Ring enlargement of carbohydrate-derived 1,2-Oxazines to enantiopure 5-Bromo-1,2-oxazepines and subsequent palladium-catalyzed reactions

Synthesis

Volumn , Issue 2, 2010, Pages 304-314

  Al Harrasi, Ahmed ^a,b   Fischer, Sebastian ^a   Zimmer, Reinhold ^a   Reissig, Hans Ulrich ^a  

^a FREIE UNIVERSITÄT BERLIN   (Germany)

^b Department of Food Science and Nutrition   (Oman)

Author keywords

1,2 oxazepines; 1,2 oxazines; Alkynes; Carbene additions; Cyclopropanes; Palladium catalysis; Ring enlargement

Indexed keywords

ALKENYL; C-C BOND FORMING; CARBENES; ENANTIOPURE; HECK REACTIONS; PALLADIUM CATALYSIS; PALLADIUM-CATALYZED REACTIONS; RING ENLARGEMENT; SYNTHETIC ELABORATION;

ACETYLENE; CARBOHYDRATES; CATALYSIS; METHANOL; PROPANE;

PALLADIUM;

1,2 OXAZINE DERIVATIVE; 5 BROMO 1,2 OXAZEPINE; ARABINOSE DERIVATIVE; BROMINE DERIVATIVE; CARBENOID; CARBOHYDRATE DERIVATIVE; CARBON; CYCLOPROPANE DERIVATIVE; DIBROMOCARBENE; DIBROMOCYCLOPROPANE; GLYCERALDEHYDE; METHANOL; OXAZEPINE DERIVATIVE; PALLADIUM; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL BOND; HECK REACTION; RING OPENING; SONOGASHIRA REACTION; STILLE REACTION; SUZUKI REACTION; SYNTHESIS;

EID: 73949129201     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1217126     Document Type: Article

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