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Volumn 48, Issue 52, 2009, Pages

Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: Intercyelobutadiene metal migration

Author keywords

Ab initio calculations; Arene ligands; Haptotropism; Isomerization; Photochemistry

Indexed keywords

AB INITIO CALCULATIONS; ARENE LIGANDS; ARENE RINGS; CYCLOBUTADIENES; METAL MIGRATIONS; PHOTO-THERMAL;

EID: 72449136275     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200905088     Document Type: Article
Times cited : (19)

References (49)
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    • (Eds.: H. Dürr, H. Bouas-Laurent), Elsevier, Amsterdam
    • h) Photochromism, Molecules and Systems (Eds.: H. Dürr, H. Bouas-Laurent), Elsevier, Amsterdam, 2003.
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    • (Ed.: V. W. W Yam), Springer, Berlin
    • For selected reviews, see: a) Photofunctional Transition Metal Complexes (Ed.: V. W. W Yam), Springer, Berlin, 2007;
    • (2007) Photofunctional Transition Metal Complexes
  • 19
    • 44649184558 scopus 로고    scopus 로고
    • For a recent review of metallohaptotropism, see: a) I. D. Gridnev, Coord. Chem. Rev. 2008, 252,1798; for the only examples of dimetallo photo-thermal haptotropism, see:
    • (2008) Coord. Chem. Rev. , vol.252 , pp. 1798
    • Gridnev, I.D.1
  • 27
    • 72449176700 scopus 로고    scopus 로고
    • w = 0.2042. CCDC 746176 (5) and 746177 (6) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
  • 32
    • 0001653562 scopus 로고
    • c) B. E. Bursten, R. F. Fenske, Inorg. Chem. 1979, 18, 1760; for this effect in [(benzocyclobutadiene)CpCo], see:
    • (1979) Inorg. Chem. , vol.18 , pp. 1760
    • Bursten, B.E.1    Fenske, R.F.2
  • 35
    • 1842608370 scopus 로고    scopus 로고
    • The observed relatively large chemical shifts of the arene hydrogens are minimal values, since the magnetic anisotropy of {CpCo} in this area of space is (if anything) shielding. For selected references, see ref. [10d] and: a) A. G Myers, M. Sogi, M. A. Lewis, S. P. Arvedson, J. Org. Chem. 2004, 69, 2516;
    • (2004) J. Org. Chem. , vol.69 , pp. 2516
    • Myers, A.G.1    Sogi, M.2    Lewis, M.A.3    Arvedson, S.P.4
  • 42
    • 70349310080 scopus 로고    scopus 로고
    • d) A. C Tsipis, Phys. Chem. Chem. Phys. 2009, 11,8244; for a recent appraisal of the concept of aromaticity, see :
    • (2009) Phys. Chem. Chem. Phys. , vol.11 , pp. 8244
    • Tsipis, A.C.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.