An efficient transition metal-free aziridination of alkenes with Chloramine-T using aqueous H 2O 2/HBr

Tetrahedron Letters

Volumn 45, Issue 47, 2004, Pages 8731-8732

  Jain, Suman L ^a   Sharma, Vishal B ^a   Sain, Bir ^a  

^a CSIR INDIAN INSTITUTE OF PETROLEUM   (India)

Author keywords

Aziridination; H 2O 2; HBr; Nitrene; Olefins

Indexed keywords

ALKENE DERIVATIVE; HYDROBROMIC ACID; HYDROGEN PEROXIDE; TOSYLCHLORAMIDE SODIUM;

AQUEOUS SOLUTION; ARTICLE; AZIRIDINATION; CATALYSIS; CHEMICAL REACTION;

EID: 7044231320     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.09.155     Document Type: Article

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23. 2) using ethyl acetate/hexane (4:6) as eluent. After completion, the solvent was evaporated under reduced pressure. The residue obtained was purified through a short silica gel column using hexane/ethyl acetate (4:1) as eluent. Evaporation of the solvent yielded N-(p-tolylsulfonyl)-2-(p-methylphenyl)aziridine (yield 247 mg, 80%). Similarly, other aziridines were prepared via this procedure