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36749009541
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An historical perspective on the pertinence of metal dithiolene redox systems to the development of organometallic electrochemistry has appeared. See: Geiger, W. E.
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An historical perspective on the pertinence of metal dithiolene redox systems to the development of organometallic electrochemistry has appeared. See: Geiger, W. E. Organometallics 2007, 26, 5738.
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33947478566
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(a) Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H. Inorg. Chem. 1963, 2, 1227.
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24
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33845892491
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25
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33847710343
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Kokatam, S.-L.; Ray, K.; Pap, J.; Bill, E.; Geiger, W. E.; LeSuer, R. J.; Rieger, P. H.; Weyhermüller, T.; Neese, F.; Wieghardt, K. Inorg. Chem. 2007, 46, 1100.
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Weyhermüller, T.8
Neese, F.9
Wieghardt, K.10
-
26
-
-
37049067099
-
-
1-/2-/3- couples reported in this paper was consistent with unpublished observations made previously at the University of Vermont by A. Bijunas and one of the present authors.
-
1-/2-/3- couples reported in this paper was consistent with unpublished observations made previously at the University of Vermont by A. Bijunas and one of the present authors.
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Best, S.P.1
Ciniawsky, S.A.2
Clark, R.J.H.3
McQueen, R.C.S.4
-
27
-
-
70450183366
-
-
A fifth (monocationic) member of the gold dithiolene series has been isolated using a (di-tert-butylphenyl)ethylene-dithiolate ligand in place of mnt. See reference 11.
-
A fifth (monocationic) member of the gold dithiolene series has been isolated using a (di-tert-butylphenyl)ethylene-dithiolate ligand in place of mnt. See reference 11.
-
-
-
-
29
-
-
70450161543
-
-
Chemically reversible but electrochemically irreversible ET processes may be generally traced to either a slow ET step (possibly involving a significant structural change), to a reversible coupled chemical reaction, or both.
-
( 15) Chemically reversible but electrochemically irreversible ET processes may be generally traced to either a slow ET step (possibly involving a significant structural change), to a reversible coupled chemical reaction, or both.
-
-
-
-
31
-
-
0040751201
-
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Maki, A. H.; Edelstein, N.; Davison, A.; Holm, R. H. J. Am. Chem. Soc. 1964, 86, 4580.
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Maki, A.H.1
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33
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7644224742
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LeSuer, R. J.; Buttolph, C.; Geiger, W. E. Anal. Chem. 2004, 76, 6395.
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Lesuer, R.J.1
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-
36
-
-
70450190641
-
-
note
-
3- and the CV scan rate.
-
-
-
-
37
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-
0034940369
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Linert, W.; Fukuda, Y.; Camard, A. Coord. Chem. Rev. 2001, 218, 113.
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Linert, W.1
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38
-
-
70450185605
-
-
note
-
For double potential step chronoamperometry, see reference 5, pp 207-210. Using step potentials of -0.5 V to -2.0 V and a step time of 300 msec, the ratios of reverse-to-forward currents at different t/r values reproduced those obtained for ferrocene/ferrocenium under identical conditions (e.g., 0.27 at t/z = 2, close to the theoretical value of 0.29). See Supporting Information, Figure S1.
-
-
-
-
39
-
-
70450176977
-
-
-1 experiment for the purpose of lowering the solution resistance. See reference 19.
-
-1 experiment for the purpose of lowering the solution resistance. See reference 19.
-
-
-
-
40
-
-
33947338222
-
-
s is likely a factor of 2 to 3 larger than the lower estimate reported here, see
-
s is likely a factor of 2 to 3 larger than the lower estimate reported here, (see: Nicholson, R. S. Anal. Chem. 1966, 38, 1406.
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, pp. 1406
-
-
Nicholson, R.S.1
-
41
-
-
70450182773
-
-
p/2 « 115 mV; α = 0.41).
-
p/2 « 115 mV; α = 0.41).
-
-
-
-
46
-
-
0000379078
-
-
Fawcett, W. R.; Fedurco, M.; Opallo, M. J. Phys. Chem. 1992, 96, 9959.
