Photochemical reactivity of gold clusters: dependence on size and spin multiplicity

Langmuir

Volumn 25, Issue 24, 2009, Pages 13888-13893

  Sakamoto, Masanori ^a   Tachikawa, Takashi ^a   Fujitsuka, Mamoru ^a   Majima, Tetsuro ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AU CLUSTERS; DENSITY OF STATE; FERMI WAVELENGTH; GOLD CLUSTERS; NOBLE METAL CLUSTERS; PHOTOCHEMICAL REACTIVITY; SINGLE-MOLECULE FLUORESCENCE SPECTROSCOPY; SPIN MULTIPLICITY;

EXCITED STATES; FLUORESCENCE SPECTROSCOPY; GOLD; PHOTOREACTIVITY; POLYMER FILMS; PRECIOUS METALS; SPIN DYNAMICS;

GOLD COMPOUNDS;

EID: 74049145713     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la901552f     Document Type: Article

References (28)

1. Chen, S.; Ingram, R. S.; Hostetler, M. J.; Pietron, J. J.; Murray, R. W.; Schaaff, T. G; Khoury, J. T.; Alvarez, M. M.; Whetten, R. L. Science 1998, 250, 2098.
2. Peyser, L. A.; Vinson, A. E.; Bartko, A. P.; Dickson, R. M. Science 2001, 297, 103.
3. Haruta, M. Chem. Rec 2003, 3, 75.
4. Lee, T.-H.; Gonzalez, J. I.; Zheng, J.; Dickson, R. M. Acc. Chem. Res. 2005, 35, 534.
5. Branham, M. R.; Douglas, A. D.; Mills, A. J.; Tracy, J. B.; White, P. S.; Murray, R. W. Langmuir 2006, 22,11376.
6. Zheng, J.; Nicovich, P. R.; Dickson, R. M. Annu. Rev. Phys. Chem. 2007, 58, 409.
7. Tsunoyama, H.; Ichikuni, N.; Tsukuda, T. Langmuir 2008, 24, 11327.
8. Rodriguez-Vazquez, M. J.; Blanco, M. C.; Lourido, R.; Vazquez-Vazquez, C.; Pastor, E.; Planes, G. A.; Rivas, J.; López-Quintela, M. A. Langmuir 2008, 24, 12690.
9. Vosch, T.; Antoku, Y.; Hsiang, J.-C.; Richards, C. I.; Gonzalez, J. I.; Dickson, R. M. Proc. Nat. Acad. Sci. U.S.A. 2007, 104, 12616.
10. Lin, C.-A. J.; Yang, T.-Y.; Lee, C.-H.; Huang, S. H.; Sperling, R. A.; Zanella, M.; Li, J. K.; Shen, J.-L.; Wang, H.-H.; Yeh, H.-I.; Parak, W. J.; Chang, W. H. ACS Nano 2009, 3, 395.
11. Diez, I.; Pusa, M.; Kulmala, S.; Jiang, H.; Walther, A.; Goldmann, A. S.; Müller, A. H. E.; Ikkala, O.; Ras, R. H. A. Angew. Chem. 2009, 48, 2122.
12. Sakamoto, M.; Tachikawa, T.; Fujitsuka, M.; Majima, T. J. Am. Chem. Soc. 2009, 131, 6.
13. Zheng, J.; Dickson, R. M. J. Am. Chem. Soc. 2002, 124, 13982.
14. Sakamoto, M.; Fujitsuka, M.; Majima, T. J. Photochem. Photobiol., C 2009, 10, 33.
15. 16,17 Thus, it is concluded that the absorption band of aged PVAc film does not originated from the surface plasmon band of the larger gold nanoparticles ( > 3 nm).
16. Shimizu, T.; Teranishi, T.; Hasegawa, S.; Miyake, M. J. Phys. Chem. B 2003, 107, 2719.
17. Wyrwas, R. B.; Alvarez, M. M.; Khoury, J. T.; Price, R. C.; Schaaff, T. G.; Whetten, R. L. Euro. Phys. J. D 2007, 43, 91.
18. 19,20 implying that m is an odd number. Therefore, m is estimated to be an odd number between 17 and 23.
19. Salisbury, B. E.; Wallace, W. T.; Whetten, R. L. Chem. Phys. Lett. 2000, 262, 131.
20. Yoon, B.; Koskinen, P.; Huber, B.; Kostko, O.; von Issendorff, B.; Häkkinen, H.; Moseler, M.; Landman, U. ChemPhysChem 2007, 8, 157.
21. Teo, B. K.; Zhang, H. Coord. Chem. Rev. 1995, 143, 611.
22. Marcus, R. A.; Eyring, H. Annu. Rev. Phys. Chem. 1964, 15, 155.
23. Kavarnos, G. J.; Turro, N. J. Chem. Rev. 1986, 86, 401.
24. Yip, W.-T.; Hu, D.; Yu, J.; Vanden Bout, D. A.; Barbara, P. F. J. Phys. Chem. A 1998, 102, 7564.
25. Veerman, J. A.; Garcia-Parajo, M. F.; Kuipers, L.; van Hülst, N. F. Phys. Rev. Lett. 1999, 53, 2155.
26. English, D. S.; Furube, A.; Barbara, P. F. Chem. Phys. Lett. 2000, 324, 15.
27. Park, S.-J.; Gesquiere, A. J.; Yu, J.; Barbara, P. F. J. Am. Chem. Soc. 2004, 126, 4116.
28. -.