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Volumn 5, Issue 1, 2010, Pages 46-49

Chiral metallacrown supramolecular compartments that template nanochannels: self-assembly and guest absorption

Author keywords

Guest absorption; Host guest systems; Metallacrowns molecular; Nanostructures; Recognition

Indexed keywords

CENTRAL METALS; COORDINATION NUMBER; COPPER ATOMS; CRYSTALLINE SOLIDS; ENANTIOSELECTIVE SEPARATION; HIGH AFFINITY; HOST-GUEST SYSTEM; HOSTGUEST CHEMISTRY; LANTHANIDES; MESOSTRUCTURES; METALLACROWNS MOLECULAR; MOLECULAR NANOSTRUCTURES; NANO CHANNELS; NLO MATERIALS;

EID: 73949111712     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200900612     Document Type: Article
Times cited : (51)

References (78)
  • 1
    • 0024279870 scopus 로고
    • a) D. J. Cram, Science 1988, 240, 760;
    • (1988) Science , vol.240 , pp. 760
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  • 68
    • 73949117534 scopus 로고    scopus 로고
    • Crystal data for 1: For a crystal of dimensions 0.34 x× 0.20 x× 0.11 mm3, a total of 5190 frames were collected with a scan width of 0.5° in w and 0.45° in γ with an exposure time of 20 s frame-1 The structure was solved with formula C111H 178N20O56Cu10Dy2, M r, 3649.16 gmor-1. Triclinic space group P1, aα, 14.8653(10) Å, b, 17.0643(10) Å, c, 17.8253(12) Å, aα, 76.069(1)°, bβ, 87.081(1)°, y γ= 79.311(1)°, V, 3807.0(4) Å3, Z, 1, pcalcd, 1.592mgcm-3, mμ, 2.422 mmr-1, max. and min. transmission 0.7765 and 0.4931, respectively, maximum 2θ, 56.72°, 117140 reflections Rint, 0.0316, 37759 independent reflections, 491 restraints, 1999 parameters, for observed data R 1=0
    • -3.
  • 69
    • 73949134394 scopus 로고    scopus 로고
    • Crystal data for 2: For a crystal of dimensions 0.37x 0.10x 0.10 mm3, a total of 3365 frames were collected with a scan width of 0.5° in w and 0.45° in γ with an exposure time of 60s frame-1. The structure was solved with formula C111H 186Cu10La2N20O60, Mr= 3674.02 gmol-1. Hexagonal space group P6222, a, b, 45.328(2) Å, c, 29.754(3) Å, aα=bβ, 90°, yγ, 120°, V, 52943(6) Å3, Z, 12, pcalcd, 1.383 mg cm -3, uμ, 1.730 mm-1, max. and min. transmission 0.8461 and 0.5672, respectively, maximum 2θ, 35.08°, 333062 reflections Rint=0.0888, 11288 independent reflections, 612 restraints, 1227 parameters for observed data R1, 0.0935, wR2
    • -3.
  • 70
    • 73949152206 scopus 로고    scopus 로고
    • 222.
    • 222.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.