Preparation of photoreactive oligomers by ADMET polymerization of [(c 5h4(ch2)8ch=ch2)Mo(Co) 3]2

Macromolecules

Volumn 42, Issue 20, 2009, Pages 7644-7649

  Shultz, Ginger V ^a   Zemke, Jennifer M ^a   Tyler, David R ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACYCLIC DIENE METATHESIS POLYMERIZATIONS; M-O BOND; METAL CHLORIDES; OLIGOMER CHAINS; POLYDISPERSES; POLYMERIZATION REACTION; RING CLOSING METATHESIS; SOLVENT CONDITIONS;

CATALYSIS; CATALYSTS; CHLORINE COMPOUNDS; IRRADIATION; MOLYBDENUM; OLEFINS; OLIGOMERS; POLYDISPERSITY; POLYMERS;

POLYMERIZATION;

EID: 70449346592     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9013252     Document Type: Article

References (41)

1. Guillet, J. Polymer Photophysics and Photochemistry; Cambridge University Press: New York, 1985.
2. Guillet, J. E. Photodegradable Plastics In Degradable Materials; Barenberg, S. A., Brash, J. L., Narayan, R., Redpath, A. E., Eds.; CRC Press: Boston, MA, 1990.
3. Tyler, D. R. Coord. Chem. Rev. 2003, 246, 291-303.
4. Tyler, D. R. In Macromolecules Containing Metal and Metal-Like Elements; Volume 6: Transition Metal-Containing Polymers; Abd-El-Aziz, A. S., Carraher, C. E., Jr.; Pittman, C. U., Jr., Zeldin, M., Eds.; John Wiley & Sons: Hoboken, NJ, 2006.
5. Tyler, D. R.; Daglen, B. C.; and Shultz, G. V. In Macromolecules Containing Metal and Metal-like Elements; Volume 8; Abd-El-Aziz, A. S., Carraher, C. E., Jr., Pittman, C. U., Jr., Sheats, J., Zeldin, M., Eds.; Wiley-Interscience: New York, 2009.
6. Stevens, E. S. Green Plastics; Princeton University Press: Princeton, NJ, 2002.
7. Chen, R.; Yoon, M; Smalley, A.; Johnson, D. C.; Tyler, D. R. J. Am. Chem. Soc. 2004, 126, 3054.
8. Chen, R.; Tyler, D. R. Macromolecules 2004, 37, 5430-5436.
9. Daglen, B. C.; Tyler, D. R. J. Inorg. Organomet. Polym. Mat. 2009, 19, 91.
10. Daglen, B. C.; Harris, J. D.; Tyler, D. R. J. Inorg. Organomet. Polym. 2007, 17, 261.
11. Stiegman, A. E.; Tyler, D. R. Coord. Chem. Rev. 1985, 63, 217.
12. Landrum, J. T.; Hoff, C.D. J. Organomet. Chem. 1985, 215, 282.
13. Grubbs, R. H. Angew. Chem., Int. Ed. 2006, 45, 3760.
14. Odian, G. Principles of Polymerization, 4th Ed.; Wiley-Interscience: Hoboken, NJ, 2004.
15. Chauvin, Y. Angew. Chem., Int. Ed. 2006, 45, 3741.
16. Abd-El-Aziz, A. S.; Manners, I. Frontiers in Metal-containing Polymers; Wiley-Interscience: Hoboken, NJ, 2007.
17. Manners, I. Synthetic Metal-containing Polymers; Wiley-VCH: Weinheim, Germany, 2004.
18. Wagener, K. B.; Baughman, T. W. Adv. Polym. Sci. 2005, 176, 1.
19. Schwenderman, J. E.; Church, A. C.; Wagener, K. B. Adv. Synth. Catal. 2002, 344, 597.
20. 30
21. Baughman, T. W.; Wagener, K. B. Adv. Polym. Sci. 2005, 176, 1.
22. Watson, M. D.; Wagener, K. B. Macromolecules 2000, 33, 8963.
23. Sworen, J. C.; Smith, J. A.; Berg, J. M.; Wagener, K. B. J. Am. Chem. Soc. 2001, 129, 11238.
24. Wolfe, P. S.; Gomez, F. J.; Wagener, K. B. Macromolecules 1997, 20, 714.
25. Gomez, F. J.; Wagener, K. B. J. Organomet. Chem. 1999, 592, 271.
26. Church, A. C.; Pawlow, J. H.; Wagener, K. B. Macromol. Chem. Phys. 2003, 204, 32.
27. Gamble, A. S.; Patton, J. T.; Boncella, J. M. Makromol. Chem. Rapid Commun. 1993, 13, 109.
28. Wirth-Pfeifer, C.; Michel, A.; Wiess, K., Novel Metathesis Chemistry; NATO Science Series, II: Mathematics, Physics and Chemistry, Vol. 122; Kluwer Academic Publishing: Boston, MA, 2003.
29. Weychardt, H.; Plenio, H. Organometallics 2008, 27, 1479.
30. Shultz, G. V.; Zakharov, L. N.; Tyler, D. R. Macromolecules 2008, 41, 5555.
31. Baughman, T. W.; Sworen, J. C.; Wagener, K. B. Tetrahedron 2004, 60, 10943.
32. You-Feng, X.; Yan, S.; Zhen, P. J. Organomet. Chem. 2004, 689, 823.
33. Martin-Alvarez, J. M.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 955.
34. Shultz, G. V.; Berryman, O. R.; Zakharov, L. V.; Tyler, D. R. J. Inorg. Organometal. Polym. Mat. 2008, 18, 149.
35. Curtis, M. D.; Hay, M. S. Inorg. Syn. 1990, 28, 150.
36. Tenhaeff, S. C.; Tyler, D. R. Organometallics 1991, 10, 473.
37. ADMET polymerization was also carried out using Grubbs' first and second generation catalysts. However, these catalysts were less active toward the polymerization of complex 1 and therefore Schrock's catalyst was determined to be the preferred catalyst in this case. More specifically, complete monomer conversion was observed after approximately 3 days when Grubbs' second generation catalyst was used and approximately 5 days when Grubbs first generation catalyst was used.
38. Church, A. C.; Smith, J. A.; Pawlow, J. H.; Wagener, K. B. In Synthetic Methods in Step Growth Polymerization; Rogers, M. E.; Long, T. E., Eds.; Wiley-Interscience: Hoboken, NJ, 2003.
39. Watson, M. D.; Wagener, K. B. Macromolecules 2000, 33, 8963.
40. Characterization of the ring-closing product by mass spectrometry was attempted using several methods, including MALDI, LC/MS mass spectrometry, and ESI mass spectrometry, but was unsuccessful.
41. Alway, D. G.; Barnett, K. W. Inorg. Chem. 1980, 19, 1533.