; Reibenspies, J. H.; Ortiz, C. G.; Darensbourg, D. J.; Darensbourg, M. Y. Angew. Chem., Int. Ed. 2005, 44, 1217-1220.
5. Shin, R. Y. C.; Teo, M. E.; Tan, G. K.; Koh, L. L.; Vittal, J. J.; Goh, L. Y.; Murray, K. S.; Moubaraki, B.; Zhou, X.-Y. Organometallics 2005, 24, 4265-4273.
6. Rao, P. V.; Bhaduri, S.; Jiang, J.; Hong, D.; Holm, R. H. J. Am. Chem. Soc. 2005, 127, 1933-1945.
7. Linck, R. C.; Spahn, C. W.; Rauchfuss, T. B.; Wilson, S. R. J. Am. Chem. Soc. 2003, 125, 8700-8701.
8. Takagi, F.; Seino, H.; Hidai, M.; Mizobe, Y. Organometallics 2003, 22, 1065-1071.
9. Forniés-Cámer, J.; Masdeu-Bultó, A. M.; Claver, C.; Tejel, C.; Ciriano, M. A.; Cardin, C. J. Organometallics 2002, 21, 2609-2618.
10. Sunada, Y.; Hayashi, Y.; Kawaguchi, H.; Tatsumi, K. Inorg. Chem. 2001, 40, 7072-7078.
11. Kuwata, S.; Kabashima, S.; Sugiyama, N.; Ishii, Y.; Hidai, M. Inorg. Chem. 2001, 40, 2034-2040.
12. Casado, M. A.; Pérez-Torrente, J. J.; Ciriano, M. A.; Edwards, A. J.; Lahoz, F. J.; Oro, L. A. Organometallics 1999, 18, 5299-5310.
13. Takemoto, S.; Kuwata, S.; Nishibayashi, Y.; Hidai, M. Inorg. Chem. 1998, 37, 6428-6434.
14. Amador, U.; Delgado, E.; Forniés, J.; Hernández, E.; Lalinde, E.; Moreno, M. T. Inorg. Chem. 1995, 34, 5279-5284.
15. Huang, Y.; Drake, R. J.; Stephan, D. W. Inorg. Chem. 1993, 32, 3022-3028.
16. Rousseau, R.; Stephan, D. W. Organometallics 1991, 10, 3399-3403.
17. Fourmigué, M. Coord. Chem. Rev. 1998, 178, 823-864.
18. Nomura, M.; Kusui, A.; Kajitani, M. Organometallics 2005, 24, 2811-2818.
19. Nihei, M.; Nankawa, T.; Kuribara, M.; Nishihara, H. Angew. Chem., Int. Ed. 1999, 38, 1098-1100.
20. del Rio, I.; Terroba, R.; Cerrada, E.; Hursthouse, M. B.; Laguna, M.; Light, M. E.; Ruiz, A. Eur. J. Inorg. Chem. 2001, 2013-2019.
21. Cai, S.; Wang, J.-Q.; Jin, G.-X. Organometallics 2005, 24, 4226-4231.
22. Chen, Y.-D.; Qin, Y.-H.; Zhang, L.-Y.; Shi, L.-X.; Chen, Z.-N. Inorg. Chem. 2004, 43, 1197-1205.
23. Mashima, K.; Kaneyoshi, H.; Kaneko, S.; Mikami, A.; Tani, K.; Nakamura, A. Organometallics 1997, 16, 1016-1025.
24. Xi, R.; Abe, M.; Suzuki, T.; Nishioka, T.; Isobe, K. J. Organomet. Chem. 1997, 549, 117-125.
25. Takemoto, S.; Oshio, S.; Shiromoto, T.; Matsuzaka, H. Organometallics 2005, 24, 801-804.
26. Takemoto, S.; Kobayashi, T.; Matsuzaka, H. J. Am. Chem. Soc. 2004, 126, 10802-10803.
27. Takemoto, S.; Oshio, S.; Kobayashi, T.; Matsuzaka, H.; Hoshi, M.; Okimura, H.; Yamashita, M.; Miyasaka, H.; Ishii, T.; Yamashita, M. Organometallics 2004, 23, 3587-3589.
28. Takemoto, S.; Ogura, S.; Kamikawa, K.; Matsuzaka, H. Inorg. Chim. Acta, in press.
29. Quebatte, L.; Scopelliti, R.; Severin, K. Angew. Chem., Int. Ed. 2004, 43, 1520-1524.
30. Iwasa, T.; Shimada, H.; Takami, A.; Matsuzaka, H.; Ishii, Y.; Hidai, M. Inorg. Chem. 1999, 38, 2851-2859.
31. For example, see: (a) Suzuki, H.; Kakigano; T.; Tada, K.; Igarashi, M.; Matsubara, K.; Inagaki, A.; Oshima, M.; Takao, T. Bull. Chem. Soc. Jpn. 2005, 78, 67-87.
