Nitrogen atom transfer to alkenes utilizing Chloramine-T as a nitrogen source

Tetrahedron Letters

Volumn 39, Issue 3-4, 1998, Pages 309-312

  Ando, Takeya ^a   Minakata, Satoshi ^a   Ryu, Ilhyong ^a   Komatsu, Mitsuo ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; AZIRIDINE DERIVATIVE; NITROGEN; TOSYLCHLORAMIDE SODIUM;

ARTICLE; ATOM; CATALYST; CHEMICAL MODIFICATION; ION TRANSPORT; REACTION ANALYSIS; STEREOSPECIFICITY; SYNTHESIS;

EID: 0032518652     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10553-6     Document Type: Article

References (25)

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23. 9 The commercially available Chloramine-T trihydrate was dried at 90 °C under vacuum (see ref. 8).
24. 2. The solvent was removed in vacuo to give an oil which was purified by flash column chromatography.
25. 11 This phenomena is also observed in Evans' copper catalyzed aziridination by PhI=NTs. It is known that the stereospecificity is highly dependent on the copper catalyst employed (see ref. 2b). We are currently pursuing this problem.