Metal-containing polymers synthesized via acyclic diene metathesis: Polycarbostannanes

Macromolecules

Volumn 30, Issue 4, 1997, Pages 714-717

  Wolfe, Patrick S ^a   Gómez, Fernando J ^a   Wagener, Kenneth B ^a  

^a University of Florida   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; HYDROCARBONS; MOLECULAR WEIGHT; MOLYBDENUM COMPOUNDS; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; SYNTHESIS (CHEMICAL); TUNGSTEN COMPOUNDS;

ACYCLIC DIENE METATHESIS (ADMET); POLYCARBOSTANNANES;

METALLORGANIC POLYMERS;

EID: 0031075078     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma961291s     Document Type: Article

References (24)

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23. The gelation is a direct effect of the concentration of Sn-Cl bonds. This was verified by examining the different behaviors of polymer samples synthesized using different monomer to catalyst ratios (250:1 and 100:1). Workup of a polymer sample (250:1) in the presence of moisture did not form insoluble material whereas the polymer produced from a 100:1 ratio yielded an insoluble gel under the same conditions. We acknowledge the reviewer for bringing this to our attention.
24. 13C NMR.