32. (b) Krogh-Jespersen, K.; Czerw, M.; Summa, N.; Renkema, K. B.; Achord, P. D.; Goldman, A. S. J. Am. Chem. Soc. 2002, 124, 11404-11416.
33. Janowicz, A. H.; Bergman, R. G. J. Am. Chem. Soc. 1982, 104, 352-354.
34. Shiu, K.-B.; Wang, S.-L.; Liao, F.-L.; Chiang, M. Y.; Peng, S.-M.; Lee, G.-H.; Wang, J.-C.; Liou, L.-S. Organometallics 1998, 17, 1790-1797.
35. (a) Cullen, W. R.; Talaba, A.; Rettig, S. J. Organometallics 1992, 11, 1, 3152.
36. (b) Cabeza, J. A.; Maitínez-García, M. A.; Riera, V.; Ardura, D.; García-Granda, S. Organometallics 1998, 17, 1471-1477.
37. Cabeza, J. A.; Martínez-García, M. A.; Riera, V.; Ardura, D.; García-Granda, S.; Van der Maelen, J. F. Eur. J. Inorg. Chem. 1999, 1133, 3-1139.
38. The asymmetric unit contains two crystallographically independent molecules whose structures are essentially identical.
39. For example, see: (a) Conner, D.; Jayaprakash, K. N.; Wells, M. B.; Manzer, S.; Gunnoe, T. B.; Boyle, P. D. Inorg. Chem. 2003, 42, 4759-4772.
40. (b) Menéndez, C.; Morales, D.; Pérez, J.; Riera, V.; Miguel, D. Organometallics 2001, 20, 2775-2781.
41. Touchard, D.; Haquette, P.; Daridor, A.; Romero, A.; Dixneuf, P. H. Organometallics 1998, 17, 3844-3852.
42. (a) Li, C.; Ogasawara, M.; Nolan, S.; Caulton, K. G. Organometallics 1996, 15, 4900-4903.
43. (b) Werner, H.; Baum, M.; Schneider, D.; Windmüller, B. Organometallics 1994, 13, 1089-1097.
44. (a) Bianchini, C.; Peruzzini, M.; Vacca, A.; Zanobini, F. Organometallics 1991, 10, 3697-3707.
45. (b) Bustelo, E.; Carbó, J. J.; Lledós, A.; Mereiter, K.; Puerta, M. C.; Valerga, P. J. Am. Chem. Soc. 2003, 125, 3311-3321.
46. Werner, H.; Garcia Alonso, F. J.; Otto, H.; Wolf, J. Z. Naturforsch., B 1988, 43, 722-726.
47. (a) Berenguer, J. R.; Bernechea, M.; Forniés, J.; Lalinde, E.; Torroba, J. Organometallics 2005, 24, 431-438.
48. (b) Crementieri, S.; Leoni, P.; Marchetti, F.; Marchetti, L.; Pasquali, M. Organometallics 2002, 21, 2575-2577.
49. Jiménez, M. V.; Sola, E.; Martinez, A. P.; Lahoz, F. J.; Oro, L. A. Organometallics 1999, 18, 1125-1136.
50. Smith, A. K. Trinuclear Clusters of Ruthenium and Osmium: (ii) Hydrocarbon Ligands on Metal Clusters. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 7, Chapter 13.2.3, p 772.
51. 3.
52. (a) Hirpo, W.; Curtis, M. D.; Kampf, J. W. Organometallics 1994, 13, 3360-3363.
53. (b) Omori, H.; Suzuki, H.; Morooka, Y. Organometallics 1989, 8, 1576.
54. Campion, B. K.; Heyn, R. H.; Tilley, T. D. Organometallics 1990, 9, 1106-1112.
55. (a) Albers, M. O.; daWaal, D. J.; Lies, D. C.; Robinson, D. J.; Singleton, E.; Wiege, M. B. J. Chem. Soc., Chem. Commun. 1986, 1680.
56. (b) Yi, C. S.; Torres-Lubian, J. R.; Liu, N.; Rheingold, A. L.; Guzei, I. Organometallics 1998, 17, 1257-1259.
57. (a) Kirchner, K.; Calhorda, M. J.; Schmid, R.; Veiros, L. F. J. Am. Chem. Soc. 2003, 125, 11721-11729.
58. (b) Hardesty, J. H.; Koerner, J. B.; Albright, T. A.; Lee, G.-Y. J. Am. Chem. Soc. 1999, 121, 6055-6067.
59. Schunn, R. A.; Wonchoba, E. R. Inorg. Synth. 1971, 13, 131-134.
60. PROCESS-AUTO, Automatic Data Acquisition and Processing Package for Imaging Plate Diffractometer; Rigaku Corp., Tokyo, Japan, 1998.
61. Higashi, T. ABSCOR, Empirical Absorption Correction based on Fourier Series Approximation; Rigaku Corp., Tokyo, Japan, 1995.
62. Sheldrick, G. M. SHELX97, Program for Crystal Structure Determination; University of Göttingen, Göttingen, Germany, 1997.