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Fawcett, W.R.1
Fedurco, M.2
Opallo, M.3
-
47
-
-
70450204428
-
-
24] has an electrochemical "window" from about + 1.4 to -2.3 V vs Ag/AgCl in THF at a glassy carbon electrode.
-
24] has an electrochemical "window" from about + 1.4 to -2.3 V vs Ag/AgCl in THF at a glassy carbon electrode.
-
-
-
-
48
-
-
84889365392
-
-
This voltammetric behavior places the CE process in the Saveant "KP region" (pure kinetic control), whereas the "KE region" is found in THF (intermediate kinetics). See: John Wiley & Sons: New York
-
This voltammetric behavior places the CE process in the Saveant "KP region" (pure kinetic control), whereas the "KE region" is found in THF (intermediate kinetics). See: Savéant, J.-M. Elements of Molecular and Biomolecular Electrochemistry; John Wiley & Sons: New York, 2006; pp 92-94.
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Savéant, J.-M.1
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49
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0000820968
-
-
Bard, A. J., Ed; Marcel Dekker: New York
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Evans, D. H.; O'Connell, K. M. In Electroanalytical Chemistry;Bard, A. J., Ed; Marcel Dekker: New York, 1986; Vol. 14, pp 113-208.
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-
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Evans, D.H.1
In, O.K.M.2
-
50
-
-
70450205742
-
-
f
-
f;
-
-
-
-
52
-
-
70450190639
-
-
10 zinc complex, which we find to be optically silent in the 400-800 nm region (see Supporting Information, Figure S7).
-
10 zinc complex, which we find to be optically silent in the 400-800 nm region (see Supporting Information, Figure S7).
-
-
-
-
54
-
-
33744463647
-
-
See, for example: (acetonitrile) (a)
-
See, for example: (acetonitrile) (a) Chase, P. A.; Romero, P. E.; Piers, W. E.; Parvez, M.; Patrick, B. O. Can. J. Chem. 2005, 83, 2098;
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Chase, P.A.1
Romero, P.E.2
Piers, W.E.3
Parvez, M.4
Patrick, B.O.5
-
55
-
-
18744403749
-
-
dichloromethane:(b)
-
(dichloromethane):(b) Park, Y-D.; Kim, J.-J.; Cho, S.-D.; Lee, S.-G.; Falck, J. R.; Yoon, Y-J. Synthesis 2005, 1136.
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, pp. 1136
-
-
Park, Y.-D.1
Kim, J.-J.2
Cho, S.-D.3
Lee, S.-G.4
Falck, J.R.5
Yoon, Y.-J.6
-
56
-
-
70450182772
-
-
6] when the voltammetry is carried out at a glassy carbon electrode. Some irreversibility and electrode history is observed when a platinum or gold working electrode is employed (A. Bijunas, unpublished work at the University of Vermont).
-
6] when the voltammetry is carried out at a glassy carbon electrode. Some irreversibility and electrode history is observed when a platinum or gold working electrode is employed (A. Bijunas, unpublished work at the University of Vermont).
-
-
-
-
57
-
-
8344228441
-
-
Five-coordinate Au(I) complexes are rare. See
-
Five-coordinate Au(I) complexes are rare. See: Gimeno, M. C.; Laguna, A. Chem. Rev. 1997, 97, 511.
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Gimeno, M.C.1
Laguna, A.2
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0034614521
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Yam, V.W-W.; Chan, C.-L.; Choi, S.W-K.; Wong, K.M-C.; Cheng, E.C-C.; Yu, S.-C.; Ng, P.-K.; Chan, W.-K.; Cheung, K.-K. Chem. Commun. 2000, 53.
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Yam, V.W.-W.1
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Wong, K.M.-C.4
Cheng, E.C.-C.5
Yu, S.-C.6
Ng, P.-K.7
Chan, W.-K.8
Cheung, K.-K.9
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61
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44949202495
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Cerda, J.F.1
Koder, R.L.2
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Moser, C.M.4
Miller, A.-F.5
Dutton, P.L.6
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