Which one is preferred: Myers-Saito cyclization of ene-yne-allene or Garratt-Braverman cyclization of conjugated bisallenic sulfone? A theoretical and experimental study

Journal of the American Chemical Society

Volumn 131, Issue 43, 2009, Pages 15695-15704

  Basak, Amit ^a   Das, Sanket ^a   Mallick, Dibyendu ^b   Jemmis, Eluvathingal D ^b,c  

^a INDIAN INSTITUTE OF TECHNOLOGY   (India)

^b INDIAN INSTITUTE OF SCIENCE   (India)

^c INDIAN INSTITUTE OF SCIENCE EDUCATION AND RESEARCH   (India)

Author keywords

[No Author keywords available]

Indexed keywords

BASIC CONDITIONS; CLEAVING AGENTS; COMPUTATIONAL TECHNIQUE; CYCLIZATION PATHWAYS; CYCLIZATIONS; DNA CLEAVAGE; ENE-YNE; EXPERIMENTAL STUDIES; INVERSE RELATIONS; MECHANISTIC STUDIES; RATE DETERMINING STEP; REACTION PATHWAYS; SELF-QUENCHING; THEORETICAL PREDICTION;

ACTIVATION ENERGY; BENZENE; DNA; GENES; NAPHTHALENE; NUCLEIC ACIDS; QUENCHING;

CYCLIZATION;

2,2' [3,3' [2,2' [3,3' SULFONYLBIS(PROP 1 YNE 3,1 DIYL)]BIS(2,1 PHEPHENYLENE)]BIS(PROP 2 YN 3,1 DIYL)]BIS(OXY)BIS(TETRAHYDRO 2H PYRAN); 3,3' [2,2' [3,3' SULFONYLBIS(PROP 1 YNE 3,1 DIYL)]BIS(2,1 PHEPHENYLENE)]DIPROP 2 YN 1 OL; 3,3' [2,2' [3,3' SULFONYLBIS(PROP 1 YNE 3,1 DIYL)]BIS(4 NITRO 2,1 PHEPHENYLENE)]DIPROP 2 YN 1 OL; 8,8' SULFONYLDIOCTA 4 EN 2,6 DIYN 1 OL; BENZENE; BENZOSULFOLENE; ENEDIYNE; NAPHTHALENE; NAPHTHOSULFOLENE; NITRONAPHTHOSULFOLENE; SULFONE DERIVATIVE; SULFOXIDE; UNCLASSIFIED DRUG;

ARTICLE; COMPARATIVE STUDY; CONJUGATION; CYCLIZATION; DNA CLEAVAGE; FEASIBILITY STUDY; ISOMERISM; THERMODYNAMICS;

CYCLIZATION; KINETICS; MODELS, THEORETICAL; SULFONES;

EID: 70350676806     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9023644     Document Type: Article

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