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although the second step can be inhibited by coordination saturation at the zinc center, see: Clegg, W.; Conway, B.; Graham, D. V.; Hevia, E.; Kennedy, A. R.; Mulvey, R. E.; Russo, L.; Wright, D. S. Chem.-Eur. J. 2009, 15, 7074.
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2] have been previously described by us in: Garcia-Alvarez, J.; Hevia, E.; Kennedy, A. R.; Klett, J.; Mulvey, R. E. Chem. Commun. 2007, 2402.
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72449158584
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Long reaction times at room temperature (48 h) or refluxing conditions (hexane or toluene) only yield 4 as the major product
-
Long reaction times at room temperature (48 h) or refluxing conditions (hexane or toluene) only yield 4 as the major product.
-
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54
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72449164322
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-
3)] showed that in solution the three isobutyl groups appear equivalent, suggesting that these Li ... C bonds are forming/breaking fast in the NMR time scale, seeref 1b
-
3)] showed that in solution the three isobutyl groups appear equivalent, suggesting that these Li ... C bonds are forming/breaking fast in the NMR time scale, seeref 1b.
-
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55
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72449164792
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3] has been previously reported by us in ref 5
-
3] has been previously reported by us in ref 5.
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56
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