Giant pores in a chromium 2,6-Naphthalenedicarboxylate Open- Framework structure with MIL-101 topology

Angewandte Chemie - International Edition

Volumn 48, Issue 21, 2009, Pages 3791-3794

  Sonnauer, Andreas ^a   Hoffmann, Frank ^b   Fröba, Michael ^b   Kienle, Lorenz ^a   Duppel, Viola ^a   Thommes, Matthias ^c   Serre, Christian ^d   Férey, Gérard ^d   Stock, Norbert ^a  

^a UNIVERSITY OF KIEL   (Germany)

^b UNIVERSITY OF HAMBURG   (Germany)

^c QUANTACHROME INSTRUMENTS   (United States)

^d UNIVERSITÉ DE VERSAILLES SAINT QUENTIN EN YVELINES   (France)

Author keywords

High throughput methods; Mesoporous materials; Metal organic frameworks; Solvothermal synthesis; Structure simulation

Indexed keywords

BENZENEDICARBOXYLATE; HIGH-THROUGHPUT METHOD; HIGH-THROUGHPUT METHODS; MESOPOROUS; METAL-ORGANIC FRAMEWORKS; MOLECULAR SIMULATIONS; OPEN-FRAMEWORK STRUCTURES; POWDER X RAY DIFFRACTION; REACTION CONDITIONS; SOLVOTHERMAL SYNTHESIS; STRUCTURE SIMULATION; TEM;

CHROMIUM; SORPTION;

MESOPOROUS MATERIALS;

EID: 70349976626     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200805980     Document Type: Article

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43. 2O (954 μL) were homogenized for 20 min by stirring. The following temperature program was used: heating to 200°C over 3 h, holding the temperature for 5 h, cooling to room temperature over 3 h. The reaction product MIL-101-NDC-as (as = as synthesized) was activated three times by treating with EtOH (10 mL) at 160°C for 30 min under microwave heating. This treatment led to an increase in the specific surface area (see the Supporting Information). Thermogravimetric analysis in air revealed that MIL-101-NDC is stable up to 260°C.
44. All molecular simulations were carried out with software package Materials Studio Version 4.3, Accelrys Inc., San Diego, CA, 2008. For details, see the Supporting Information.
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46. IR and Raman spectroscopy gave no information on the existence of aliphatic C-H vibrations. Thus, the incorporation of acetate groups could be ruled out (see the Supporting Information).