Photochemical reaction of Mo(CO)6 with et2GeH 2: NMR and DFT studies of reaction products; crystal structure of a novel complex [{Mo(μ-η2-H-GeEt2)(CO) 4}2]

Organometallics

Volumn 28, Issue 20, 2009, Pages 5857-5865

  Zyder, Magdalena ^a   Kochel, Andrzej ^a   Handzlik, Jarosław ^b   Szymańska Buzar, Teresa ^a  

^a UNIVERSITY OF WROC AW   (Poland)

^b CRACOW UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

BINUCLEAR COMPLEXES; CRYSTALLINE FORM; DFT STUDY; DIHYDRIDE COMPLEXES; GE ATOM; H NMR SPECTROSCOPY; HYDRIDE LIGANDS; NMR SPECTROSCOPY; PROTON RESONANCES; REACTION PRODUCTS; SINGLE CRYSTAL X-RAY DIFFRACTION; THERMAL BEHAVIORS;

CRYSTAL ATOMIC STRUCTURE; GERMANIUM; LIGANDS; MOLYBDENUM; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOCHEMICAL REACTIONS; PROBABILITY DENSITY FUNCTION;

MOLYBDENUM COMPOUNDS;

EID: 70350318967     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900299k     Document Type: Article

References (71)

1. Kubas, G. J. Chem. Rev. 2007, 107,4152.
2. Nakata, N.; Fukuzawa, S.; Ishii, A. Organometallics 2009, 28,534.
3. Tanabe, M.; Ishikawa, N.; Osakada, K. Organometallics 2006, 25, 796.
4. Matthews, S. L.;Pons, V.; Heinekey, D. Inorg. Chem. 2006, 45, 6453.
5. Minato, M.; Zhou, D.-Yang; Zhang, L.-B.; Hirabayashi, R.; Kakeya, M.; Matsumoto, T.; Harakawa, A.; Kikutsuji, G.; Ito, T. Organometallics 2005, 24, 3434.
6. (a) White, C. P.; Braddock-Wilking, J.; Corey, J. Y.; Xu, H.; Redekop, E.; Sedinkin, S.; Rath, N. P. Organometallics 2007, 26,1996.
7. (b) Braddock-Wilking, J.; Corey, J. Y.; White, C.; Xu, H.; Rath, N. P. Organometallics 2005, 46,4113.
8. Matthews, S. L.; Pons, V.; Heinekey, D. M. J. Am. Chem. Soc. 2005, 127, 850.
9. Gadek, A.; Szymańska-Buzar, T. Polyhedron 2006, 25, 1441.
10. Gadek, A.; Kochel, A.; Szymanska-Buzar, T. J. Organomet. Chem. 2007, 692, 3765.
11. Vincent, J. L.; Luo, S.; Scott, B. L.; Butcher, R.; Unkefer, C. J.; Burns, C. J.; Kubas, G. J.; Lledós, A.; Maseras, F.; Tomàs, J. Organometallics 2003, 22, 5307.
12. Marciniec, B.; Lawicka, H. Appl. Organomet. Chem. 2008, 22, 510.
13. Lakhtin, V. G.; Knyazev, S. P.; Pavlov, K. V.; Gusel'nikov, L. E.; Buravtseva, E. N.; Kuyantseva, N. A.; Parshkova, L. A.; Mid'ko, A. A.; Bykovchenko, V. G.; Kisin, A. V.; Chernyshev, E. A. Russ. J. Gen. Chem. 2008, 78, 898.
14. Schumann, H.; Aksu, Y. Organometallics 2007, 26, 397.
15. Miura, K.; Ootsuka, K.; Hosomi, A. J. Organomet. Chem. 2007, 692,514.
16. Yorimitsu, H.; Oshima, K. Inorg. Chem. Commun. 2005, 8, 131.
17. Kinoshita, H.; Nakamura, T. Kakiya, H.; Shinokubo, H.; Matsubara, S.; Oshima, K.
18. Furukawa, N.; Kourogi, N.; Seki, Y.; Kakiuchi, F.; Murai, S. Organometallics 1999, 18, 3764.
19. Esteruelas, M. A.; Martn, M.; Oro, L. A. Organometallics 1999, 18, 2267.
20. Kuivila, H. G.; Warner, C. R. J. Org. Chem. 1964, 29,2845.
21. Zyder, M.; Szymańska-Buzar, T. J. Organomet. Chem. 2009, doi: 10.1016/j.jorganchem.2009.02.013.
22. Gadek, A.; Kochel, A.; Szymańska-Buzar, T. Organometallics 2003, 22,4869.
23. Burschka, C.; Stroppel, K.; Jutzi, P. Acta. Cryslallogr. 1981, B37, 1397.
24. Petz, W. Chem. Rev. 1986, 86, 1019.
25. Jutzi, P.; Hampel, B.; Hursthouse, M. B.; Howles, A. J. J. Organomet. Chem. 1986, 299, 19.
26. Ueno, K.; Yamaguchi, K.; Ogino, H. Organometallics 1999, 18, 4468.
27. Bibal, C.; Mazières, S.; Gornitzka, H.; Couret, C. Organometallics 2002, 21, 2940.
28. Saur, I.; Rima, G.; Miqueu, K.; Gornitzka, H.; Barrau, J. J. Organomet. Chem. 2003, 672, 77.
29. Saur, I.; Alonso, S. G.; Gornitzka, H.; Lemierre, V.; Chrostowska, A.; Barrau, J. Organometallics 2005, 24,2988.
30. Górski, M.; Kochel, A.; Szymańska-Buzar, T. J. Organomet. Chem. 2006, 691, 3708.
