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72949124729
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Synthesis: for 1, a mixture of HAmTAZ (0.053 g, Cd(NO3),·4H 2O (0.087 g, AgCl (0.033 g, andmixed solvents H2O (8.5 mL)/NH3 · H2O (25, 5 mL) was sealed in a Teflon-lined reaction vessel; for a mixture of 1 and 2, a mixture of HAmTAZ (0.052 g, Cd(NO3)2·H2O (0.065 g, AgCl (0.026 g, and mixed solvents H2O (8.5 mL)/NH3 · H2O (25, 5 mL, for 3, a mixture of HAmTAZ (0.084 g, Cd(NO 3)2·4H2O (0.065 g, AgCl (0.062 g, and mixed solvents H2O (8.5 mL)/NH3·H2O (25, 5 mL) was sealed in a Teflon-lined reaction vessel. These vessels were heated at 130 °C for 60 h and then cooled to room temperature during 48 h. Red and yellow crystals of 1 (yield, 36% based on Cd) and 2 (yield, 12% based on Cd) and orange crystals of 3 (yield, 57% based on Cd) were isolated from yellow fil
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16 3: C, 14.55; H, 1.83; N, 33.93. Found: C, 14.43; H, 2.03; N, 33.35%.
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20
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72949102942
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U.S. Patent 46 623 409A, 1986
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23
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72949121569
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2) = 0.0221 (0.0687) and S = 1.009 for 1645 reflections with I > 2σ(I).
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2) = 0.0221 (0.0687) and S = 1.009 for 1645 reflections with I > 2σ(I).
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-
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24
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72949108114
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2) = 0.0200 (0.0378) and S = 1.166 for 890 reflections with I > 2σ(I).
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2) = 0.0200 (0.0378) and S = 1.166 for 890 reflections with I > 2σ(I).
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25
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72949102715
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Crystal data for 3: C8H12Ag 2CdN16, Mr, 660.48, triclinio, space group P1, a, 6.6021(3) Å, b, 6.6711(5) Å, c, 9.6337(3) Å, α, 70.08(3)°, β, 71.84(2)°, γ, 87.15(3)°, V, 378.28(4) Å3, Z= 1, T= 293(2) K, Dc, 2.899 g cm-3, R(int, 0.0231,3023 reflections collected, R1 (WR2, 0.0379 (0.0922) and S, 1.051 for 1480 reflections with I > 2σI
-
2) = 0.0379 (0.0922) and S = 1.051 for 1480 reflections with I > 2σ(I).
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26
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35148847345
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