Studies on copper(II), cobalt (II) and nickel (II) picrate complexes with the ligand 1,3-bis(2-benzimidazyl)- 2-thiapropane

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 39, Issue 10, 2009, Pages 629-632

  Wu, Huilu ^a   Wang, Kaitong ^a   Yun, Ruirui ^a   Huang, Xingcai ^a   Li, Ke ^a   Sun, Tao ^a  

^a LANZHOU JIAOTONG UNIVERSITY   (China)

Author keywords

1,3 bis(2 benzimidazyl) 2 thiapropane; Cyclic voltammograms; Synthesis; Transition metal complexes

Indexed keywords

EID: 73549084266     PISSN: 15533174     EISSN: 15533182     Source Type: Journal    
DOI: 10.1080/15533170903433055     Document Type: Article

References (22)

1. Foster, C.J., Kilmer, C.A., Thornton-Pett, M., and Halcrow, M.A. Steric effects on the stereochemistry of copper complexes of 2,6-bis(pyrazol-1- ylmethyl)pyridines. Polyhedron. 2002, 21, 1031-1041.
2. Ismail, M.A., Brun, R., Wenzler, T., Tanious, F.A., Wilson, W.D., and Boykin, D.W. Dicationic biphenyl benzimidazole derivatives as antiprotozoal agents. Bioorg. Med. Chem. 2004, 12, 5405-5413.
3. MacDonald, L.M., Armson, A., Thompson, R.C.A., and Reynoldson, J.A. Characterisation of benzimidazole binding with recombinant tubulin from Giardia duodenalis, Encephalitozoon intestinalis, and Cryptosporidium parvum and Cryptosporidium parvum. Biochem Parasitol. 2004, 138, 89-96.
4. Delescluse, C., Piechock, M.P., Ledirac, N., Hines, R.H., Li, R., Gidrol, X., and Rahmani, R. Induction of cytochrome P450 1A1 gene expression, oxidative stress, and genotoxicity by carbaryl and thiabendazole in transfected human HepG2 and lymphoblastoid cells. Biochem Pharmacol. 2001, 61, 399-407.
5. Agh-Atabay, N.M., Dulger, B., and Gucin, F. Structural characterization and antimicrobial 1,3-bis(2-benzimidazyl)-2-thiapropane ligand and its Pd(II)and Zn(II) halide complexes. Eur. J. Med. Chem. 2005, 40, 1096-1102.
6. Monthilal, K.K., Karunakaran, C., Rajendran, A., and Murugesan, R. Synthesis, X-ray crystal structure, antimicrobial activity and photodynamic effects of some thiabendazole complexes. J. Inorg. Biochem. 2004, 98, 322-332.
7. Orjales, A., Mosquera,R., Toledo, A., Pumar, C., and Labeaga, L. Innerarity, A. New3-benzisothiazolyl and 3-benzisoxazolylpiperazine derivativeswith atypical antipsychotic binding profile. Eur. J. Med. Chem. 2002, 37, 721-730.
8. Agh-Atabay, N.M., Dulger, B., and Gucin, F. Synthesis and investigation of antimicrobial activity of some bisbenzimidazole-derived chelating agents. Eur.J. Med. Chem. 2003, 38, 875-881.
9. Agh-Atabay, N.M., Metin, Tulu., Yaghub, M.,Mehmet, S., and Basaran, D. FT-Raman, FT-IR and NMR spectra, vibrational assignments and density functional studies of 1,3-bis(benzimidazol-2-yl)-2-thiapropane ligand and its Zn(II) halide complexes. Struct. Chem. 2008, 19, 21-32.
10. Matthews, C.J., Leese, T.A., Thorp, D., and Lockhart, J.C. Three-phase transport studies of benzimidazole ligands bearing hydrophobic N-alkyl substituents: transport of metal(II) ions (Ni, Cu, Zn, Cd) in singleand multiple-ion experiments. J. Chem. Soc., Dalton Trans. 1998, 79-88.
11. Agh-Atabay, N.M., Baykal, A., and Somer, M. Synthesis and characterisation of 1,3-bis(2-benzimidazyl)-2-thiapropane,1,5-bis(2- benzimidazyl)- 3-thiapentane ligands and their PdCl2 complexes. Trans. Met. Chem. 2004, 29, 159-163.
12. Geary, W.J. The use of conductivity measurements in organic solvents for the characterization of coordination compounds. Coord. Chem. Rev. 1971, 7, 81-122.
13. Zhou, W.H., Miao, Z.W., Liu X.L., Miao, F.M., Wang, H.G., and Yao, X.K. Synthesis, crystal structure and PM3 quantum chemistry study of monohydrated multidentate ligand tris(2-benzimidazylmethyl)amine. Chin. J. Struct. Chem. 1999, 18(3), 204-207.
14. Su, C.Y., Kang, B.S., Du, C.X., Yang, Q.C., and Mak, T.C.W. Formation of mono-, bi-, and tetranuclear Ag(I) complexes of C3-symmetric tripodal benzimidazole ligands. Inorg. Chem. 2000, 39, 4843-4849.
15. Lane, T.J., Nakagawa, I., Walter, J.L., and Kandathil, A.J. Infrared investigation of certain imidazole derivatives and their metal chelates. Inorg. Chem. 1962, 1, 267-276.
16. McKee, M., Zvagulis, M., and Reed, C.A. Furthur insight into magneto structure correlations in binuclear copper (II) species related to methemocyanin: X-ray crystal structure of a 1,2-mnitrito complex. Inorg. Chem. 1985, 24, 2914-2919.
17. Wu, H.L., Sun, T., Li, K., Xu, Y.H., and Yun, R. Synthesis, crystal structure, and characterization of two novel five-coordinate zinc(II) complexes with the tripod ligand tris(N-methylbenzimidazol-2-yl-methyl)amine and á, â-unsaturated carboxylates. Z. Anorg. Allg. Chem. 2009, 635, 146-150.
18. Thompson, L.K., Ramaswamy, B.S., and Seymour, E.A. Cobalt (11) and zinc (11) complexes of the tripod ligand tris(2-benzimidazylmethy1)amine. Some five-coordinate derivatives and some with mixed stereochemistriesl. Can. J. Chem. 1977, 55, 878-888.
19. Thompson, L.K., Ramaswamy, B.S., and Dawe, R.D. Nickel (I1) and copper( I1) complexes of the tripod ligand tris(2-benzimidazylmethy1)amine. Can. J. Chem. 1978, 56,1311-1318.
20. Addison, A.W., Hendriks, H.M.J., Reedije, J., and Thompson, L.K. Copper complexes of the tripod ligand tris(2-benzimidazolylmethyl)amine: five and six-coordinate copper(II) derivatives and copper(I) derivatives. Inorg. Chem. 1981, 20, 103-110.
21. Valentine, J.S., and Defreitas, D.M. Copper-zinc superoxide dismutase a unique biological ligand for bioinorganic studies. J. Chem. Educ. 1985, 62, 990-997.
22. Richardson, D.C., Thomas, K.A., Silevrton, E.W., and Davies, D.R. Similarity of three-dimensional structure between the immunoglobulin domain and the copper, zinc superoxide dismutase subunit. J. Mol. Biol. 1976, 102(2), 221-235.