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Volumn 28, Issue 22, 2009, Pages 6462-6468

Contacted ion-pair lithium alkylamidoaluminates: Intramolecular alumination (Al-H exchange) traps for TMEDA and PMDETA

Author keywords

[No Author keywords available]

Indexed keywords

BASE COMPONENTS; BRIDGING LIGANDS; CYCLOHEXANE SOLUTIONS; HETEROBIMETALLICS; INTRAMOLECULAR COMMUNICATION; ION PAIRS; LITHIUM CATIONS; PROXIMITY EFFECTS;

EID: 72449160612     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900736a     Document Type: Article
Times cited : (30)

References (63)
  • 4
    • 38849134892 scopus 로고    scopus 로고
    • This is in contrast to most TMP-zincate bases which exhibit twostep DoM. see: Nobuto, D.; Uchiyama, M. J. Org. Chem. 2008, 73, 1117,
    • (2008) J. Org. Chem. , vol.73 , pp. 1117
    • Nobuto, D.1    Uchiyama, M.2
  • 15
    • 0004219714 scopus 로고    scopus 로고
    • Schlosser, M., Ed. 2nd ed. Wiley: New York
    • (c) Schlosser, M., Ed. Organometallics in Synthesis-A Manual 2nd ed.; Wiley: New York, 2002.
    • (2002) Organometallics in Synthesis-A Manual
  • 25
    • 0003417469 scopus 로고
    • Trost, B. M., Fleming, I., Eds. Pergamon Press: New York
    • (c) Trost, B. M., Fleming, I., Eds. in Comprehensive Organic Synthesis; Pergamon Press: New York, 1991.
    • (1991) Comprehensive Organic Synthesis
  • 27
    • 0001386975 scopus 로고
    • For an enlightening discussion on the role of TMEDA in group 1 chemistry, see: (a) Collum, D. B. Acc. Chem. Rev. 1992, 25, 448.
    • (1992) Acc. Chem. Rev. , vol.25 , pp. 448
    • Collum, D.B.1
  • 28
    • 0004085598 scopus 로고
    • Advances in Chemistry Series; American Chemical Society: Washington, DC
    • See also: (b) Langer, A. W. Polyamine-Chelate Alkali Metal Compounds; Advances in Chemistry Series; American Chemical Society: Washington, DC, 1974; p 130.
    • (1974) Polyamine-chelate Alkali Metal Compounds , pp. 130
    • Langer, A.W.1
  • 53
    • 72449158584 scopus 로고    scopus 로고
    • Long reaction times at room temperature (48 h) or refluxing conditions (hexane or toluene) only yield 4 as the major product
    • Long reaction times at room temperature (48 h) or refluxing conditions (hexane or toluene) only yield 4 as the major product.
  • 54
    • 72449164322 scopus 로고    scopus 로고
    • 3)] showed that in solution the three isobutyl groups appear equivalent, suggesting that these Li ... C bonds are forming/breaking fast in the NMR time scale, seeref 1b
    • 3)] showed that in solution the three isobutyl groups appear equivalent, suggesting that these Li ... C bonds are forming/breaking fast in the NMR time scale, seeref 1b.
  • 55
    • 72449164792 scopus 로고    scopus 로고
    • 3] has been previously reported by us in ref 5
    • 3] has been previously reported by us in ref 5.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.