31. (a) Zabula, A. V.; Hahn, F .E.; Pape, T.; Hepp, A. Organometallics 2007, 26, 1972.
32. (b) Hahn, F. E.; Zabula, A. V.; Pape, T.; Hepp, A.; Tonner, R.; Haunschild, R.; Franking, G. Chem.-Eur. J. 2008, 14,1076.
33. Filippou, A. C.; Winter, J. G.; Kociok-Köhn; Hinz, I. J. Chem. Soc., Dalton Trans. 1998,2029.
34. Handzlik, J.; Stosur, M.; Kochel, A.; Szymańska-Buzar, T. Inorg. Chim. Acta 2008, 361, 502.
35. Chan, L. Y. Y.; Dean, W. K.; Graham, W. A. G. Inorg. Chem. 1977, 16, 1067.
36. Carrè, F.; Colomer, E.; Corriu, R. J. P.; Vioux, A. Organometallics 1984, 3, 970.
37. Baik, M.-H.; Friesner, R. A.; Parkin, G. Polyhedron 2004, 23, 2879.
38. Stosur, M.; Kochel, A.; Keller, A.; Szymańska-Buzar, T. Organometallics 2006, 25, 3791.
39. (a) Boese, R.; Müller, U. Acta Crystallogr. 1976, B32, 582.
40. (b) Schmid, G.; Boese, R.; Welz, E. Chem. Ber. 1975, 108, 260.
41. Tanabe, M.; Ishikawa, N.; Hanzawa, M.; Osakada, K. Organometallics 2008, 27,5152.
42. CCD data collection and reduction GUI, Version 1.173.13 beta (release 14.11.2003); Oxford Diffraction Poland Sp., 1995-2003.
43. Sheldrick, G. M. SHELXS-97, Program/or Crystal Structure Solution; University of Göttingen: Germany, 1997.
44. Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement; University of Göttingen: Gennany, 1997.
45. Becke, A. D. Phys. Rev. A 1988, 38, 3098.
46. Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785.
47. Perdew, J. P. Phys. Rev. 1986, B 33, 8822.
48. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865.
49. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1997, 78, 1396.
50. Perdew, J. P.; Chevary, J. A,; Vosko, S. H.; Jackson, K. A.; Pederson, M. R.; Singh, D. J.; Fiolhais, C. Phys. Rev. 1992, B 46, 6671.
51. Tao, J.; Perdew, J. P.; Staroverov, V. N.; Scuseria, G. E. Phys. Rev. Lett. 2003, 91, 146401.
52. Van Voorhis, T.; Scuseria, G. E. J. Chem. Phys. 1998, 109,400.
53. Becke, A. D. J. Chem. Phys. 1993, 95, 5648.
54. Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98, 11623.
55. Wilson, P. J.; Bradley, T. J.; Tozer, D. J. J. Chem. Phys. 2001, 115, 9233.
56. Adamo, C.; Barone, V. J. Chem. Phys. 1999, 110,6158.
57. Zhao, Y.; Schultz, N. E.; Truhlar, D. G. J. Chem. Phys. 2005, 123,161103.
58. Staroverov, V. N.; Scuseria, G. E.; Tao, J.; Perdew, J. P. J. Chem. Phys. 2003, 119, 12129.
59. Krieger, J. B.; Chen, J.; Iafrate, G. J.; Savin, A. In Electron Correlations and Materials Properties; Gonis, A.; Kioussis, N., Eds.; Plenum: New York, 1999; p 463.
60. Toulouse, J.; Savin, A.; Adamo, C. J. Chem. Phys. 2002, 117, 10465.
61. Zhao, Y.; Lynch, B. J.; Truhlar, D. G. Phys. Chem. Chem. Phys. 2005, 7,43.
62. Weigend, F.; Ahlrichs, R. Phys. Chem. Chem. Phys. 2005, 7, 3297.
63. Andrae, D.; Haeussermann, U.; Dolg, M.; Stoll, H.; Preuss, H. Theor. Chim. Acta 1990, 77, 123.
64. Peng, C.; Ayala, P. Y.; Schlegel, H. B.; Frisch, M. J.Comput. Chem. 1996, 17,49.
65. Ditchfield, R. Mol. Phys. 1974, 27, 789.
66. Wolinski, K.; Hilton, J. F.; Pulay, P. J. Am. Chem. Soc. 1990, 112,8251.
67. Kutzelnigg, W.; Fleischer, U.; Schindler, M. In NMR Basic Principles and Progress; Diehl, P; Fluck, E.; Günther, H.; Kosfeld, R.; Seelig, J., Eds.; Springer-Verlag: Berlin, 1990; Vol. 23, p 165.
68. Enevoldsen, T.; Oddershede, J.; Sauer, S. P. A. Theor. Chem. Acc. 1998, 100,275.
69. Provasi, P. F.; Aucar, G. A.; Sauer, S. P. A. J. Chem. Phys. 2001, 115, 1324.
70. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. K.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, Revision E.01; Gaussian, Inc.: Wallingford, CT, 2004.
71. Dennington , R., II; Keith, T.; Millam, J. Gauss View, Version 4.1; Semichem, Inc.: Shawnee Mission, KS, 2007.