Kinetic study of heterogeneous ozonolysis of alachlor, trifluralin and terbuthylazine adsorbed on silica particles under atmospheric conditions

Atmospheric Environment

Volumn 43, Issue 35, 2009, Pages 5597-5603

  Pflieger, Maryline ^a   Monod, Anne ^a   Wortham, Henri ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

Author keywords

Flow reactor; Ozone; Pesticide; Semi volatile organic compound; Silica particles

Indexed keywords

ALACHLOR; ATMOSPHERIC CONDITIONS; ATMOSPHERIC LIFETIME; EXPERIMENTAL DATA; EXPERIMENTAL SETUP; FLOW REACTOR; FLOW REACTORS; GAS/SOLID ADSORPTION; KINETIC STUDY; LANGMUIR-HINSHELWOOD MODELS; LANGMUIRS; MINERAL PARTICLES; OZONE CONCENTRATION; OZONOLYSIS; SEMIVOLATILE ORGANIC COMPOUNDS; SILICA PARTICLES; TERBUTHYLAZINE; TRIFLURALIN;

ADSORPTION; AGRICULTURAL CHEMICALS; ATMOSPHERIC MOVEMENTS; DEGRADATION; HERBICIDES; SILICA; VOLATILE ORGANIC COMPOUNDS;

OZONE;

ALACHLOR; SILICON DIOXIDE; TERBUTYLAZINE; TRIFLURALIN;

ADSORPTION; ALACHLOR; DEGRADATION; KINETICS; OZONE; PESTICIDE; SILICA; TRIFLURALIN; VOLATILE ORGANIC COMPOUND;

ADSORPTION KINETICS; ARTICLE; ATMOSPHERIC DISPERSION; CHEMICAL REACTION; CONCENTRATION RESPONSE; CONTROLLED STUDY; DEGRADATION; EQUILIBRIUM CONSTANT; OZONOLYSIS; PRIORITY JOURNAL; SIMULATION; UPFLOW REACTOR;

EID: 71749094880     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2009.07.064     Document Type: Article

References (39)

