메뉴 건너뛰기




Volumn 48, Issue 23, 2009, Pages 10859-10861

Ag(I)-Mediated in situ dehydrogenative coupling of 3-amino-1,2,4-triazole into 3,3′-Azobis(1,2,4-triazole) in Cd(II) coordination polymers

Author keywords

[No Author keywords available]

Indexed keywords

3,3' AZOBIS(1,2,4 TRIAZOLE); 3,3'-AZOBIS(1,2,4-TRIAZOLE); AMITROLE; CADMIUM; ORGANOMETALLIC COMPOUND; POLYMER; SILVER; TRIAZOLE DERIVATIVE;

EID: 72949090226     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9007813     Document Type: Article
Times cited : (21)

References (31)
  • 19
    • 72949124729 scopus 로고    scopus 로고
    • Synthesis: for 1, a mixture of HAmTAZ (0.053 g, Cd(NO3),·4H 2O (0.087 g, AgCl (0.033 g, andmixed solvents H2O (8.5 mL)/NH3 · H2O (25, 5 mL) was sealed in a Teflon-lined reaction vessel; for a mixture of 1 and 2, a mixture of HAmTAZ (0.052 g, Cd(NO3)2·H2O (0.065 g, AgCl (0.026 g, and mixed solvents H2O (8.5 mL)/NH3 · H2O (25, 5 mL, for 3, a mixture of HAmTAZ (0.084 g, Cd(NO 3)2·4H2O (0.065 g, AgCl (0.062 g, and mixed solvents H2O (8.5 mL)/NH3·H2O (25, 5 mL) was sealed in a Teflon-lined reaction vessel. These vessels were heated at 130 °C for 60 h and then cooled to room temperature during 48 h. Red and yellow crystals of 1 (yield, 36% based on Cd) and 2 (yield, 12% based on Cd) and orange crystals of 3 (yield, 57% based on Cd) were isolated from yellow fil
    • 16 3: C, 14.55; H, 1.83; N, 33.93. Found: C, 14.43; H, 2.03; N, 33.35%.
  • 20
    • 72949102942 scopus 로고    scopus 로고
    • U.S. Patent 46 623 409A, 1986
    • (a) Lee, K. Y. U.S. Patent 46 623 409A, 1986.
    • Lee, K.Y.1
  • 23
    • 72949121569 scopus 로고    scopus 로고
    • 2) = 0.0221 (0.0687) and S = 1.009 for 1645 reflections with I > 2σ(I).
    • 2) = 0.0221 (0.0687) and S = 1.009 for 1645 reflections with I > 2σ(I).
  • 24
    • 72949108114 scopus 로고    scopus 로고
    • 2) = 0.0200 (0.0378) and S = 1.166 for 890 reflections with I > 2σ(I).
    • 2) = 0.0200 (0.0378) and S = 1.166 for 890 reflections with I > 2σ(I).
  • 25
    • 72949102715 scopus 로고    scopus 로고
    • Crystal data for 3: C8H12Ag 2CdN16, Mr, 660.48, triclinio, space group P1, a, 6.6021(3) Å, b, 6.6711(5) Å, c, 9.6337(3) Å, α, 70.08(3)°, β, 71.84(2)°, γ, 87.15(3)°, V, 378.28(4) Å3, Z= 1, T= 293(2) K, Dc, 2.899 g cm-3, R(int, 0.0231,3023 reflections collected, R1 (WR2, 0.0379 (0.0922) and S, 1.051 for 1480 reflections with I > 2σI
    • 2) = 0.0379 (0.0922) and S = 1.051 for 1480 reflections with I > 2σ(I).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.