Sol-gel synthesis, porous structure, and mechanical property of polymethylsilsesquioxane aerogels

Journal of the Ceramic Society of Japan

Volumn 117, Issue 1372, 2009, Pages 1333-1338

  Kanamori, Kazuyoshi ^a   Nakanishi, Kazuki ^a   Hanada, Teiichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Aerogels; Mechanical property; Nitrogen adsorption; Organic inorganic hybrid; Porous structure; Small angle X ray scattering (SAXS); Sol gel

Indexed keywords

AEROGELS; GAS ADSORPTION; HYDROLYSIS; MECHANICAL PROPERTIES; MORPHOLOGY; NITROGEN; PHASE SEPARATION; POROSITY; SURFACE ACTIVE AGENTS; UREA; X RAY SCATTERING;

COMPRESSIVE MECHANICAL PROPERTIES; MACROSCOPIC PHASE SEPARATION; NITROGEN ADSORPTION; ORGANIC-INORGANIC HYBRID; ORGANIC-INORGANIC HYBRID AEROGELS; POLYMETHYLSILSESQUIOXANE; POROUS STRUCTURES; TWO STEP SOL GEL PROCESS;

SOL-GEL PROCESS;

EID: 73049110517     PISSN: 18820743     EISSN: 13486535     Source Type: Journal    
DOI: 10.2109/jcersj2.117.1333     Document Type: Article

References (33)

1. J. Fricke and A. Emmerling, J. Am. Ceram. Soc., 75, 2027-2036 (1992).
2. N. Hüsing and U. Schubert, Angew. Chem. Int. Ed., 37, 22-45 (1998).
3. A. C. Pierre and G. M. Pajonk, Chem. Rev., 102, 4243-4265 (2002).
4. S. Hæreid, J. Anderson, M. A. Einarsrud, D. W. Hua and D. M. Smith, J. Non-Cryst. Solids, 185, 221-226 (1995).
5. S. Hæreid, M. Dahle, S. Lima and M. A. Einarsrud, J. NonCryst. Solids, 186, 96-103 (1995).
6. G. Reichenauer, J. Non-Cryst. Solids, 350, 189-195 (2004).
7. B. M. Novak, D. Auerbach and C. Verrier, Chem. Mater., 6, 282-286 (1994).
8. N. Hüsing and U. Schubert, J. Sol-Gel Sci. Tech., 8, 807-812 (1997).
9. H. El Rassy, P. Buisson, B. Bouali, A. Perrard and A. C. Pierre, Langmuir, 19, 358-363 (2003).
10. A. Venkateswara Rao, S. D. Bhagat, H. Hirashima and G. M. Pajonk, J. Colloid Interface Sci., 300, 279-285 (2006).
11. N. Leventis, Acc. Chem. Res., 40, 874-884 (2007).
12. A. Fidalgo, J. P. S. Farinha, J. M. G. Martinho, M. E. Rosa and L. M. Ilharco, Chem. Mater., 19, 2603-2609 (2007).
13. T.-Y. Wei, S.-Y. Lu and Y.-C. Chang, J. Phys. Chem. B, 112, 11881-11886 (2008).
14. K. Kanamori, M. Aizawa, K. Nakanishi and T. Hanada, Adv. Mater., 19, 1589-1593 (2007).
15. K. Kanamori, M. Aizawa, K. Nakanishi and T. Hanada, J. Sol- Gel Sci. Tech., 48, 172-181 (2008).
16. K. Kanamori, H. Yonezawa, K. Nakanishi, K. Hirao and H. Jinnai, J. Sep. Sci., 27, 874-886 (2004).
17. K. S. W. Sing, Carbon, 27, 5-11 (1989).
18. A. Saito and H. Foley, AIChE J., 37, 429-436 (1991).
19. M. Kruk, V. Antochshuk and M. Jaroniec, J. Phys. Chem. B, 103, 10670-10678 (1999).
20. M. Meyer, A. Fischer and H. Hoffmann, J. Phys. Chem. B, 106, 1528-1533 (2002).
21. D. W. Schaefer and K. D. Keefer, Phys. Rev. Lett., 56, 2199-2202 (1986).
22. A. Emmerling and J. Fricke, J. Non-Cryst. Solids, 145, 113-120 (1992).
23. M. D. Haw, M. Sievwright, W. C. K. Poon and P. N. Pusey, Physica A, 217, 231-260 (1995).
24. W. C. K. Poon and M. D. Haw, Adv. Colloid Interface Sci., 73, 71-126 (1997).
25. D. W. Shaefer, R. Pekala and G. Beaucage, J. Non-Cryst. Solids, 186, 159-167 (1995).
26. G. Reichenauer, A. Emmerling, J. Fricke and R. W. Pekala, J. Non-Cryst. Solids, 225, 210-214 (1998).
27. O. Barbieri, F. Ehrburger-Dolle, T. P. Rieker, G. M. Pajonk, N. Pinto and A. V. Rao, J. Non-Cryst. Solids, 285, 109-115 (1998).
28. G. Reichenauer and G. W. Scherer, Colloids Surf. A, 187-188, 41-50 (2001).
29. K. Kaneko, C. Ishii, M. Ruike and H. Kuwabara, Carbon, 30, 1075-1088 (1992).
30. C. J. Brinker and G. W. Scherer, in "Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing," Academic Press, San Diego (1990) pp. 194-203.
31. T. Asakawa, H. Kitano, A. Ohta and S. Miyagishi, J. Colloid Interface Sci., 242, 284-287 (2001).
32. S. Yang, P. A. Mirau, C.-S. Pai, O. Nalamasu, E. Reichmanis, E. K. Lin, H.-J. Lee, D. W. Gidley and J. Sun, Chem. Mater., 13, 2762-2764 (2001).
33. P. A. Mirau and S. Yang, Chem. Mater., 14, 249-255 (2002).