A novel hybrid inorganic-metalorganic compound based on a polymeric polyoxometalate and a copper complex: Synthesis, crystal structure and topological studies

Chemistry - A European Journal

Volumn 10, Issue 20, 2004, Pages 5138-5146

  San Felices, Leire ^a   Vitoria, Pablo ^a   Gutiérrez Zorrilla, Juan M ^a   Reinoso, Santiago ^a   Etxebarria, Juan ^a   Lezama, Luis ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Copper complexes; Density functional calculations; Polyhedral distortion; Polyoxometalates

Indexed keywords

CRYSTAL STRUCTURE; HYDROGEN BONDS; MAGNETIC PROPERTIES;

CONTINOUS SHAPE MEASURES (CSM); COPPER COMPLEXES; DOUBLE CHAINS; POLYOXOMETALATES (POM);

ORGANIC COMPOUNDS;

COPPER COMPLEX; INORGANIC COMPOUND; METAL COMPLEX; POLYMER;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; HYDROGEN BOND; STRUCTURE ANALYSIS; SYNTHESIS;

COPPER; CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; MAGNETICS; MOLECULAR CONFORMATION; POLYMERS; TEMPERATURE; TUNGSTEN COMPOUNDS;

EID: 7044272780     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400279     Document Type: Article

References (71)