1. Alebic-Juretic A., Cvita T., and Klasinc L. Kinetics of heterogeneous ozone reactions. Chemosphere 41 (2000) 667-670
2. Ammann M., Pöschl U., and Rudich Y. Effects of reversible adsorption and Langmuir-Hinshelwood surface reactions on gas uptake by atmospheric particles. Physical Chemistry Chemical Physics 5 (2003) 351-356
3. Aston L.S., and Seiber J.N. Fate of summertime airborne organophosphate pesticide residues in the Sierra Nevada Mountains. Journal of Environmental Quality 26 (1997) 1483-1492
4. Atkinson R., Guicherit R., Hites R.A., Palm W.U., Seiber J.N., and De Voogt P. Transformations of pesticides in the atmosphere: a state of the art. Water, Air, and Soil Pollution 115 (1999) 219-243
5. Bidleman T.F. Atmospheric processes. Environmental Science and Technology 22 (1988) 361-367
6. Bidleman T.F. Atmospheric transport and air-surface exchange of pesticides. Water, Air, and Soil Pollution 115 (1999) 115-166
7. C.I.L. (Cluzeau Info Labo), 2005. Security Data of Pesticides, PCB, PBB, HPA. CD-Rom.
8. Coupe R.H., Manning M.A., Foreman W.T., Goolsby D.A., and Majewski M.S. Occurrence of pesticides in rain and air in urban and agricultural areas of Mississippi, April-September 1995. Science of the Total Environment 248 (2000) 227-240
9. 2 and OH radicals with polycyclic aromatic hydrocarbons adsorbed on carbonaceous particles. Part 2: PAHs adsorbed on diesel particulate exhaust SRM 1650a. Atmospheric Environment 40 (2006) 201-211
10. Finlayson-Pitts B.J., and Pitts Jr. J.N. Chemistry of the Upper and Lower Atmosphere: Theory, Experiments and Applications (2000), Academic Press, USA
11. Genualdi S.A., Killin R.K., Woods J., Wilson G., Schmedding D., and Simonich S.L.M. Trans-Pacific and regional atmospheric transport of polycyclic aromatic hydrocarbons and pesticides in biomass burning emissions to Western North America. Environment, Science and Technology 43 (2009) 1061-1066
12. Glotfelty D.E., Leech M.M., Jersey J., and Taylor A.W. Volatilization and wind erosion of soil surface applied atrazine, simazine, alachlor and toxaphene. Journal of Agriculture and Food Chemistry 37 (1989) 546-551
13. Guicherit R., Bakker D.J., Pim de V., Van den Berg F., Van Dijk H.F.G., and Van Pul W.A.J. Environmental risk assessment for pesticides in the atmosphere; the results of an international workshop. Water, Air, and Soil Pollution 115 (1999) 5-19
14. Hung H., Blanchard T.P., Halsall C.J., Bidleman T.F., Stern G.A., Fellin P., Muir D.C.G., Barrie L.A., Jantunen L.M., Helm P.A., Ma J., and Konoplev A. Temporal and spatial variabilities of atmospheric polychlorinated biphenyls (PCBs), organochlorine (OC) pesticides and polycyclic aromatic hydrocarbons (PAHs) in the Canadian Arctic: results from a decade of monitoring. Science of the Total Environment 342 (2005) 119-144
15. Kwamena N.O.A., Thornton J.A., and Abbatt J.P.D. Kinetics of surface-bound benzo[a]pyrene and ozone on solid organic and salt aerosols. Journal of Physical Chemistry A 108 (2004) 11626-11634
16. Kwamena N.O.A., Staikova M.G., Donaldson D.J., George I.J., and Abbatt J.P.D. Role of the aerosol substrate in the heterogeneous ozonation reactions of surface-bound PAHs. Journal of Physical Chemistry A 111 (2007) 11050-11058
17. Kwok E.S., and Atkinson R. Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: an update. Atmospheric Environment 29 (1995) 1685-1695
18. Le Person A., Mellouki A., Munoz A., Borras E., Martin-Reviejo M., and Wirtz K. Trifluralin: photolysis under sunlight conditions and reaction with HO radicals. Chemosphere 67 (2007) 376-383
19. Lee S., McLaughlin R., Harnly M., Gunier R., and Kreutzer R. Community exposures to airborne agricultural pesticides in California: ranking of inhalation risks. Environmental Health Perspectives 1101 (2002) 1175-1184
20. Li J., Zhu T., Wang F., Qiu X.H., and Lin W.L. Observation of organochlorine pesticides in the air of the Mt. Everest region. Ecotoxicology and Environmental Safety 63 (2006) 33-41
21. Palm W.-U., Elend M., Krueger H.-U., and Zetzsch C. OH radical reactivity of airborne terbutylazine adsorbed on inert aerosol. Environmental Science and Technology 31 (1997) 3389-3396
22. Palm W.-U., Millet M., and Zetzsch C. OH radical reactivity of pesticides adsorbed in aerosol materials: first results of experiments with filter samples. Ecotoxicology and Environmental Safety 41 (1998) 36-43
23. 2. Chemosphere 38 (1999) 1241-1252
24. Pankow J.F. An absorption model of gas/particle partitioning of organic compounds in the atmosphere. Atmospheric Environment 28 (1994) 185-188
25. 2 with polycyclic aromatic hydrocarbons adsorbed on silica particles. Atmospheric Environment 39 (2005) 6557-6567
26. Perraudin E., Budzinskia H., and Villenave E. Kinetic study of the reactions of ozone with polycyclic aromatic hydrocarbons adsorbed on atmospheric model particles. Journal of Atmospheric Chemistry 56 (2007) 57-82
27. Pflieger M., Goriaux M., Temime-Roussel B., Gligorovski S., Monod A., and Wortham H. Validation of an experimental setup to study atmospheric heterogeneous ozonolysis of semi-volatile organic compounds. Atmospheric Chemistry and Physics 9 (2009) 2215-2225
28. Rosen E.P., Garland E.R., and Baer T. Ozonolysis of oleic acid adsorbed to polar and nonpolar aerosol particles. Journal of Physical Chemistry A 112 (2008) 10315-10324
29. Sanusi A., Millet M., Mirabel P., and Wortham H. Comparison of atmospheric pesticide concentrations measured at three sampling sites: local, regional and long-range transport. Science of the Total Environment 263 (2000) 263-277
30. Sanusi A., Millet M., Mirabel P., and Wortham H. Gas-particle partitioning of pesticides in atmospheric samples. Atmospheric Environment 33 (1999) 4941-4951
31. Sauret-Szczepanski N., Mirabel Ph., and Wortham H. Development of a SPME-GC-MS/MS method for the determination of pesticides in rain water. Environmental Pollution 139 (2006) 133-142
32. Sauret N., Wortham H., Putaud J.P., and Mirabel P. Study of the effects of environmental parameters on the gas/particle partitioning of current-use pesticides in urban air. Atmospheric Environment 42 (2008) 544-553
33. Scheringer M., Salzmann M., Stroebe M., Wegmann F., Fenner K., and Hungerbühler K. Long-range transport and global fractionation of POPs: insights from multimedia modeling studies. Environmental Pollution 128 (2004) 177-188
34. Scheyer A., Morville S., Mirabel P., and Millet M. Variability of atmospheric pesticide concentrations between urban and rural areas during intensive pesticide application. Atmospheric Environment 41 (2007) 3604-3618
35. Segal-Rosenheimer M., and Dubowski Y. Heterogeneous ozonolysis of cypermethrin using real-time monitoring FTIR techniques. Journal of Physical Chemistry C 111 (2007) 11682-11691
36. Usher C.R., Michel A.E., and Grassian V.H. Reactions on mineral dust. Chemical Reviews 103 (2003) 4883-4939
37. Van den Berg F., Kubiak R., Benjey W.G., Majewski M.S., Yates S.R., Reeves G.L., Smelt J.H., and Van der Linden A.M.A. Emission of pesticides into the air. Water, Air, and Soil Pollution 115 (1999) 195-218
38. Vingarzan R. A review of surface ozone background levels and trends. Atmospheric Environment 38 (2004) 3431-3442
39. Waite D.T., Bailey P., Sproull J.F., Quiring D.V., Chau D.F., Bailey J., and Cessna A.J. Atmospheric concentrations and dry and wet deposits of some herbicides currently used on the Canadian Prairies. Chemosphere 58 (2005) 683-703