Metal-containing polymers synthesized via acyclic diene metathesis: Polycarbostannanes

Macromolecules

Volumn 30, Issue 4, 1997, Pages 714-717

  Wolfe, Patrick S ^a   Gómez, Fernando J ^a   Wagener, Kenneth B ^a  

^a University of Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; HYDROCARBONS; MOLECULAR WEIGHT; MOLYBDENUM COMPOUNDS; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; SYNTHESIS (CHEMICAL); TUNGSTEN COMPOUNDS;

ACYCLIC DIENE METATHESIS (ADMET); POLYCARBOSTANNANES;

METALLORGANIC POLYMERS;

EID: 0031075078     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma961291s     Document Type: Article

References (24)

1. (a) Wagener, K. B.; Boncella, J. M.; Nel, J. G. Macromolecules 1991, 24, 2649.
2. (b) Wagener, K. B.; Nel, J. G.; Konzelman, J.; Boncella, J. M. Macromolecules 1990, 23, 5155.
3. (c) Konzelman, J.; Wagener, K. B. Macromolecules 1995, 28, 4686.
4. Wolf, A.; Wagener, K. B. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.). 1991, 32 (1), 535.
5. For examples see: (a) Portmess, J. D.; Wagener, K. B. J. Polym. Sci. Part A: Polym. Chem. 1996, 34, 1353. (b) Wagener, K. B.; Brzezinska, K. Macromolecules 1991, 24, 5273.
6. For examples see: (a) Portmess, J. D.; Wagener, K. B. J. Polym. Sci. Part A: Polym. Chem. 1996, 34, 1353. (b) Wagener, K. B.; Brzezinska, K. Macromolecules 1991, 24, 5273.
7. (c) Wagener, K. B.; Patton, J. T. Macromolecules 1993, 26, 249.
8. (d) Smith, D. W., Jr.; Wagener, K. B. Macromolecules 1993, 26, 1633.
9. Brzezinska, K.; Wolfe, P. S.; Watson, M. D.; Wagener, K. B. Macromol. Chem. Phys. 1996, 197, 2065.
10. Wolfe, P. S.; Wagener, K. B. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.). 1996, 37 (1), 439.
11. (a) Lindmark-Hamberg, M.; Wagener, K. B. Macromolecules 1987, 20, 2949.
12. (b) Wagener, K. B.; Boncella, J. M.; Nel, J. G.; Duttweiler, R. P.; Hillmyer, M. A. Makromol. Chem. 1990, 191, 365.
13. Nugent, W. A.; Feldman, J.; Calabrese, J. C. J. Am. Chem. Soc. 1995, 117, 8992.
14. Gómez, F. J.; Wagener, K. B. PMSE Prepr. (Am. Chem. Soc., Div. Polym. Mat. Sci. Eng.). 1997, in press.
15. Nubel, P. O.; Lutman, C. A.; Yokelson, H. B. Macromolecules 1994, 27, 7000.
16. Schrock, R. R.; Murdzek, J. S.; Bazan, G. C.; Robbins, J.; DiMare, M.; O'Regan, M. J. Am. Chem. Soc. 1990, 112, 3875.
17. Pomogailo, A. D.; Savost'yanov, V. S. Synthesis and Polymerization of Metal-Containing Monomers; CRC Press, Inc.: Boca Raton, FL, 1994; p 164.
18. For recent examples of polymers containing tin see: (a)Tilley, T. Don; Lu, Victor. Macromolecules 1996, 29, 5763. (b) Yokohama, Y.; Hayakawa, M.; Azemi, T.; Mochida, K. J. Chem. Soc., Chem. Commun. 1995, 2275.
19. For recent examples of polymers containing tin see: (a)Tilley, T. Don; Lu, Victor. Macromolecules 1996, 29, 5763. (b) Yokohama, Y.; Hayakawa, M.; Azemi, T.; Mochida, K. J. Chem. Soc., Chem. Commun. 1995, 2275.
20. (c) Imori, T.; Lu, V.; Cai, H. Tilley, T. D. J. Am. Chem. Soc. 1995, 117, 9931.
21. (d) Devylder, N.; Hill, M.; Molloy, K. C.; Price, G. J. Chem. Commun. 1996, 711.
22. For a discussion on the role of main group metal alkyls as cocatalysts of aryloxo complexes in classical metathesis catalytic systems, see: Quignard, F.; Leconte, M.; Basset, J. M. J. Mol. Catal. 1986, 36, 13.
23. The gelation is a direct effect of the concentration of Sn-Cl bonds. This was verified by examining the different behaviors of polymer samples synthesized using different monomer to catalyst ratios (250:1 and 100:1). Workup of a polymer sample (250:1) in the presence of moisture did not form insoluble material whereas the polymer produced from a 100:1 ratio yielded an insoluble gel under the same conditions. We acknowledge the reviewer for bringing this to our attention.
24. 13C NMR.