1. a) M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991. 30, 34;
2. a) M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991. 30, 34;
3. b) Polyoxometalates: From Platonic Solids to Antiretroviral Activity (Eds. : M. T. Pope, A. Müller), Kluwer, Dordrecht (The Netherlands), 1994;
4. d) Polyoxometalates: From Topology via Self-Assembly to Applications (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht (The Netherlands), 2001;
5. e) Polyoxometalate Chemistry for Nanocomposite Design (Eds.: M. T. Pope, T. Yamase), Kluwer, Dordrecht (The Netherlands), 2002;
6. f) Polyoxometalate Molecular Science (Eds.: J. J. Borrás-Almenar, E. Coronado, A. Müller, M. Pope), Kluwer, Dordrecht (The Netherlands), 2003.
7. D. E. Katsoulis, Chem. Rev. 1998, 98, 359. and references therein.
8. a) A. Milonas, E. Papaconstantinou, J. Mol. Catal. 1994, 92, 261;
9. b) A. Corma, Chem. Rev. 1995, 95, 559;
10. c) I. V. Kozhevnikov, Catal. Rev. Sci. Eng. 1995, 37, 311;
11. d) I. A. Weinstock, Chem. Rev. 1998, 98, 113;
12. e) I.V. Kozhevnikov, Chem. Rev. 1998, 95, 171;
13. f) N. Mizuno, M. Misono, Chem. Rev. 1998, 95, 199;
14. g) R. Neumann, Prog. Inorg. Chem. 1998, 47, 317;
15. g) M. Misono, Chem. Commun. 2001, 1141; A. M. Khenkin, L. Weiner, Y. Wang, R. Neumann, J. Am. Chem. Soc. 2001, 123, 8531.
16. g) M. Misono, Chem. Commun. 2001, 1141; A. M. Khenkin, L. Weiner, Y. Wang, R. Neumann, J. Am. Chem. Soc. 2001, 123, 8531.
17. a) E. Coronado, C. J. Gómez-García, Comments Inorg. Chem. 1995, 17, 255;
18. b) E. Coronado, C. J. Gómez-Garcia, Chem. Rev. 1998, 98, 273;
19. c) T. Yamase, Chem. Rev. 1998, 98, 307;
20. d) L. Ouahab, Coord. Chem. Rev. 1998, 178, 1501;
21. e) E. Coronado, J. R. Galán-Mascarós, C. Giménez-Saiz, C. J. Gómez-García, Adv. Mater. Opt. Electron. 1998, 8, 61;
22. f) J. M. Clemente-Juan, E. Coronado, Coord. Chem. Rev. 1999,193, 361;
23. g) M. Clemente-Leon, E. Coronado, P. Delhaes, C. J. Gómez- García, C. Mingolaud, Adv. Mater. 2001, 13, 574.
24. a) C. L. Hill, M. S. Weeks, R. F. Schinazi, J. Med. Chem. 1990, 55, 2767;
25. b) Y. Inouye, Y. Tale, Y. Tokutake, T. Yoshida, A. Yamamoto, T. Yamase, S. Nakamura, Chem. Pharm. Bull. 1990, 38, 285;
26. c) J.T. Rhule, C. L. Hill, D. A. Judd, R. F. Schinazi, Chem. Rev. 1998, 98, 327;
27. d) N. Fukuda, T. Yamase, Y. Tajima, Biol. Pharm. Bull. 1999, 22, 463.
28. a) D. Hagrman, P. J. Zapf, J. Zubieta, Chem. Commun. 1998, 1283;
29. b) D. Hagrman, P. J. Hagrman, J. Zubieta, Angew. Chem. 1999, 111, 3359; Angew. Chem. Int. Ed. 1999, 38, 3165;
30. b) D. Hagrman, P. J. Hagrman, J. Zubieta, Angew. Chem. 1999, 111, 3359; Angew. Chem. Int. Ed. 1999, 38, 3165;
31. c) L.-M. Zheng, T. Whitfield, X. Wang, A. J. Jacobson. Angew. Chem. 2000, 112, 4702; Angew. Chem. Int. Ed. 2000, 39, 4528;
32. c) L.-M. Zheng, T. Whitfield, X. Wang, A. J. Jacobson. Angew. Chem. 2000, 112, 4702; Angew. Chem. Int. Ed. 2000, 39, 4528;
33. d) J. Do, A. J. Jacobson, Inorg. Chem. 2001, 40, 598;
34. e) P.J. Hagrman, J. Zubieta, Inorg. Chem. 2001, 40, 2800;
35. f) L.-M. Zheng, X. Wang, Y. Wang, A. J. Jacobson, J. Mater. Chem. 2001, 11, 1100;
36. g) R. L. Laduca, Jr., R. S. Rarig, Jr., J. Zubieta, Inorg. Chem. 2001, 40, 607;
37. h) C.-Z. Lu, C-D. Wu, H.-H. Zhuang, J.-S. Huang, Chem. Mater. 2002, 14, 2649;
38. i) R. Nandini Devi, J. Zubieta, Inorg. Chim. Acta 2002, 332, 72;
39. j) R. C. Finn, J. Sims, C. J. O'Connor, J. Zubieta, J. Chem. Soc. Dalton Trans. 2002, 159.
40. E. Burkholder, V. Golub, C. J. O'Connor, J. Zubieta, Inorg. Chem. Commun. 2004, 7, 363.
41. a) J. R. Galán-Mascarós, C. Giménez-Saiz, S. Triki, C. J. Gómez-García, E. Coronado, L. Ouahab, Angew. Chem. 1995, 107, 1601; Angew. Chem. Int. Ed. 1995, 34, 1460;
42. a) J. R. Galán-Mascarós, C. Giménez-Saiz, S. Triki, C. J. Gómez-García, E. Coronado, L. Ouahab, Angew. Chem. 1995, 107, 1601; Angew. Chem. Int. Ed. 1995, 34, 1460;
43. b) E. Coronado, J. R. Galán-Mascarós, C. Giménez-Saiz, C. J. Gómez-García, S. Triki, J. Am. Chem. Soc. 1998, 120, 4671.
44. H. T. Evans, T. J. R. Weakley, G. B. Jameson, J. Chem. Soc. Dalton Trans. 1996, 2537.
45. B. Yan, Y. Xu, X. Bu, N. K. Goh, L. S. Chia, G. D. Stucky, J. Chem. Soc. Dalton Trans. 2001, 2009.
46. L. Lisnard, A. Dolbecq, P. Mialane, J. Marrot, F. Sécheresse, Inorg. Chim. Acta 2004, 357, 845.
47. S. Reinoso, P. Vitoria, L. Lezama, A. Luque, J. M. Gutiérez- Zorrilla, Inorg. Chem. 2003, 42, 3709.
48. a) H. Zabrodsky, S. Peleg, D. Avnir, J. Am. Chem. Soc. 1992, 114, 7843:
49. b) S. Alvarez, M. Llunell, J. Chem. Soc. Dalton Trans. 2000, 3288;
50. c) S. Alvarez, D. Avnir, M. Llunell, M. Pinsky, New J. Chem. 2002, 26, 996; S. Alvarez, An. Quim. 2003, 99, 29.
51. c) S. Alvarez, D. Avnir, M. Llunell, M. Pinsky, New J. Chem. 2002, 26, 996; S. Alvarez, An. Quim. 2003, 99, 29.
52. D. Casanova, J. Cirera, M. Llunell, P. Alemany, D. Avnir, S. Alvarez, J. Am. Chem. Soc. 2004, 126, 1755.
53. F. H. Allen, Acta Crystallogr. Sect. B 2002, 55, 380.
54. H. Zabrodsky, S. Peleg, D. Avnir, J. Am. Chem. Soc. 1993, 115, 8278; H. Zabrodsky, S. Peleg, D. Avnir, J. Am. Chem. Soc. 1994, 116, 656.
55. H. Zabrodsky, S. Peleg, D. Avnir, J. Am. Chem. Soc. 1993, 115, 8278; H. Zabrodsky, S. Peleg, D. Avnir, J. Am. Chem. Soc. 1994, 116, 656.
56. A. Tézé, G. Hervé, J. Inorg. Nucl. Chem. 1977, 39, 999.
57. Oxford Diffraction, CrysAlis CCD and RED. Version 1.70, Oxford Diffraction Ltd, Oxford (UK), 2003.
58. A. Altomare, M. C. Burla, M. Camalli, G. Cascarano, G. Luca, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori, R. Spagna, J. Appl. Crystallogr. 1999, 32, 115.
59. G. M. Sheldrick, SHELXL97, University of Göttingen, Göttingen (Germany), 1999.
60. L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837.
61. A. L. Speck, PLATON, Utrecht University, Utrecht (The Netherlands), 2001.
62. Gaussian 98W (Revision A.7), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi. B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian, Inc., Pittsburgh PA, 1998.
63. a) P. L. A. Popelier, R. G. A. Bone, MORPHY98, UMIST, Manchester, England, 1998;
64. b) P. L. A. Popelier, Comput. Phys. Commun. 1995, 93, 212.
65. A. D. Becke, J. Chem. Phys. 1993, 98, 5648.
66. a) A. J. H. Wachters, J. Chem. Phys. 1970, 52, 1033;
67. b) P. J. Hay, J. Chem. Phys. 1977, 66, 4377;
68. c) K. Raghavachari, G. W. Trucks, J. Chem. Phys. 1989, 91, 1062.
69. T. Clark, J. Chandrasekhar, G. W. Spitznagel, P. V. R. Schleyer, J Comput. Chem. 1983, 4, 294.
70. M. J. Frisch, J. A. Pople, J. S. Winkley, J. Chem. Phys. 1984, 80, 3265.
71. M. Llunell, D. Casanova, J. Cirera, J. M. Bofill, P. Alemany, S. Alvarez, M. Pinsky, D. Avnir, SHAPE v1.1a, Barcelona (Spain), 2003.