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2)}/{w (mm) × l (mm)}, where M is the total weight hanging from the end of the film, w is the width of film, and l is its thickness.
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48 These workers divided the infrared bands of PVC into three types. The first type consists of bands that characterize the configuration and conformation of the sample; these bands are always present, whatever the physical state of the sample. Most of the bands in the carbon-chlorine stretching region are of this type, at least for commercial PVC. The second type of band is associated with long stereoregular chain segments, These bands are present even in noncrystalline samples, which proves they are not due to the crystalline phase of PVC. The third type consists of bands that are characteristic of crystalline regions, and consequently their intensity can be used to assess the amount of crystallinity. It is interesting to note that the crystalline bands have peaks split into two components, caused by the interactions between neighboring chains in the crystal unit cell. The two bands cannot be observed simultaneously because one component of each pair is infrared active and the other one Raman active.
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