Intermolecular oxidative animation of olefins with amines catalyzed by the Pd(II)/NPMoV/O2 System

Organic Letters

Volumn 11, Issue 21, 2009, Pages 5058-5061

  Obora, Yasushi ^a   Shimizu, Yosuke ^a   Ishii, Yasutaka ^a  

^a KANSAI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 70350662974     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol902052z     Document Type: Article

References (46)

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44. 2O (NPMOV) (35 mg, 0.02 mmol, 1 mol %), and hydroquinone (HQ) (44 mg, 0.4 mmol, 20 mol %) in DMF (2 mL) under atmospheric oxygen (1 atm) at 60 °C for 6 h in a 30 mL round-bottomed flask. The conversions and yields of products were estimated from peak areas based on an internal standard using GC and the product 3a was obtained in 90% yield along with a trace amount of 4a. The product 3a was isolated by column chromatography (230-400 mesh silica gel, n-hexane/ethyl acetate = 9/1) in 84% yield (224 mg).
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