Activation of the Si-H bond of Et2SiH2 in photochemical reaction with W(CO)6: Spectroscopic characterization of intermediate W-Si compounds and the revisited crystal structure of the bis{(μ-η2-hydridodiethylsilyl)tetracarbonyltungsten(I)} complex [{W(μ-η2-H-SiEt2)(CO)4}2]

Journal of Organometallic Chemistry

Volumn 692, Issue 17, 2007, Pages 3765-3777

  Gadek, Agnieszka ^a   Kochel, Andrzej ^a   Szymańska Buzar, Teresa ^a  

^a UNIVERSITY OF WROC AW   (Poland)

Author keywords

Agostic interaction; Hydride ligands; Si ligands; Silicon; Tungsten

Indexed keywords

AGOSTIC INTERACTION; AGOSTIC PROTONS; HYDRIDE LIGANDS;

CHEMICAL BONDS; CRYSTAL STRUCTURE; LIGANDS; METAL COMPLEXES; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOCHEMICAL REACTIONS; SILANES;

TUNGSTEN COMPOUNDS;

HELIOTHIS ZEA VIRUS 1;

EID: 34447285222     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.05.027     Document Type: Article

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