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Crystal data for 1: For a crystal of dimensions 0.34 x× 0.20 x× 0.11 mm3, a total of 5190 frames were collected with a scan width of 0.5° in w and 0.45° in γ with an exposure time of 20 s frame-1 The structure was solved with formula C111H 178N20O56Cu10Dy2, M r, 3649.16 gmor-1. Triclinic space group P1, aα, 14.8653(10) Å, b, 17.0643(10) Å, c, 17.8253(12) Å, aα, 76.069(1)°, bβ, 87.081(1)°, y γ= 79.311(1)°, V, 3807.0(4) Å3, Z, 1, pcalcd, 1.592mgcm-3, mμ, 2.422 mmr-1, max. and min. transmission 0.7765 and 0.4931, respectively, maximum 2θ, 56.72°, 117140 reflections Rint, 0.0316, 37759 independent reflections, 491 restraints, 1999 parameters, for observed data R 1=0
-
-3.
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69
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73949134394
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Crystal data for 2: For a crystal of dimensions 0.37x 0.10x 0.10 mm3, a total of 3365 frames were collected with a scan width of 0.5° in w and 0.45° in γ with an exposure time of 60s frame-1. The structure was solved with formula C111H 186Cu10La2N20O60, Mr= 3674.02 gmol-1. Hexagonal space group P6222, a, b, 45.328(2) Å, c, 29.754(3) Å, aα=bβ, 90°, yγ, 120°, V, 52943(6) Å3, Z, 12, pcalcd, 1.383 mg cm -3, uμ, 1.730 mm-1, max. and min. transmission 0.8461 and 0.5672, respectively, maximum 2θ, 35.08°, 333062 reflections Rint=0.0888, 11288 independent reflections, 612 restraints, 1227 parameters for observed data R1, 0.0935, wR2
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